Date stone activated carbon supercapacitor

Patent metadata

Field	Value
Publication number	US-12243686-B2
Application number	US-202318332048-A
Country	US
Kind code	B2
Filing date	Jun 9, 2023
Priority date	Jun 9, 2023
Publication date	Mar 4, 2025
Grant date	Mar 4, 2025

Abstract

A supercapacitor including a gel electrolyte and two electrodes having a substrate, date stone activated carbon, a conductive carbon compound different from the date stone activated carbon, and a binding compound. A mixture of the date stone activated carbon, the conductive carbon compound, and the binding compound partially coats a surface of the substrate. The two electrodes are assembled in a symmetrical layered configuration with the surfaces coated with the mixture facing each other. The gel electrolyte is present between the surfaces coated with the mixture to form the supercapacitor. The gel electrolyte is a mixture of H 2 SO 4 , polyvinyl alcohol, and anthraquinone. Particles of the date stone activated carbon have a nanosheet morphology, and the nanosheets are stacked on top of each other to form a hierarchical structure.

First claim

The invention claimed is:

1. A supercapacitor, comprising:
a gel electrolyte; and
two electrodes;
wherein the electrodes comprise:
a substrate;
date stone activated carbon;
a conductive carbon compound different from the date stone activated carbon; and
a binding compound,

wherein a mixture of the date stone activated carbon, the conductive carbon compound, and the binding compound at least partially coats a surface of the substrate,
wherein the two electrodes are assembled in a symmetrical layered configuration with the surfaces coated with the mixture facing each other,
wherein the gel electrolyte is present between the surfaces coated with the mixture to form the supercapacitor,
wherein the gel electrolyte is a mixture of H 2 SO 4 , polyvinyl alcohol, and anthraquinone,
wherein particles of the date stone activated carbon have a nanosheet morphology, and
wherein the nanosheets are stacked on top of each other to form a hierarchical structure.

2. The supercapacitor of claim 1 , wherein the date stone activated carbon is at least 70% graphitic.

3. The supercapacitor of claim 1 , wherein the nanosheets have a width of 100-500 nm.

4. The supercapacitor of claim 1 , wherein the date stone activated carbon comprises carbon, oxygen, potassium, and magnesium.

5. The supercapacitor of claim 1 , wherein the date stone activated carbon comprises 80-95 wt. % carbon, 1-15 wt. % oxygen, 1-5 wt. % potassium, and 0.1-2 wt. % magnesium, based on a total weight of the date stone activated carbon.

6. The supercapacitor of claim 1 , wherein the date stone activated carbon has a BET surface area of 1500-1700 m 2 /g.

7. The supercapacitor of claim 1 , wherein the date stone activated carbon has a pore volume of 0.6-0.8 cm 2 /g.

8. The supercapacitor of claim 1 , wherein the date stone activated carbon has micropores, mesopores, and macropores.

9. The supercapacitor of claim 1 , wherein the mixture comprises 65-85 wt. % of the date stone activated carbon, 5-25 wt. % of the conductive carbon compound, and 5-15 wt. % of the binding compound, based on a total weight of the mixture.

10. The supercapacitor of claim 1 , wherein the gel electrolyte comprises 1-20 wt. % polyvinyl alcohol and 80-99 wt. % anthraquinone, based on a total weight of the polyvinyl alcohol and the anthraquinone in the gel electrolyte.

11. The supercapacitor of claim 1 , wherein the gel electrolyte has an equivalent series resistance of 0.3-0.7 Ω.

12. The supercapacitor of claim 1 , wherein the substrate is made from at least one material selected from the group consisting of stainless steel, aluminum, nickel, copper, platinum, zinc, tungsten, and titanium.

13. The supercapacitor of claim 1 , wherein the conductive carbon compound is at least one selected from the group consisting of graphite, activated carbon, reduced graphene oxide, carbon nanotubes, carbon nanofibers, and carbon black.

14. The supercapacitor of claim 1 , wherein the binding compound is selected from the group consisting of polyvinylidene fluoride and N-methyl pyrrolidone.

15. The supercapacitor of claim 1 , having a specific capacitance of 120-150 F/g at 0.5 A/g.

16. The supercapacitor of claim 1 , having an energy density of 15-20 Wh/kg at a power density of 250 W/kg.

17. The supercapacitor of claim 1 , having a capacitance retention of at least 85% after 1000 charge-discharge cycles.

18. A power bank, comprising:
2-10 of the supercapacitors of claim 1 connected in parallel and/or series.

19. A wearable device comprising the supercapacitor of claim 1 , wherein:
the supercapacitor is electrically connected to a sensor; and
the supercapacitor functions as a battery.

20. The supercapacitor of claim 1 , wherein the date stone activated carbon is produced by a method comprising:
cleaning and drying date stones to form dry date stones;
pulverizing the dry date stones to form a powder;
carbonizing the powder at a temperature of 300-500° C. for 1-10 hours under an inert atmosphere to form a carbon powder;
mixing the carbon powder with a base to form a carbon solution; and
carbonizing the carbon solution at a temperature of 700-1,000° C. for 1-10 hours under an inert atmosphere to form the date stone activated carbon.

Assignees

• Univ King Fahd Pet & Minerals

Inventors

• Shuaibu Abubakar Dahiru
• Alzahrani Atif Saeed
• Aziz Md Abdul

Classifications

• H01G11/24 Primary

  characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor · CPC title

• H01G11/86

  specially adapted for electrodes (carbonisation or activation of carbon for the manufacture of electrodes H01G11/34) · CPC title

• H01G11/56

  Solid electrolytes, e.g. gels; Additives therein · CPC title

• H01G11/36

  Nanostructures, e.g. nanofibres, nanotubes or fullerenes · CPC title

• H01G11/34

  characterised by carbonisation or activation of carbon · CPC title