Biologically derived cement retarder

Patent metadata

Field	Value
Publication number	US-12247157-B2
Application number	US-202217866311-A
Country	US
Kind code	B2
Filing date	Jul 15, 2022
Priority date	Jul 15, 2022
Publication date	Mar 11, 2025
Grant date	Mar 11, 2025

Abstract

Methods for cementing. An example method provides a cement composition comprising an aqueous fluid, a cement, and a cement retarder; wherein the cement retarder is a waste residue from a manufacturing process of a sweetener and comprises a sugar concentration of at least 40%, a Brix value of at least 60, a nitrogen-free extract concentration of at least 50%, a total solids concentration of at least 60%, a crude protein concentration less than 10%, a fat concentration less than 5%, a fiber concentration less than 5%, and an ash concentration less than 10%. The method also introduces the cement composition into a wellbore penetrating a subterranean formation and pumps the cement composition to a location within the wellbore, and allows the cement composition to set in the location.

First claim

What is claimed is:

1. A method for cementing in a subterranean formation, comprising:
obtaining pulp waste residue from a sweetener manufacturing process; wherein the source of a sweetener for the sweetener manufacturing process is sugar cane, beet, citrus, maize, grain sorghum, pineapple, and any combination thereof;
processing the pulp waste residue by washing the pulp waste residue with a liquid or steam, then extracting the liquid effluent from the washed pulp waste residue, then drying the extracted liquid effluent to produce a dried extract, and then grinding and/or sieving the dried extract to produce the cement retarder; wherein the cement retarder comprises a sugar concentration of at least 40%, a Brix value of at least 60, a nitrogen-free extract concentration of at least 50%, a total solids concentration of at least 60%, a crude protein concentration less than 10%, a fat concentration less than 5%, a fiber concentration less than 5%, and an ash concentration less than 10%;
providing a cement composition comprising an aqueous fluid, a cement, and the cement retarder;
introducing the cement composition into a wellbore penetrating a subterranean formation;
pumping the cement composition to a location within the wellbore; and
allowing the cement composition to set in the location.

2. The method of claim 1 , wherein the sweetener manufacturing process is the sweetener manufacturing process of a molasses selected from the group consisting of cane molasses, sugar beet molasses, fruit molasses, citrus molasses, starch molasses, unsulfured molasses, hemicellulose extract, beet molasses, grain molasses, sorghum molasses, and any combination thereof.

3. The method of claim 1 , wherein the cement retarder is present in the cement composition in an amount of about 0.1% to about 15% by weight of the cement.

4. The method of claim 1 , wherein the cement is selected from the group consisting of Portland cements, pozzolanic cements, gypsum cements, high alumina content cements, silica cements, high alkalinity cements, slag cements, shale cements, cement kiln dust, and any combination thereof.

5. The method of claim 1 , wherein the cement composition further comprises an additive selected from the group consisting of foaming additives, strength-retrogression additives, lightweight additives, gas-generating additives, mechanical-property-enhancing additives, lost-circulation materials, fluid-loss-control additives, defoaming additives, thixotropic additives, and any combination thereof.

6. The method of claim 1 , wherein the cement composition has a density in the range of from about 4 pounds per gallon to about 20 pounds per gallon.

7. The method of claim 1 , wherein the cement composition is free of suspending aids and/or viscosifiers.

8. The method of claim 1 , wherein the cement composition is introduced into the subterranean formation during a remedial cementing operation.

Assignees

• Halliburton Energy Services Inc

Inventors

• Benkley James Robert
• Morgan Ronnie G
• Pisklak Thomas Jason

Classifications

• C09K8/467 Primary

  containing additives for specific purposes · CPC title

• C04B2103/20

  Retarders · CPC title

• Y02W30/91

  Use of waste materials as fillers for mortars or concrete · CPC title

• C04B28/02 Primary

  containing hydraulic cements other than calcium sulfates · CPC title