Aqueous resin dispersion and aqueous coating composition containing said resin dispersion

Patent metadata

Field	Value
Publication number	US-12252609-B2
Application number	US-202017613511-A
Country	US
Kind code	B2
Filing date	May 13, 2020
Priority date	May 23, 2019
Publication date	Mar 18, 2025
Grant date	Mar 18, 2025

Abstract

Described herein is an aqueous resin dispersion (AD) including a resin component (R) including at least one di- and/or polyfunctional monomeric primary and/or secondary amine (M) and polyfunctional polymeric organic amines having primary and/or secondary amino groups. Also described herein is an aqueous two-component coating composition including the resin dispersion.

First claim

The invention claimed is:

1. An aqueous resin dispersion (AD) comprising:
a resin component (R) comprising:
at least one di- and/or polyfunctional monomeric primary and/or secondary amine (M) and
polyfunctional polymeric organic amines having primary and/or secondary amino groups,

wherein the resin component (R) has an NH equivalent of 150 to 400 g/mol and a proportion by weight of di- and/or polyfunctional monomeric organic amines (M) of 5% to 15% by weight,
and wherein the aqueous dispersion (AD) is prepared by a two-stage process (A+B) comprising:
(A) reacting two starting components (Ia) and (Ib) to give an amino-functional resin mixture (I) having an NH equivalent of 50 to 140 g/mol and a proportion by weight of di- and/or polyfunctional monomeric primary and/or secondary amines (M) of 17.5% to 40% by weight,
wherein
component (Ia) is an epoxy-functional resin mixture and, in interreacted form, comprises the following components (Ia1) and (Ia2):
(Ia1)=at least one di- and/or multifunctional organic epoxy compound,
(Ia2)=at least one compound X—R wherein X is a functional group reactive toward epoxy groups and R is an organic radical containing polyoxyalkylene units and not containing any further X groups,

and
component (Ib) comprises at least one di- and/or multifunctional monomeric primary and/or secondary amine (M),

(B) reacting two starting components (IIa) and (IIb) in the aqueous phase to give the resin component (R), wherein
component (IIa) comprises the amino-functional resin mixture (I)
and
component (IIb) comprises at least one di- and/or multifunctional organic epoxy compound, wherein the epoxy compounds used have an average epoxy equivalent weight of less than 400 g/mol,

wherein the amines (M) consist to an extent of at least 65 mol % of amines consisting of amino groups and hydrocarbon units.

2. The aqueous resin dispersion (AD) as claimed in claim 1 , wherein the amines (M) are difunctional primary and/or secondary amines.

3. The aqueous resin dispersion (AD) as claimed in claim 1 , wherein the resin component (R) has an N—H equivalent of 170 to 250 g/mol.

4. The aqueous resin dispersion (AD) as claimed in claim 1 , wherein the X group in the compound (Ia2) is a primary amino group.

5. The aqueous resin dispersion (AD) as claimed in claim 1 , wherein the compound (Ia2) is a primary polyoxyalkylenemonoamine.

6. The aqueous resin dispersion (AD) as claimed in claim 1 , wherein the resin mixture (I) has an N—H equivalent of 70 to 120 g/mol.

7. The aqueous resin dispersion (AD) as claimed in claim 1 , wherein the at least one di- and/or multifunctional organic epoxy compound of component (IIb) has an average epoxy equivalent weight of less than 250 g/mol.

8. The aqueous resin dispersion (AD) as claimed in claim 1 , wherein the resin mixture (I) consists of components (Ia1), (Ia2) and (Ib), wherein component (Ib) moreover consists of at least one amine (M).

9. The aqueous resin dispersion (AD) as claimed in claim 8 , wherein component (IIa) consists of the resin mixture (I) and component (IIb) consists of at least one di- and/or multifunctional organic epoxy compound, wherein the epoxy compounds used have an average epoxy equivalent weight of less than 400 g/mol.

10. A process for preparing an aqueous dispersion (AD) comprising:
a resin component (R) comprising:
at least one di- and/or polyfunctional monomeric primary and/or secondary amine (M), and
polyfunctional polymeric organic amines having primary and/or secondary amino groups,

wherein the resin component (R) has an NH equivalent of 150 to 400 g/mol and a proportion by weight of di- and/or polyfunctional monomeric organic amines (M) of 5% to 15% by weight,
the process comprising a two-stage process (A+B) comprising
(A) reacting two starting components (Ia) and (Ib) to give an amino-functional resin mixture (I) having an NH equivalent of 50 to 140 g/mol and a proportion by weight of di- and/or polyfunctional monomeric primary and/or secondary amines (M) of 17.5% to 40% by weight,
wherein
component (Ia) is an epoxy-functional resin mixture and, in interreacted form, comprises the following components (Ia1) and (Ia2):
(Ia1)=at least one di- and/or multifunctional organic epoxy compound,
(Ia2)=at least one compound X—R wherein X is a functional group reactive toward epoxy groups and R is an organic radical containing polyoxyalkylene units and not containing any further X groups,

and
component (Ib) comprises at least one di- and/or multifunctional monomeric primary and/or secondary amine (M),

(B) reacting two starting components (IIa) and (IIb) in the aqueous phase to give the resin component (R), where
component (IIa) comprises the amino-functional resin mixture (I)
and
component (IIb) comprises at least one di- and/or multifunctional organic epoxy compound, wherein the epoxy compounds used have an average epoxy equivalent weight of less than 400 g/mol,

wherein the amines (M) consist to an extent of at least 65 mol % of amines consisting of amino groups and hydrocarbon units.

11. An aqueous two-component coating composition comprising a paint base component (1) and a curing component (2), wherein
I) the paint base component (1) comprises at least one aqueous dispersion as claimed in claim 1 and the curing component (2) comprises at least one epoxy resin, wherein the epoxy resins have an average epoxy equivalent weight of less than 400 g/mol,
or

II) the paint base component (1) comprises at least one epoxy resin, wherein the epoxy resins have an average epoxy equivalent weight of less than 400 g/mol, and the curing component (2) comprises the at least one aqueous dispersion.

12. The coating composition as claimed in claim 11 , characterized in that it is a surfacer or primer-surfacer.

13. A process for producing a cured coating on a substrate, the process comprising applying a coating composition as claimed in claim 11 to the substrate and then curing the composition.

14. A process for repairing a multicoat paint system having defects, comprising applying a coating composition as claimed in claim 11 in the region of the defects, curing the composition to produce a cured coating layer and then sanding the cured coating layer.

15. A coating that has been produced by a process as claimed in claim 13 .

16. The aqueous resin dispersion (AD) as claimed in claim 1 , wherein the amines (M) are difunctional primary amines.

Assignees

• Basf Coatings Gmbh

Inventors

• Kunze Andreas Arrian
• Schoeps Sibylle
• Hamsen Rene
• Benning Dirk
• Diekmann Hildegund
• Geuting Martin
• Przybilla Silke
• Ressel Joerg
• Rump Ignacia
• Schemschat Dagmar
• Theil Hubert
• Kondrat Anna
• Rohkamp Beate
• Tiggemann Monika
• Winkler Thorsten
• Nienhaus Egbert
• Gosheger Sven

Classifications

• C09D5/02 Primary

  Emulsion paints {including aerosols} · CPC title

• C08L2201/54

  Aqueous solutions or dispersions · CPC title

• C08L63/00

  Compositions of epoxy resins; Compositions of derivatives of epoxy resins · CPC title

• C09D163/00

  Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title