Method for preparing positive electrode active material for lithium secondary battery, positive electrode comprising the positive electrode active material prepared by the same and lithium secondary battery

Patent metadata

Field	Value
Publication number	US-12244010-B2
Application number	US-202117605806-A
Country	US
Kind code	B2
Filing date	Jan 11, 2021
Priority date	Jan 10, 2020
Publication date	Mar 4, 2025
Grant date	Mar 4, 2025

Abstract

Provided are a manufacturing method of a positive electrode active material for a lithium secondary battery including: a first step of dry-mixing a transition metal hydroxide and an anhydrous lithium raw material; a second step of subjecting the mixture of the transition metal hydroxide and the anhydrous lithium raw material to primarily firing; and a third step of finely pulverizing and mixing the primarily fired material and performing secondary firing, and thus obtaining a lithium transition metal oxide, wherein, in the first step, the anhydrous lithium raw material is mixed at 40 parts by weight or less based on 100 parts by weight of the transition metal hydroxide, and a positive electrode for a lithium secondary battery including a positive electrode active material manufactured by the above-described manufacturing method, and a lithium secondary battery.

First claim

The invention claimed is:

1. A method of manufacturing a positive electrode active material for a lithium secondary battery, comprising:
a first step of preparing an anhydrous lithium raw material, wherein the anhydrous lithium raw material is LiOH comprising pulverizing hydrated lithium hydroxide (LiOH·H2O) having an average particle size (D50) of 300 μm or more until the average particle size (D50) becomes 50 μm to 250 μm to form a primary pulverized lithium hydroxide, vacuum-drying the primarily pulverized lithium hydroxide at 100° C. to 150° C. for 1 hour to 30 hours to form a vacuum-dried lithium hydroxide, and subsequently secondarily pulverizing the vacuum-dried lithium hydroxide until the average particle size (D50) becomes 5 μm to 30 μm;
a second step of dry-mixing a transition metal hydroxide and the anhydrous lithium raw material to form a mixture;
a third step of subjecting the mixture of the transition metal hydroxide and the anhydrous lithium raw material to primary firing to form a primarily fired material; and
a fourth step of finely pulverizing and mixing the primarily fired material and subsequently performing secondary firing, and thus obtaining a lithium transition metal oxide,
wherein, in the second step, the anhydrous lithium raw material is mixed at 40 parts by weight or less based on 100 parts by weight of the transition metal hydroxide.

2. The method of claim 1 , wherein, in the second step, the anhydrous lithium raw material is mixed at 10 parts by weight to 40 parts by weight based on 100 parts by weight of the transition metal hydroxide.

3. The method of claim 1 , wherein each of the primary firing and the secondary firing is carried out in an oxygen atmosphere.

4. The method of claim 1 , wherein each of the primary firing and the secondary firing is carried out in an oxygen atmosphere with an oxygen concentration of 80% or more by volume.

5. The method of claim 1 , wherein the primary firing is carried out at a temperature of 400° C. to 700° C.

6. The method of claim 1 , wherein the secondary firing is carried out at a temperature of 700° C. to 900° C.

7. The method of claim 1 , further comprising, after the fourth step, a fifth step of mixing the lithium transition metal oxide with a washing solution and thus removing a lithium by-product present on a surface of the lithium transition metal oxide.

8. The method of claim 7 , further comprising, after the fifth step, a sixth step of forming a coating layer including one or more selected from the group consisting of B, Al, Nb, W, Mo, Zr, Ti, Y, Ce, yttria-stabilized zirconia (YSZ), calcia-stabilized zirconia (CSZ), indium tin oxide (ITO), and Sr on a surface of the lithium transition metal oxide.

Assignees

• Lg Chemical Ltd

Inventors

• Kwak Ick Soon
• Chae Chang Wan
• Nam Hyo Joung
• Jeon Hye Ji

Classifications

• H01M2004/028

  Positive electrodes · CPC title

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/5825

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title