Mixture of octene hydroformylation by-product and diesel, kerosene or C8-C20 olefins as collectors

Patent metadata

Field	Value
Publication number	US-12246332-B2
Application number	US-202017435406-A
Country	US
Kind code	B2
Filing date	Mar 3, 2020
Priority date	Mar 5, 2019
Publication date	Mar 11, 2025
Grant date	Mar 11, 2025

Abstract

The presently claimed invention relates to a process for the beneficiation of coal and other hydrophobic materials, wherein a collector composition comprising by-products obtained by hydroformylation of octene isomers as a first component and diesel, kerosene and/or C 8 -C 20 olefins as a second component is used.

First claim

The invention claimed is:

1. A method for the beneficiation of at least one material, the method comprising:
a) providing a slurry comprising the at least one material dispersed in a liquid,
b) contacting the slurry with a collector composition,
c) subjecting the at least one material to beneficiation to result in a beneficiated material, and
c) recovering the beneficiated material,
wherein the collector composition comprises a mixture of collector A and collector B;
wherein the collector A are by-products obtained by hydroformylation of octene isomers and the collector B is selected from the group consisting of diesel, kerosene and C 8 -C 20 olefins;

wherein the by-products obtained by hydroformylation of octene isomers comprise
≥10 wt. % to ≤20 wt. % isomers of dinonyl ether,
≥20 wt. % to ≤35 wt. % isomers of nonyl esters and
≥25 wt. % to ≤45 wt. % isomers of trinonyl esters and trinonyl ethers.

2. The method according to claim 1 , wherein the by-products have a boiling point of ≥294° C.

3. The method according to claim 1 , wherein the by-products are obtained by hydroformylation of octene isomers at a temperature in the range of ≥120° C. to ≤ 240° C. and separating the by-products from the mixture by distillation at a temperature in the range of ≥200° C. to ≤250° C. to isolate the by-products.

4. The method according to claim 1 , wherein the diesel comprises paraffins, naphthenes and aromatic compounds.

5. The method according to claim 1 , wherein the kerosene comprises branched and straight chain alkanes, naphthenes and aromatic hydrocarbon.

6. The method according to claim 1 , wherein the collector composition comprises ≥10 wt. % to ≤90 wt. % of collector A and ≥90 wt. % to ≤10 wt. % of collector B.

7. The method according to claim 1 , wherein the collector composition is present in an amount of ≥50 g/ton to ≤2000 g/ton of the at least one material.

8. The method according to claim 1 , wherein at least one frothing agent is added to the slurry.

9. The method according to claim 1 , wherein at least one auxiliary agent selected from the group consisting of surfactants, depressants and activators is added to the slurry.

10. The method according to claim 9 , wherein the surfactants are selected from the group consisting of non-ionic surfactants, cationic surfactants and anionic surfactants.

11. The method according to claim 9 , wherein the depressants are selected from the group consisting of sodium isopropylnaphthalene sulfonate, sodium dioctylsulfo succinate, poly(ethylene) oxide, polycarboxylate ethers, sodium polyacrylate, polysaccharides, cellulose derivatives, and tannic acid.

12. The method according to claim 9 , wherein the activators are selected from the group consisting of copper sulfate, barium nitrate, calcium chloride and sodium sulphide.

13. The method according to claim 1 , wherein the at least one material is selected from the group consisting of coal, phosphate ore, molybdenum ore and graphite ore.

14. The method according to claim 1 , wherein the liquid is water.

15. A composition comprising at least one target material, a collector composition and a liquid, wherein the collector composition comprises a mixture of collector A and collector B;
wherein the collector A are by-products obtained by hydroformulation of octene isomers and the collector B is selected from the group consisting of diesel, kerosene and C 8 -C 20 olefins;
wherein the by-products obtained by hydroformylation of octene isomers comprise
≥10 wt. % to ≤20 wt. % isomers of dinonyl ether,
≥20 wt. % to ≤35 wt. % isomers of nonyl esters and

≥25 wt. % to ≤45 wt. % isomers of trinonyl esters and trinonyl ethers.

Assignees

• Basf Se

Inventors

• Dickie Scott Alexander
• Bai qian
• Villanueva Berindoague Adrian Mauricio
• Michailovski Alexej

Classifications

• B03D2203/08

  Coal ores, fly ash or soot · CPC title

• B03D2203/06

  Phosphate ores · CPC title

• B03D2201/02

  Collectors · CPC title

• B03D1/006

  Hydrocarbons · CPC title

• B03D1/0043

  modified so as to contain a polyether group · CPC title