Systems and methods for nanofunctionalization of powders

Patent metadata

Field	Value
Publication number	US-12239967-B2
Application number	US-202318243182-A
Country	US
Kind code	B2
Filing date	Sep 7, 2023
Priority date	Feb 1, 2017
Publication date	Mar 4, 2025
Grant date	Mar 4, 2025

Abstract

Some variations provide a system for producing a functionalized powder, comprising: an agitated pressure vessel; first particles and second particles contained within the agitated pressure vessel; a fluid contained within the agitated pressure vessel; an exhaust line for releasing the fluid from the agitated pressure vessel; and a means for recovering a functionalized powder containing the second particles disposed onto surfaces of the first particles. A preferred fluid is carbon dioxide in liquefied or supercritical form. The carbon dioxide may be initially loaded into the pressure vessel as solid carbon dioxide. The pressure vessel may be batch or continuous and is operated under reaction conditions to functionalize the first particles with the second particles, thereby producing a functionalized powder, such as nanofunctionalized metal particles in which nanoparticles act as grain refiners for a component ultimately produced from the nanofunctionalized metal particles. Methods for making the functionalized powder are also disclosed.

First claim

What is claimed is:

1. A system for producing a functionalized powder, said system comprising:
(a) an agitated pressure vessel under an inert atmosphere and at a vessel pressure greater than atmospheric pressure;
(b) a thermal-control unit disposed in thermal communication with said agitated pressure vessel;
(c) a plurality of first particles contained within said agitated pressure vessel;
(d) a plurality of second particles contained within said agitated pressure vessel, wherein said second particles are compositionally different than said first particles, and wherein said second particles are selected from the group consisting of zirconium hydrides, tantalum hydrides, niobium hydrides, titanium hydrides, and combinations thereof;
(e) a fluid contained within said agitated pressure vessel;
(f) an exhaust line for releasing said fluid from said agitated pressure vessel; and
(g) a means for recovering a functionalized powder directly from said agitated pressure vessel, wherein said functionalized powder contains said second particles disposed onto surfaces of said first particles,
wherein said first particles have an average first-particle size from about 1 micron to about 1 millimeter; and
wherein said second particles have an average second-particle size from about 1 nanometer to about 5000 nanometers.

2. The system of claim 1 , wherein said fluid is non-flammable.

3. The system of claim 1 , wherein said fluid is a liquid.

4. The system of claim 1 , wherein said fluid is a gas.

5. The system of claim 1 , wherein said fluid is selected from the group consisting of carbon dioxide, nitrous oxide, C 1 -C 4 hydrocarbons, C 1 -C 4 oxygenates, and combinations thereof.

6. The system of claim 5 , wherein said fluid includes carbon dioxide in a vapor state and/or a liquid state within said agitated pressure vessel.

7. The system of claim 5 , wherein said fluid includes carbon dioxide in a supercritical state within said agitated pressure vessel.

8. The system of claim 5 , wherein said system comprises a means for introducing solid carbon dioxide into said agitated pressure vessel.

9. The system of claim 1 , wherein said exhaust line includes a filter to capture said first particles, said second particles, and/or said functionalized powder.

10. The system of claim 1 , said system further comprising a safety release line that is activated when the pressure within said agitated pressure vessel reaches a predetermined pressure.

11. The system of claim 1 , said system further comprising a separate container disposed in flow communication with said exhaust line, for receiving fluid released from said agitated pressure vessel.

12. The system of claim 1 , said system further comprising a control subsystem for adjusting temperature, pressure, residence time, and/or agitation within said agitated pressure vessel.

13. The system of claim 1 , wherein said system is a batch apparatus.

14. The system of claim 1 , wherein said system is a continuous or semi-continuous apparatus.

15. The system of claim 1 , wherein said first particles are selected from the group consisting of metal particles, intermetallic particles, ceramic particles, and combinations thereof.

16. The system of claim 1 , wherein said first particles contain one or more metals selected from the group consisting of aluminum, iron, nickel, copper, titanium, magnesium, zinc, silicon, lithium, silver, chromium, manganese, vanadium, bismuth, gallium, lead, and combinations thereof.

17. The system of claim 1 , wherein said second particles are selected from the group consisting of metal particles, intermetallic particles, ceramic particles, and combinations thereof.

18. The system of claim 1 , wherein said second particles contain one or more elements selected from the group consisting of zirconium, tantalum, niobium, titanium, and oxides, nitrides, hydrides, carbides, or borides thereof, and combinations of the foregoing.

19. The system of claim 1 , wherein said agitated pressure vessel is disposed within an outer container.

Assignees

• Hrl Lab Llc

Inventors

• Martin John H
• Yahata Brennan D
• Mone Robert

Classifications

• B22F1/056

  Submicron particles having a size above 100 nm up to 300 nm · CPC title

• B22F1/18

  Non-metallic particles coated with metal · CPC title

• B01F35/22161

  duration of the mixing process or parts of it · CPC title

• B01F35/7543

  using pneumatic pressure, overpressure or gas pressure in a closed receptacle or circuit system · CPC title

• B01F35/2215

  Temperature · CPC title