Process of preparation of an aqueous gel ink with fixed color comprising silver nanoparticles

Patent metadata

Field	Value
Publication number	US-12247131-B2
Application number	US-202017630805-A
Country	US
Kind code	B2
Filing date	Aug 28, 2020
Priority date	Aug 29, 2019
Publication date	Mar 11, 2025
Grant date	Mar 11, 2025

Abstract

The present invention concerns a process for preparing an aqueous gel ink with fixed color comprising the following steps: (i) preparing a gel-based matrix of aqueous ink; (ii) preparing an aqueous suspension of silver nanoparticles with a fixed color by mixing silver salts with: —water, —a mixture of at least an alkali metal or alkaline earth metal salt of citrate, —an oxidizing agent, preferably hydrogen peroxide H 2 O 2 , —and polyvinylpyrrolidone; (iii) adding under agitation the aqueous suspension of silver nanoparticles obtained in step (ii) to the gel-based matrix of aqueous ink obtained in step (i), to obtain an aqueous gel ink with fixed color with silver nanoparticles dispersed therein.

First claim

The invention claimed is:

1. A process for preparing an aqueous gel ink with fixed color comprising the following steps:
(i) preparing a gel-based matrix of aqueous ink;
(ii) preparing an aqueous suspension of silver nanoparticles with a fixed color by mixing silver salts with:
water,
a mixture of at least an alkali metal or alkaline earth metal salt of citrate, and an alkali metal hydride,
an oxidizing agent, and
and polyvinylpyrrolidone,
wherein the silver nanoparticles obtained in step (ii) are silver nanoparticles with the shape of spheres; and

(iii) adding under agitation the aqueous suspension of silver nanoparticles obtained in step (ii) to the gel-based matrix of aqueous ink obtained in step (i), to obtain an aqueous gel ink with fixed color with silver nanoparticles dispersed therein.

2. The process according to claim 1 , wherein the amount of said citrate salts added in step (ii) ranges from 0.001 to 0.08 weight % based on the total weight of the aqueous suspension.

3. The process according to claim 1 , wherein the total amount of silver salts added in step (ii) ranges from 0.0005 to 0.006 weight % based on the total weight of the aqueous suspension.

4. The process according to claim 1 , wherein the amount of alkali metal hydride added in step (ii) ranges from 0.0005 to 0.005 weight % based on the total weight of the aqueous suspension.

5. The process according to claim 1 , wherein the amount of oxidizing agent added in step (ii) ranges from 0.03 to 0.1 weight % based on the total weight of the aqueous suspension.

6. The process according to claim 1 , wherein the amount of polyvinylpyrrolidone added in step (ii) ranges from 0.05 to 0.1 weight % based on the total weight of the aqueous suspension.

7. An aqueous suspension of silver nanoparticles with a fixed color obtainable by the process of claim 1 , comprising silver nanoparticles and polyvinylpyrrolidone.

8. An aqueous gel ink with fixed color obtainable by the process of claim 1 , comprising silver nanoparticles and polyvinylpyrrolidone.

9. The aqueous gel ink according to claim 8 , further comprising an alkali metal salt, wherein the amount of alkali metal salt is of at least 0.0003 weight % based on the total weight of the aqueous gel ink.

10. The aqueous gel ink according to claim 8 , wherein the silver nanoparticles have an average particle size ranging from 1 to 100 nm.

11. The aqueous gel ink according to claim 8 , wherein the amount of silver nanoparticles ranges from 0.0005 to 5 weight % relative to the total weight of the aqueous gel ink.

12. The aqueous gel ink according to claim 8 , wherein the amount of water ranges from 50 to 95% by weight relative to the total weight of the aqueous gel ink.

13. The aqueous gel ink according to claim 8 , further comprising:
a co-solvent, in an amount ranging from 5 to 35% by weight relative to the total weight of the aqueous gel ink; and/or
an antimicrobial agent, in an amount ranging from 0.01 to 0.5% by weight relative to the total weight of the aqueous gel ink; and/or
a corrosion inhibitor, in an amount ranging from 0.05 to 1% by weight relative to the total weight of the aqueous gel ink; and/or
an antifoam agent, in an amount ranging from 0.05 to 1% by weight relative to the total weight of the aqueous gel ink; and/or
a rheology modifier, in an amount ranging from 0.08 to 2% by weight relative to the total weight of the aqueous gel ink.

14. A writing instrument comprising:
an axial barrel containing an aqueous gel ink with fixed color according to claim 8 , and
a pen body which delivers the aqueous gel ink stored in the axial barrel, wherein the writing instrument is chosen in the group consisting of gel pens, felt pens, correction fluid, and markers.

15. The aqueous suspension according to claim 7 , further comprising an alkali metal salt, wherein the amount of alkali metal salt is of at least 0.0003 weight % based on the total weight of the aqueous suspension.

16. The aqueous suspension according to claim 7 , wherein the silver nanoparticles have an average particle size ranging from 1 to 100 nm.

17. The aqueous suspension according to claim 7 , wherein the amount of silver nanoparticles ranges from 0.0005 to 5 weight % relative to the total weight of the aqueous suspension.

18. The aqueous suspension according to claim 7 , wherein the amount of water ranges from 50 to 95% by weight relative to the total weight of the aqueous suspension.

19. The aqueous gel ink according to claim 9 , wherein the silver nanoparticles have an average particle size ranging from 1 to 100 nm.

Assignees

• SOCIéTé BIC
• Univ Haute Alsace
• Centre Nat Rech Scient

Inventors

• Albenge Olivier
• Metillon Romain
• Mougin Karine
• Ghellal Feriel
• Spangenberg Arnaud

Classifications

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• C09D11/17 Primary

  characterised by colouring agents · CPC title

• C09D11/16 Primary

  Writing inks · CPC title