Process and device for producing hydrogen, carbon monoxide and a carbon-containing product

Patent metadata

Field	Value
Publication number	US-12252405-B2
Application number	US-201917309737-A
Country	US
Kind code	B2
Filing date	Dec 19, 2019
Priority date	Dec 20, 2018
Publication date	Mar 18, 2025
Grant date	Mar 18, 2025

Abstract

The invention relates to a process for producing hydrogen, carbon monoxide and a carbon-containing product in at least one reaction apparatus, wherein the at least one reaction apparatus comprises a bed of carbon-containing material and is characterized in that the bed of carbon-containing material in the at least one reaction apparatus is alternately heated to a temperature of >800° C. and, no later than upon reaching a temperature of 1800° C., cooled to a maximum of 800° C., wherein hydrogen and carbon monoxide are produced during the heating phase and carbon and hydrogen are produced during the cooling phase.

First claim

The invention claimed is:

1. A process for producing molecular hydrogen (H 2 ), carbon monoxide and a carbon-containing product, the process comprising the following steps:
(a) providing molecular hydrogen (H 2 ) and molecular oxygen (O 2 ),
(b) heating a bed of carbon-containing material to a temperature of >800° C. by reacting the molecular hydrogen (H 2 ) with the molecular oxygen (O 2 ),
wherein steps (a) and (b) proceed in the same reaction apparatus,
(c) drawing off the synthesis gas formed, containing molecular hydrogen (H 2 ) and carbon monoxide,
(d) ending the provision of molecular hydrogen (H 2 ) and molecular oxygen (O 2 ) no later than upon reaching a temperature of the bed of carbon-containing material of 1800° C.,
(e) providing a gaseous hydrocarbon stream and decomposing the hydrocarbons in the presence of the bed of carbon-containing material to give carbon and molecular hydrogen (H 2 ), the temperature of the bed of carbon-containing material decreasing in the process,
(f) drawing off the molecular hydrogen (H 2 ),
(g) ending the provision of a gaseous hydrocarbon stream no later than upon reaching a temperature of the bed of carbon-containing material of ≤900° C., and
(h) withdrawing at least a portion of the carbon-containing material of the bed, wherein the carbon-containing material includes a deposit comprising the carbon-containing product.

2. The process as claimed in claim 1 , wherein
the reaction apparatus is connected to a further reaction apparatus, which likewise contains a bed of carbon-containing material, and
while steps (e) to (h) are conducted in the reaction apparatus, steps (a) to (d) are conducted in the further reaction apparatus, and
the molecular hydrogen (H 2 ) formed in the reaction apparatus is fed at least in part to the further reaction apparatus and is reacted with molecular oxygen (O 2 ), and
on reaching the respective temperatures, the process regime is inverted, and while steps (a) to (d) are conducted in the reaction apparatus, steps (e) to (h) are conducted in the further reaction apparatus.

3. The process as claimed in claim 1 , wherein molecular hydrogen (H 2 ) and molecular oxygen (O 2 ) are introduced into the reaction apparatus and/or the further reaction apparatus and combusted, preferably at the respective end of the reaction apparatus and/or further reaction apparatus at which they are introduced.

4. The process as claimed in claim 1 , wherein the respective bed of carbon-containing material in the reaction apparatus and/or the further reaction apparatus is alternately heated to a temperature of >900° C. and, no later than upon reaching a temperature of 1800° C., cooled to ≤900° C.

5. The process as claimed in claim 1 , wherein the respective bed of carbon-containing material in the reaction apparatus and/or the further reaction apparatus is heated to a temperature in the range from 1400° C. to 1800° C.

6. The process as claimed in claim 1 , wherein the respective bed of carbon-containing material in the reaction apparatus and/or the further reaction apparatus is cooled to a temperature of ≤900° C.

7. The process as claimed in claim 1 , wherein the gaseous hydrocarbon stream is natural gas or methane.

8. The process as claimed in claim 1 , wherein the respective bed of carbon-containing material in the reaction apparatus and/or the further reaction apparatus is a fixed bed.

9. The process as claimed in claim 1 , wherein the provision of molecular hydrogen (H 2 ) and molecular oxygen (O 2 ) and of the gaseous hydrocarbon stream are operated in flow reversal.

10. The process as claimed in claim 1 , wherein steps (a) to (h) as an overall process are repeated cyclically and continuously.

11. The process as claimed in claim 1 , wherein in a further step (d1), between steps (d) and (e), a gaseous stream is led through the reaction apparatus and/or the further reaction apparatus as an agent for purging, preferably composed of molecular hydrogen (H 2 ).

12. The process as claimed in claim 1 , wherein in a further step (g1), between steps (g) and (h), a gaseous stream is led through the reaction apparatus and/or the further reaction apparatus as a purging agent, preferably composed of molecular hydrogen (H 2 ) or methane.

13. The process as claimed in claim 1 , wherein, when heating the bed of carbon-containing material to a temperature of 1600° C., an H 2 /CO molar ratio of approximately 4 and a carbon yield of approximately 50% are achieved.

Assignees

• Thyssenkrupp Ind Solutions Ag
• Thyssenkrupp Ag
• Basf Se
• Thyssenkrupp Uhde Gmbh

Inventors

• Antweiler Nicolai
• Büker Karsten
• Scheiff Frederik
• Bode Andreas

Classifications

• C01B2203/1614

  Controlling the temperature · CPC title

• C01B2203/148

  involving a recycle stream to the feed of the process for making hydrogen or synthesis gas · CPC title

• C01B2203/1241

  Natural gas or methane · CPC title

• C01B2203/0822

  the fuel containing hydrogen · CPC title

• C01B2203/0272

  containing a non-catalytic decomposition step · CPC title