Solid agglomerated product based on iron oxides and corresponding production method

Patent metadata

Field	Value
Publication number	US-12247265-B2
Application number	US-201917280706-A
Country	US
Kind code	B2
Filing date	Sep 25, 2019
Priority date	Sep 27, 2018
Publication date	Mar 11, 2025
Grant date	Mar 11, 2025

Abstract

Solid agglomerated product, usable as a charge material for an electric arc furnace, comprises at least one fraction of by-product deriving from a steel plant and which comprises a first part containing ferrous oxide FeO and a second part containing ferric oxide Fe 2 O 3 , a fraction of solid fuel (CR) containing a quantity of carbon and at least one inorganic binder to agglomerate a fraction of by-product and the fraction of solid fuel with each other and give the agglomerated product the required mechanical properties. The inorganic binder at least partly comprises slag.

First claim

The invention claimed is:

1. Solid agglomerated product usable as a charge material for an electric arc furnace, said solid agglomerated product comprising:
at least one fraction of by-product deriving from a steel plant and comprising a first part containing ferrous oxide FeO and a second part containing ferric oxide Fe 2 O 3 ;
a fraction of solid fuel (CR) containing a quantity of carbon (C_fix);
at least one inorganic binder to agglomerate said at least one fraction of by-product and said fraction of solid fuel (CR) with each other and to give the agglomerated product the required mechanical properties;
wherein said fraction of solid fuel (CR) is present in a quantity in weight determined by the formula CR=K*CS/C_fix, wherein:
K: is a constant comprised between 1.2 and 2.5;
CS: is a quantity of stoichiometric carbon in weight defined by the formula CS=0.11* (Fe 2+ _tot)+0.16*(Fe 3+ _tot), where Fe 2+ _tot is a quantity in weight of iron contained in said first part, and Fe 3+ _tot is a quantity in weight of iron contained in said second part, wherein the inorganic binder at least partly comprises slag.

2. Product as in claim 1 , wherein the slag comprises white slag.

3. Product as in claim 1 , wherein the slag comprises black slag.

4. Product as in claim 1 , wherein the at least one inorganic binder comprises slag combined with cement.

5. Product as in claim 4 , wherein said cement is present in a percentage in weight comprised between 6% and 14% with respect to said at least one fraction of by-product.

6. Product as in claim 4 , wherein said slag is present in a percentage in weight comprised between 2% and 10% with respect to said at least one fraction of by-product.

7. Product as in claim 1 , wherein the agglomerated product comprises at least one additive selected from a group consisting of calcium oxide CaO, and calcium carbonate CaCO 3 .

8. Product as in claim 1 , wherein the product is in the form of pellets.

9. Product as in claim 1 , wherein the product is in the form of briquette.

10. Product as in claim 1 , wherein the product is a product obtained by extrusion.

11. Method to produce a solid agglomerated product comprising:
making available at least one fraction of by-product comprising a first part containing ferrous oxide FeO and a second part containing ferric oxide Fe 2 O 3 ;
making available a fraction of solid fuel (CR) containing a quantity of carbon C_fix;
mixing at least said fraction of by-product with said fraction of solid fuel (CR) and with at least one inorganic binder in order to obtain said solid agglomerated product,
wherein before said mixing, the method comprises determining a quantity in weight of said fraction of solid fuel (CR) by means of the formula CR-K*CS/C_fix, wherein:
K: is a constant comprised between 1.2 and 2.5;
CS: is a quantity of stoichiometric carbon in weight defined by the formula CS=0.11*(Fe 2+ _tot)+0.16*(Fe 3+ _tot), where Fe 2+ _tot is a quantity in weight of iron contained in said first part, and Fe 3+ _tot is a quantity in weight of iron contained in said second part, wherein the inorganic binder at least partly comprises slag.

12. Method as in claim 11 , wherein the slag comprises black or white slag.

13. Method as in claim 11 , wherein the at least one inorganic binder comprises slag combined with cement.

14. Method as in claim 11 , wherein during said mixing the method provides to add at least one additive selected from a group consisting of calcium oxide CaO, and calcium carbonate CaCO 3 .

15. Method as in claim 11 , wherein the method comprises the production of pellets, a single fraction of by-product is made available before mixing with a particle size smaller than 100 μm.

16. Method as in claim 11 , wherein the method comprises making briquettes, a first fraction of by-product having a particle size of less than 100 μm and at least a second fraction of by-product having a particle size comprised between 100 μm to 8 mm are made available.

17. Product as in claim 4 , wherein said cement is present in a percentage in weight comprised between 8% and 12% with respect to said at least one fraction of by-product.

18. Product as in claim 4 , wherein said slag is present in a percentage in weight comprised between 5% and 9% with respect to said at least one fraction of by-product.

Assignees

• Danieli Off Mecc

Inventors

• Tiburzio Selena
• Arsene Liliana Florina
• Tommasi Luca
• Primavera Alessandra

Classifications

• C21B11/10

  in electric furnaces · CPC title

• Y02P10/20

  Recycling · CPC title

• C22B1/245

  with carbonaceous material for the production of coked agglomerates · CPC title

• C22B1/243 Primary

  inorganic · CPC title