Three-dimensional printing with detector solutions

Patent metadata

Field	Value
Publication number	US-12240169-B2
Application number	US-201917777802-A
Country	US
Kind code	B2
Filing date	Dec 13, 2019
Priority date	Dec 13, 2019
Publication date	Mar 4, 2025
Grant date	Mar 4, 2025

Abstract

This disclosure describes multi-fluid kits for three-dimensional printing, three-dimensional printing kits, and methods of testing powder bed material for contamination. In one example, a multi-fluid kit for three-dimensional printing can include a fusing agent and a detector solution. The fusing agent can include water, an electromagnetic radiation absorber, and a first pigment reactant. The electromagnetic radiation absorber can absorb radiation energy and convert the radiation energy to heat. The detector solution can include water and a second pigment reactant. The second pigment reactant can be reactive with the first pigment reactant to form a colored pigment.

First claim

What is claimed is:

1. A method of testing powder bed material for contamination, the method comprising:
printing a three-dimensional printed object using a process that includes applying a fusing agent to a powder bed material to form the three-dimensional object from a portion of the powder bed material while leaving a leftover portion of the powder bed material, wherein the powder bed material comprises polymer particles and wherein the fusing agent comprises a first pigment reactant; and
determining whether the leftover portion of the powder bed material is contaminated with the fusing agent by contacting a sample of the leftover portion of the powder bed material with a detector solution comprising water and a second pigment reactant, wherein the second pigment reactant is reactive with the first pigment reactant to form a colored pigment indicating contamination of the sample with the fusing agent.

2. The method of claim 1 , further comprising:
contacting the detector solution with multiple samples of the leftover portion of the powder bed material contaminated with known amounts of the first pigment reactant;
so as to generate different color intensities formed from the known amounts of the first pigment reactant in the multiple samples; and
generating a correlation curve by correlating the color intensities with the known amounts of the first pigment reactant.

3. The method of claim 1 , further comprising:
observing the sample contacted with the detector solution to determine a color intensity of the detector solution; and
either:
discarding a remainder of the leftover powder bed material if the color intensity is at or above a threshold color intensity; or
recycling the leftover powder bed material for forming an additional three-dimensional printed object if the color intensity is below the threshold color intensity.

4. The method of claim 1 , wherein the first pigment reactant is NH 4 Fe(SO 4 ) 2 ·12 H 2 O and the second pigment reactant is K 4 [Fe(CN) 6 ].

5. The method of claim 1 , wherein the fusing agent further comprises water and an electromagnetic radiation absorber.

6. The method of claim 1 , wherein at least one of the first pigment reactant and the second pigment reactant includes a metal salt.

7. The method of claim 6 , wherein the metal salt is selected from the group consisting of NH 4 Fe(SO 4 ) 2 ·12 H 2 O, (NH 4 ) 2 Fe(SO 4 ) 2 ·6H 2 O, FeSO 4 , NaOH, Na 2 SO 4 , BaCl 2 , CuSO 4 , NaHCO 3 , Na 2 CO 3 , Na 2 CrO 4 , K 2 CrO 4 , ZnSO 4 , ZnCl 2 , K 3 [Fe(CN) 6 ], K 4 [Fe(CN) 6 ], and a combination thereof.

8. The method of claim 1 , wherein the first pigment reactant is present in the fusing agent in an amount ranging from about 0.01 wt % to about 2 wt %.

9. The method of claim 1 , wherein the fusing agent is colorless.

10. The method of claim 1 , wherein the fusing agent is a low tint fusing agent.

11. The method of claim 1 , wherein the printing further includes applying a detailing agent to the powder bed material, wherein the detailing agent includes the first pigment reactant.

12. The method of claim 11 , wherein the applying of the detailing agent is accomplished utilizing an inkjet printhead.

13. The method of claim 1 , wherein the polymer particles are selected from the group consisting of polyamide 6 particles, polyamide 9 particles, polyamide 11 particles, polyamide 12 particles, polyamide 66 particles, polyamide 612 particles, polyamide copolymer particles, polyethylene particles, thermoplastic polyurethane particles, polypropylene particles, polyester particles, polycarbonate particles, polyether ketone particles, polyacrylate particles, polystyrene particles, polyvinylidene fluoride particles, poly(vinylidene fluoride-trifluoroethylene) particles, poly(vinylidene fluoride-trifluoroethylene-chlorotrifluoroethylene) particles, wax particles, and a combination thereof.

14. The method of claim 1 , wherein the applying of the fusing agent is accomplished utilizing an inkjet printhead.

Assignees

• Hewlett Packard Development Co

Inventors

• Discekici Emre Hiro
• Negri Jimenez Graciela Emma
• Woodruff Shannon Reuben
• Yemane Alay
• Wright Jacob

Classifications

• B29C64/188

  involving additional operations performed on the added layers, e.g. smoothing, grinding or thickness control (surface shaping B29C59/00; after-treatment of articles without altering their shape B29C71/00) · CPC title

• B29C64/30

  Auxiliary operations or equipment · CPC title

• G01N21/94

  Investigating contamination, e.g. dust (G01N21/85 takes precedence) · CPC title

• G01N21/91

  using penetration of dyes, e.g. fluorescent ink · CPC title

• G01N21/78

  producing a change of colour · CPC title