Phosphor, method of producing phosphor, light-emitting element, light-emitting device, and image display apparatus

Patent metadata

Field	Value
Publication number	US-12256579-B2
Application number	US-202017621050-A
Country	US
Kind code	B2
Filing date	Jun 18, 2020
Priority date	Jun 26, 2019
Publication date	Mar 18, 2025
Grant date	Mar 18, 2025

Abstract

A phosphor in which at least some of an element M in a phosphor host crystal represented by Mα(L, A)βXγ is substituted with Eu as an activation material. M represents one or more (including at least Sr) of Mg, Ca, Sr, Ba, and Zn, L represents one or more of Li, Na, and K, A represents one or more of Al, Ga, B, In, Sc, Y, La, and Si, X represents one or more (except that X represents only N) of O, N, F, and Cl, α, β, γ, and δ satisfy 8.70≤α+β+γ+δ≤9.30, 0.00<α≤1.30, 3.70≤β≤4.30, 3.70≤γ≤4.30, and 0.00<δ≤1.30. In a fluorescence spectrum obtained by irradiation with light having a wavelength of 260 nm, when a fluorescence intensity at a wavelength of 569 nm is represented by I0 and a fluorescence intensity at a wavelength of 617 nm is represented by I1, I1/I0 is 0.01 or more and 0.4 or less.

First claim

The invention claimed is:

1. A phosphor in which at least some of an element M in a phosphor host crystal represented by M α (L, A) β X γ is substituted with Eu, in both Eu 3+ and Eu 2+ states, as an activation material, the phosphor having a composition represented by Formula: M α (L, A) β X γ :Eu δ ,
wherein M represents one or more elements (including at least Sr) selected from Mg, Ca, Sr, Ba, and Zn,
L represents one or more elements selected from Li, Na, and K,
A represents one or more elements selected from Al, Ga, B, In, Sc, Y, La, and Si,
X represents one or more elements selected from O, N, F, and Cl, wherein X is not only N,
α, β, γ, and δ satisfy 8.70≤α+β+γ+δ≤9.30,
0.00<α≤1.30,

3.70≤β≤4.30,

3.70≤δ≤4.30, and

0.00<δ≤1.30, and

in a fluorescence spectrum obtained by irradiation with light having a wavelength of 260 nm, when a fluorescence intensity at a wavelength of 569 nm is represented by I 0 and a fluorescence intensity at a wavelength of 617 nm is represented by I 1 , a fluorescence intensity ratio I 1 /I 0 is 0.01 or more and 0.4 or less,
wherein the phosphor is powdery such that, when an average particle size corresponding to a cumulative value of 50% in a volume frequency particle size distribution measured using a laser diffraction scattering method is represented by d50, d50 is from 0.1 μm or more to 50 μm or less.

2. The phosphor according to claim 1 ,
wherein in the fluorescence spectrum, when an emission intensity at a wavelength of 628 nm is represented by I 2 , a fluorescence intensity ratio I 2 /I 0 is 0.01 or more and 0.3 or less.

3. The phosphor according to claim 1 ,
wherein the phosphor is represented by a compositional formula Sr e Li f Al g O h1 N h2 Eu i , compositional proportions e, f, g, h1, h2, and i satisfy
e+f+g+h 1+ h 2+ i= 9,
0.00 <e <1.30,
0.70 ≤f ≤3.30,

0.70 ≤g ≤3.30,

3.70 ≤h 1 +h 2≤4.30 (where h 1>0),

0.00 <i <1.30, and
0.70 ≤e+i ≤1.30.

4. The phosphor according to claim 3 ,
wherein the compositional proportions f and g satisfy
7/40 ≤g /( f+g )<30/40.

5. The phosphor according to claim 3 ,
wherein the compositional proportions h1 and h2 satisfy
0 <h 1/( h 1 +h 2)≤1.

6. The phosphor according to claim 1 ,
wherein by irradiation with light having a light intensity peak in a wavelength range of 250 nm or longer and 500 nm or shorter, fluorescence having a light intensity peak in a wavelength range of 430 nm or longer and 670 nm or shorter is emitted.

7. The phosphor according to claim 6 ,
wherein by irradiation with light having a light intensity peak in the wavelength range of 250 nm or longer and 500 nm or shorter, fluorescence having a light intensity peak in a wavelength range of 560 nm or longer and 580 nm or shorter is emitted.

8. A method of producing a phosphor having a composition including at least one element M selected from the group consisting of Mg, Ca, Sr, Ba, and Zn, at least one element L selected from the group consisting of Li, Na, and K, at least one element A selected from the group consisting of Al, Ga, B, In, Sc, Y, La, and Si, at least one element X selected from the group consisting of O, N, F, and Cl, and Eu, wherein X is not only N,
the method comprising:
a mixing step of obtaining a raw material mixture including respective elements forming the composition; and
a firing step of firing the raw material mixture such that at least some of Eu 3+ in the raw material mixture is reduced into Eu 2+ ,

wherein in a fluorescence spectrum obtained by irradiation with light having a wavelength of 260 nm, when a fluorescence intensity at a wavelength of 569 nm is represented by I 0 and a fluorescence intensity at a wavelength of 617 nm is represented by I 1 , a fluorescence intensity ratio I 1 /I 0 is 0.01 or more and 0.4 or less, and
wherein the firing step is performed in a firing atmosphere including NH 3 .

9. A light-emitting element comprising the phosphor according to claim 1 .

10. A light-emitting device comprising the light-emitting element according to claim 9 .

11. An image display apparatus comprising the light-emitting element according to claim 9 .

Assignees

• Denka Company Ltd

Inventors

• Toyoshima Hiroaki
• Kawagoe Mitsuru

Classifications

• C09K11/645

  with alkali or alkaline earth metals · CPC title

• C09K11/63

  containing boron · CPC title

• C09K11/62

  containing gallium, indium or thallium · CPC title

• C09K11/77346

  Aluminium Nitrides or Aluminium Oxynitrides · CPC title

• H10H20/851

  Wavelength conversion means · CPC title