Light-emitting element, light-emitting device, electronic device, and lighting device

Patent metadata

Field	Value
Publication number	US-12239010-B2
Application number	US-202017101101-A
Country	US
Kind code	B2
Filing date	Nov 23, 2020
Priority date	Apr 1, 2016
Publication date	Feb 25, 2025
Grant date	Feb 25, 2025

Abstract

A novel organometallic complex with high reliability is provided. A light-emitting element includes an EL layer between a pair of electrodes. The EL layer includes at least a light-emitting layer. The light-emitting layer contains an organometallic complex. The organometallic complex includes a first ligand and a second ligand which are coordinated to a central metal. The HOMO is distributed over the first ligand, and the LUMO is distributed over the second ligand. The first ligand and the second ligand are cyclometalated ligands.

First claim

The invention claimed is:

1. A light-emitting device comprising:
a light-emitting layer comprising a first organic compound, a second organic compound, and an organometallic complex having a structure represented by General Formula (G1):

wherein R 1 to R 5 and R 7 to R 12 , R 14 , and R 15 separately represent hydrogen, an alkyl group having 1 to 6 carbon atoms, an unsubstituted aryl group having 6 to 13 carbon atoms, or an unsubstituted heteroaryl group having 3 to 12 carbon atoms,
wherein R 13 represents a methyl group,
wherein R 6 represents a tert-butyl group, and
wherein light emission of the organometallic complex is yellow.

2. The light-emitting device according to claim 1 , wherein the structure is represented by (102):

3. The light-emitting device according to claim 1 , wherein the first organic compound and the second organic compound form an exciplex.

4. The light-emitting device according to claim 1 ,
wherein the first organic compound is a π-electron deficient heteroaromatic compound, and
wherein the second organic compound is a π-electron rich heteroaromatic compound or an aromatic amine compound.

5. A light-emitting device comprising:
a light-emitting layer comprising a first organic compound, a second organic compound, and an organometallic complex,
wherein the organometallic complex comprises a first ligand comprising a phenylpyridine ligand and a second ligand comprising a ligand of a phenylpyrimidine derivative represented by General Formula (G1):

wherein R 1 to R 5 and R 7 to R 12 , R 14 , and R 15 separately represent hydrogen, an alkyl group having 1 to 6 carbon atoms, an unsubstituted aryl group having 6 to 13 carbon atoms, or an unsubstituted heteroaryl group having 3 to 12 carbon atoms,
wherein R 13 represents a methyl group,
wherein R 6 represents a tert-butyl group,
wherein a HOMO is distributed over the first ligand, and
wherein a LUMO is distributed over the second ligand.

6. The light-emitting device according to claim 5 , wherein the organometallic complex is represented by (102):

7. The light-emitting device according to claim 5 , wherein the first organic compound and the second organic compound form an exciplex.

8. The light-emitting device according to claim 5 , wherein light emission of the organometallic complex is yellow.

9. The light-emitting device according to claim 5 ,
wherein the first organic compound is a π-electron deficient heteroaromatic compound, and
wherein the second organic compound is a π-electron rich heteroaromatic compound or an aromatic amine compound.

10. A light-emitting device comprising:
a light-emitting layer comprising a first organic compound, a second organic compound, and an organometallic complex having a structure represented by General Formula (G1):

wherein R 1 to R 5 and R 7 to R 15 separately represent hydrogen, an alkyl group having 1 to 6 carbon atoms, an unsubstituted aryl group having 6 to 13 carbon atoms, or an unsubstituted heteroaryl group having 3 to 12 carbon atoms,
wherein R 13 or R 14 represents a phenyl group,
wherein R 6 represents a tert-butyl group, and
wherein light emission of the organometallic complex is yellow.

11. The light-emitting device according to claim 10 , wherein the structure is represented by (102) or (117):

12. The light-emitting device according to claim 10 , wherein the first organic compound and the second organic compound form an exciplex.

13. The light-emitting device according to claim 10 ,
wherein the first organic compound is a π-electron deficient heteroaromatic compound, and
wherein the second organic compound is a π-electron rich heteroaromatic compound or an aromatic amine compound.

14. An organometallic complex having a structure represented by General Formula (G1):

wherein R 1 to R 5 and R 7 to R 12 , R 14 , and R 15 separately represent hydrogen, an alkyl group having 1 to 6 carbon atoms, an unsubstituted aryl group having6 to 13 carbon atoms, or an unsubstituted heteroaryl group having 3 to 12 carbon atoms,
wherein R13 represents a methyl group, and
wherein R6 represents a tert-butyl group.

15. The organometallic complex according to claim 14 , wherein the structure is represented by (102):

Assignees

• Semiconductor Energy Lab

Inventors

• Seo Satoshi
• Inoue Hideko
• Kurihara Miki
• Yamada Yui
• Takahashi Tatsuyoshi
• Kido Hiromitsu

Classifications

• C09K2211/185

  of the platinum group, i.e. Os, Ir, Pt, Ru, Rh or Pd · CPC title

• C09K2211/1059

  containing three nitrogen atoms as heteroatoms · CPC title

• C09K2211/1044

  containing two nitrogen atoms as heteroatoms · CPC title

• C09K2211/1007

  Non-condensed systems · CPC title

• C09K11/06

  containing organic luminescent materials · CPC title