Dry reforming of methane using a nickel-based bi-metallic catalyst

Patent metadata

Field	Value
Publication number	US-12258272-B2
Application number	US-202117401071-A
Country	US
Kind code	B2
Filing date	Aug 12, 2021
Priority date	Aug 12, 2021
Publication date	Mar 25, 2025
Grant date	Mar 25, 2025

Abstract

A method of dry reforming methane with CO 2 using a bi-metallic nickel and ruthenium-based catalyst. A dry reformer having the bimetallic catalyst as reforming catalyst, and a method of producing syngas with the dry reformer.

First claim

What is claimed is:

1. A method of dry reforming methane, comprising reacting the methane with carbon dioxide via a reforming catalyst at a temperature of 700-900° C. and a pressure of 7 bar to 14 bar to generate synthesis gas comprising hydrogen and carbon monoxide, wherein the reforming catalyst comprises:
19.5 wt % of a nickel component;
0.5 wt % of a ruthenium component;
and
80 wt % of a cerium and gadolinium oxide component.

2. The method of claim 1 , wherein the cerium and gadolinium oxide component is Ce 0.9 Gd 0.1 O 2-x .

3. The method of claim 1 , wherein the catalyst is resistant to the formation of coke on the catalyst during use of the catalyst.

4. The method of claim 1 , comprising prior to the reacting, exposing the reforming catalyst to hydrogen and nitrogen at 700-800° C. for 3-6 hours.

5. The method of claim 1 , wherein the methane is converted to synthesis gas at a conversion rate of 70% or greater based on an initial concentration of methane.

6. The method of claim 1 , wherein the methane is in a methane-containing fluid stream, and wherein the methane-containing fluid stream further comprises propane and butane.

7. The method of claim 1 , wherein a volume ratio of the methane and carbon dioxide during the reacting is 1:1 to 1:3.

8. The method of claim 1 , wherein the methane and carbon dioxide are reacted via the reforming catalyst at a temperature of 700° C. and a pressure of 7 to 14 bar, and wherein the methane is converted to synthesis gas at a conversion rate of 71 to 80%.

9. The method of claim 8 , wherein a molar ratio of the hydrogen and carbon monoxide present in the synthesis gas is 1.8:1 to 1.9:1.

10. The method of claim 1 , wherein the methane and carbon dioxide are reacted via the reforming catalyst at a temperature of 750° C. and a pressure of 7 to 14 bar, and wherein the methane is converted to synthesis gas at a conversion rate of 79 to 85%.

11. The method of claim 10 , wherein a molar ratio of the hydrogen and carbon monoxide present in the synthesis gas is 1.5:1 to 1:2.

12. The method of claim 1 , wherein the methane and carbon dioxide are reacted via the reforming catalyst at a temperature of 800° C. and a pressure of 7 bar, and wherein the methane is converted to synthesis gas at a conversion rate of 70 to 90%.

13. The method of claim 12 , wherein a molar ratio of the hydrogen and carbon monoxide present in the synthesis gas is 1.5:1 to 1:2.

14. A method of dry reforming method, comprising:
providing methane and carbon dioxide to a dry reformer vessel, wherein a reforming catalyst comprising 19.5 wt % of a nickel component, 0.5 wt % of a ruthenium component, and 80 wt % of a cerium and gadolinium oxide component is disposed in the dry reformer vessel;
dry reforming the methane in the dry reformer vessel via the reforming catalyst at a temperature of 700-900° C. and a pressure of 7 bar to 14 bar to generate hydrogen and carbon monoxide; and
discharging the hydrogen and carbon monoxide from the dry reformer vessel.

15. The method of claim 14 , wherein the cerium and gadolinium oxide component is Ce 0.9 Gd 0.1 O 2-x .

16. The method of claim 14 , wherein the dry reforming comprises reacting the methane with the carbon dioxide.

17. The method of claim 14 , comprising providing heat to the dry reformer vessel for the dry reforming comprising reacting of the methane with the carbon dioxide, wherein the reacting of the methane with the carbon dioxide is endothermic.

Assignees

• Saudi Arabian Oil Co

Inventors

• Lee Kunho
• Katikaneni Sai P
• Harale Aadesh
• Solami Bandar

Classifications

• C01B2203/1082

  Composition of support materials · CPC title

• C01B2203/1064

  Platinum group metal catalysts · CPC title

• C01B2203/1058

  Nickel catalysts · CPC title

• B01J23/462

  Ruthenium · CPC title

• C01B2203/0238

  the reforming step being a carbon dioxide reforming step · CPC title