Process for the production of a zeolitic material having an AEI-type framework structure via solvent-free interzeolitic conversion

Patent metadata

Field	Value
Publication number	US-12239965-B2
Application number	US-201917309182-A
Country	US
Kind code	B2
Filing date	Nov 15, 2019
Priority date	Nov 16, 2018
Publication date	Mar 4, 2025
Grant date	Mar 4, 2025

Abstract

The present disclosure relates to a process preparating a zeolitic material having an AEI-type framework structure, wherein the framework structure comprises SiO2 and X2O3 and X is a trivalent element, and wherein the process comprises:(1) preparing a mixture comprising one or more cationic structure directing agents comprising a heterocyclic amine ring, seed crystals, and a first zeolitic material comprising SiO2 and X2O3 in its framework structure and having an FAU-type framework structure; and(2) heating the mixture to obtain a second zeolitic material comprising SiO2 and X2O3 in its framework structure and having an AEI-type framework structure.

First claim

The invention claimed is:

1. A process for preparing a zeolite material having an AEI-framework structure wherein the framework structure comprises SiO 2 and X 2 O 3 and X is a trivalent element, and wherein the process comprises:
(1) preparing a mixture comprising one or more cationic structure directing agent comprising a heterocyclic amine ring, seed crystals, and a first zeolite material comprising SiO 2 and X 2 O 3 in the framework structure and having an FAU framework structure, wherein (1) comprises milling the mixture; and
(2) heating the mixture to obtain a second zeolite material comprising SiO 2 and X 2 O 3 in its framework structure and having the AEI framework structure;
wherein the mixture prepared in (1) and heated in (2) contains 1000 wt.-% or less of H 2 O based on 100 wt.-% of SiO 2 in the framework structure of the first zeolite material,
wherein the mixture prepared in (1) and heated in (2) further comprises at least one OH source, and an OH − :SiO 2 molar ratio of OH − to SiO 2 in the framework structure of the first zeolite material is in a range from 0.3 to 0.4,
wherein the one or more cationic structure directing agents are chosen from N,N-di(C 1 -C 4 )alkyl-3,5-di(C 1 -C 4 )alkylpyrrolidinium, N,N-di(C 1 -C 4 )alkyl-3,5-di(C 1 -C 4 )alkylpiperidinium, N,N-di(C 1 -C 4 )alkyl-3,5-di(C 1 -C 4 )alkylhexahydroazepinium, and combinations thereof, and
wherein a molar ratio of trans isomer to cis isomer in the one or more cationic structure directing agents relative to alkyl groups at 3 and 5 positions of the heterocyclic amine ring ranges from 0.01 to 0.3,
Wherein X is chosen from Al, B, In, Ga and combinations thereof.

2. The process of claim 1 , wherein the heating in (2) is conducted at a temperature ranging from 80° C. to 250° C.

3. The process of claim 1 , wherein the heating in (2) is conducted under autogenous pressure.

4. The process of claim 1 , further comprising calcining the second zeolite material.

5. The process of claim 1 , further comprising ion-exchanging the second zeolite material.

6. The process of claim 5 , wherein at least one ionic extra-framework element contained in the zeolite framework is ion-exchanged against one or more cations chosen from Sr, Zr, Cr, Mg, Mo, Fe, Co, Ni, Cu, Zn, Ru, Rh, Pd, Ag, Os, Ir, Pt, Au, and combinations thereof.

7. The process of claim 1 , wherein primary crystals of the zeolitic material have a mean aspect ratio greater than 3.6.

Assignees

• Basf Se

Inventors

• Parvulescu Andrei-Nicolae
• Dai Yu
• Maurer Stefan
• Mueller Ulrich
• Thiel Indre

Classifications

• B01J35/40

  characterised by dimensions, e.g. grain size (in a colloidal state B01J35/23; crystallite size B01J35/77) · CPC title

• B01J35/617 Primary

  500-1000 m2/g · CPC title

• C01P2004/03

  obtained by SEM · CPC title

• C01B39/48

  using at least one organic template directing agent · CPC title

• B01J2229/18

  to introduce other elements into or onto the molecular sieve itself · CPC title