Mitigating naturally occurring radioactive material in oxidative dehydrogenation

Patent metadata

Field	Value
Publication number	US-12240806-B2
Application number	US-202118009398-A
Country	US
Kind code	B2
Filing date	Jun 8, 2021
Priority date	Jun 11, 2020
Publication date	Mar 4, 2025
Grant date	Mar 4, 2025

Abstract

A system for mitigating naturally occurring radioactive materials (NORM) in an oxidative dehydrogenation process includes a feed stream, an oxidative dehydrogenation (ODH) reactor, an effluent stream, a processing unit, and a NORM reduction unit. The feed stream includes oxygen, a hydrocarbon, and NORM. The ODH reactor is configured to receive the feed stream and react the hydrocarbon with the oxygen to form a dehydrogenated hydrocarbon and water. The effluent stream includes the dehydrogenated hydrocarbon, water, unreacted hydrocarbon, and NORM. The processing unit is configured to process the effluent stream to form a product stream and a recycle stream. The product stream includes the dehydrogenated hydrocarbon. The recycle stream includes unreacted hydrocarbon and NORM. The NORM reduction unit is configured to reduce an amount of the NORM in the recycle stream to produce a NORM-reduced recycle stream. The ODH reactor is configured to receive the NORM-reduced recycle stream.

First claim

The invention claimed is:

1. A system, comprising:
an oxidative dehydrogenation reactor configured to: i) receive a feed stream comprising oxygen, a hydrocarbon, and a naturally occurring radioactive material (NORM); and ii) react at least a portion of the hydrocarbon with the oxygen to form a dehydrogenated hydrocarbon and water, an outlet of the oxidative dehydrogenation reactor configured to provide an effluent stream comprising the dehydrogenated hydrocarbon, water, a remaining unreacted portion of the hydrocarbon, and the NORM;
a processing unit configured to: i) receive the effluent stream; and ii) process the effluent stream so that an outlet of the processing unit is configured to provide: i) a product stream comprising the dehydrogenated hydrocarbon; and ii) a recycle stream comprising the remaining unreacted portion of the hydrocarbon and the NORM; and
a NORM reduction unit configured to receive the recycle stream and reduce an amount of the NORM in the recycle stream so that an outlet of the NORM reduction unit is configured to provide a NORM-reduced recycle stream,
wherein the outlet of the NORM reduction unit is fluidically coupled with an inlet of the oxidative dehydrogenation reactor.

2. The system of claim 1 , further comprising an adsorption bed positioned between the outlet of the NORM reduction unit and the inlet of the oxidative dehydrogenation reactor, wherein the adsorption bed is configured to remove NORM from any fluid entering the oxidative dehydrogenation reactor.

3. The system of claim 1 , further comprising a filter upstream of the oxidative dehydrogenation reactor, the filter configured to capture and prevent solid material from entering the oxidative dehydrogenation reactor.

4. The system of claim 1 , further comprising an absorber upstream of the oxidative dehydrogenation reactor, the absorber configured to remove NORM from the feed stream before the feed stream enters the oxidative dehydrogenation reactor.

5. The system of claim 1 , further comprising a solid material receptacle upstream of the oxidative dehydrogenation reactor, the solid material receptacle configured to remove solid material entrained in a fluid before the fluid enters the oxidative dehydrogenation reactor.

6. The system of claim 5 , further comprising an inlet pipe, wherein:
the oxidative dehydrogenation reactor defines an inlet opening coupled to the inlet pipe;
a portion of the inlet pipe is positioned below the inlet opening with respect to gravity; and
the solid material receptacle is coupled to the portion of the inlet pipe that is positioned below the inlet opening.

7. The system of claim 6 , wherein the inlet pipe comprises a baffle configured to direct the solid material to the solid material receptacle.

8. A system, comprising:
an oxidative dehydrogenation reactor configured to: i) receive a feed stream comprising oxygen, a hydrocarbon and naturally occurring radioactive material (NORM); and ii) react at least a portion of the hydrocarbon with the oxygen to form a dehydrogenated hydrocarbon and water, an outlet of the oxidative dehydrogenation reactor configured to provide an effluent stream comprising the dehydrogenated hydrocarbon, water, a remaining unreacted portion of the hydrocarbon, and the NORM;
a processing unit configured to: i) receive the effluent stream; and ii) process the effluent stream so that an outlet of the processing unit is configured to provide: i) a product stream comprising the dehydrogenated hydrocarbon; and ii) a recycle stream comprising the remaining unreacted portion of the hydrocarbon and the NORM; and
a storage tank configured to store the recycle stream for a sufficient time period such that the NORM decays into a solid material, the storage tank fluidically coupled to the oxidative dehydrogenation reactor to recycle the remaining unreacted portion of the hydrocarbon from the recycle stream to the oxidative dehydrogenation reactor while the solid material remains within the storage tank.

9. The system of claim 8 , wherein the storage tank comprises an outlet configured to discharge the remaining unreacted portion of the hydrocarbon from the recycle stream, and the outlet comprises a filter configured to capture and prevent solid material from exiting the storage tank.

10. The system of claim 9 , further comprising an adsorption bed upstream of the oxidative dehydrogenation reactor, the adsorption bed configured to remove NORM from any fluid entering the oxidative dehydrogenation reactor.

11. The system of claim 9 , further comprising a second filter upstream of the oxidative dehydrogenation reactor, the second filter configured to capture and prevent solid material from entering the oxidative dehydrogenation reactor.

12. The system of claim 9 , further comprising an absorber upstream of the oxidative dehydrogenation reactor, the absorber configured to remove NORM from the feed stream before the feed stream enters the oxidative dehydrogenation reactor.

13. The system of claim 9 , further comprising a solid material receptacle upstream of the oxidative dehydrogenation reactor, the solid material receptacle configured to remove solid material entrained in a fluid before the fluid enters the oxidative dehydrogenation reactor.

14. The system of claim 13 , further comprising an inlet pipe, wherein:
the oxidative dehydrogenation reactor defines an inlet opening coupled to the inlet pipe;
a portion of the inlet pipe is positioned below the inlet opening with respect to gravity; and
the solid material receptacle is coupled to the portion of the inlet pipe that is positioned below the inlet opening.

15. The system of claim 14 , wherein the inlet pipe comprises a baffle configured to direct the solid material to the solid material receptacle.

16. A method, comprising:
flowing a feed stream to an oxidative dehydrogenation reactor, the feed stream comprising oxygen, a hydrocarbon, and a naturally occurring radioactive material (NORM);
reacting at least a portion of the hydrocarbon with the oxygen in the oxidative dehydrogenation reactor to form a dehydrogenated hydrocarbon and water;
discharging an effluent stream from the oxidative dehydrogenation reactor, the effluent stream comprising the dehydrogenated hydrocarbon, water, a remaining unreacted portion of the hydrocarbon, and the NORM;
processing the effluent stream to form a product stream and a recycle stream, the product stream comprising the dehydrogenated hydrocarbon, the recycle stream comprising the remaining unreacted portion of the hydrocarbon with less NORM than the feed stream; and
flowing the recycle stream to the oxidative dehydrogenation reactor.

17. The method of claim 16 , wherein processing the effluent stream comprises:
separating the remaining unreacted portion of the hydrocarbon from a remainder of the effluent stream to form an intermediate stream; and
flowing the intermediate stream through an adsorption bed, wherein the adsorption bed removes NORM from the intermediate stream to form the recycle stream.

18. The method of claim 16 , further comprising flowing a first stream through an adsorption bed to provide the effluent stream, wherein the adsorption bed removes NORM from the first stream.

19. The method of claim 16 , wherein processing the effluent stream comprises:
separating the remaining unreacted portion of the hydrocarbon from a remainder of the effluent stream to form an intermediate stream;
storing the intermediate stream in a storage tank for a sufficient time period such that the NORM decays into a so

Assignees

• Nova Chemicals International Sa

Inventors

• Simanzhenkov Vasily
• Olayiwola Bolaji
• Goodarznia Shahin

Classifications

• C07C7/12

  by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers · CPC title

• C07C7/11

  by absorption, i.e. purification or separation of gaseous hydrocarbons with the aid of liquids · CPC title

• B01J2219/0004

  Processes in series · CPC title

• B01J19/245

  placed in series · CPC title

• B01D2257/93

  Toxic compounds not provided for in groups B01D2257/00 - B01D2257/708 · CPC title