Lithium-air battery

Patent metadata

Field	Value
Publication number	US-12255309-B2
Application number	US-202217842660-A
Country	US
Kind code	B2
Filing date	Jun 16, 2022
Priority date	Jun 16, 2021
Publication date	Mar 18, 2025
Grant date	Mar 18, 2025

Abstract

A battery may include an anode, a cathode positioned opposite to the anode, a separator positioned between the anode and the cathode, an electrolyte dispersed throughout the cathode and in contact with the anode, and a dual-pore system. The anode may be configured to release a plurality of lithium ions. The cathode may include a plurality of pathways defined by a plurality of porous non-hollow carbonaceous spherical particles and may include a plurality of carbonaceous structures each based on a coalescence of a group of the porous non-hollow carbonaceous spherical particles. The dual-pore system may be disposed in the cathode and defined in shape and orientation by the plurality of carbonaceous structures. In some aspects, the dual-pore system may be configured to receive gaseous oxygen from the ambient atmosphere.

First claim

What is claimed is:

1. A lithium-air battery, comprising:
an anode;
a cathode formed of an arrangement of carbonaceous structures and positioned opposite the anode, the cathode including:
a plurality of pores defined by a first group of the carbonaceous structures, the pores configured to allow oxygen supplied by ambient air to enter the cathode;
a plurality of interconnected pathways defined by a second group of the carbonaceous structures, the interconnected pathways configured to diffuse the oxygen throughout the cathode; and
one or more cavities formed within each of the pathways, each cavity configured to store lithium metal;

an electrolyte dispersed throughout the cathode, the electrolyte in fluid contact with the anode; and
one or more openings configured to selectively expose at least some of the plurality of pores to the ambient air.

2. The lithium-air battery of claim 1 , wherein the anode consists of lithium metal.

3. The lithium-air battery of claim 1 , wherein each carbonaceous structure is based on a coalescence of a corresponding group of carbon nano-onion (CNO) particles.

4. The lithium-air battery of claim 3 , wherein each carbonaceous structure further includes a plurality of interconnected graphene flakes.

5. The lithium-air battery of claim 3 , wherein each carbonaceous structure further includes one or more of flat graphene, wrinkled graphene, curved graphene, or porous non-hollow spherical particles.

6. The lithium-air battery of claim 3 , wherein the CNO particles have a radius between approximately 5 nanometers and 500 nanometers.

7. The lithium-air battery of claim 3 , wherein at least some of the CNO particles of the first group of carbonaceous structures have a radius greater than 100 nanometers.

8. The lithium-air battery of claim 7 , wherein each of the at least some CNO particles includes a plurality of the cavities.

9. The lithium-air battery of claim 3 , wherein at least some of the CNO particles of the first group of carbonaceous structures are configured to be hydrophobic.

10. The lithium-air battery of claim 9 , wherein the hydrophobic CNO particles of the first group of carbonaceous structures inhibit a movement of water droplets along a surface towards one or more of the plurality of pores.

11. The lithium-air battery of claim 3 , wherein at least some of the CNO particles of the second group of carbonaceous structures are configured to be hydrophilic.

12. The lithium-air battery of claim 11 , wherein the hydrophilic CNO particles of the second group of carbonaceous structures allow water droplets to form a continuous water film along respective surfaces of the hydrophilic CNO particles.

13. The lithium-air battery of claim 12 , wherein the continuous water film is in an equilibrium state resulting from cohesive forces within the continuous water film and adhesive forces between the continuous water film and respective surfaces of the hydrophilic CNO particles.

14. The lithium-air battery of claim 12 , wherein a surface tension associated with the continuous water film prevents the water droplets of the continuous water film from accumulating in the cathode.

15. The lithium-air battery of claim 1 , wherein at least some of the cavities have a diameter between approximately 0.6 nanometers and 6.6 nanometers.

16. The lithium-air battery of claim 1 , further comprising:
a plurality of other interconnected pathways defined by a third group of the carbonaceous structures, the plurality of other interconnected pathways configured to remove unwanted byproducts from at least some portions of the interconnected pathways defined by the second group of carbonaceous structures.

17. The lithium-air battery of claim 1 , further comprising a separator positioned between the anode and the cathode.

18. The lithium-air battery of claim 1 , further comprising a protective layer disposed on the anode, the protective layer comprising:
a polymeric network deposited over one or more exposed surfaces of the anode, the polymeric network including the carbonaceous structures grafted with a plurality of fluorinated polymer chains cross-linked with each other; and
a lithium fluoride (LiF) film formed from the polymeric network and lithium provided by the anode.

19. The lithium-air battery of claim 18 , further comprising an outer layer deposited on the lithium fluoride film, the outer layer including one or more of a polymer or an epoxy encapsulated ionic conductor.

20. The lithium-air battery of claim 1 , wherein each of the carbonaceous structures includes a three-dimensional (3D) stack of graphene nanosheets.

Assignees

• Lyten Inc

Inventors

• Gazda Jerzy
• Vanheusden Karel
• Bugga Ratnakumar
• Cook Daniel

Classifications

• H01M12/08

  composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type · CPC title

• H01M4/62

  Selection of inactive substances as ingredients for active masses, e.g. binders, fillers · CPC title

• H01M2004/027

  Negative electrodes · CPC title

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• H01M2004/028

  Positive electrodes · CPC title