Battery with shear thickening, impact resistant electrolytes

Patent metadata

Field	Value
Publication number	US-12237469-B2
Application number	US-202318383268-A
Country	US
Kind code	B2
Filing date	Oct 24, 2023
Priority date	Apr 20, 2018
Publication date	Feb 25, 2025
Grant date	Feb 25, 2025

Abstract

A battery includes an anode, a cathode, and a porous separator having a surface and percolating pores providing a porosity of from 20% to 80%. A passively impact resistant composite electrolyte includes an electrolyte and electrically non-conducting particles that enable shear thickening. The particles can have a polydispersity index of no greater than 0.1, an average particle size in a range of from 50 nm to 1 μm, and an absolute zeta potential of greater than ±40 mV. The shear thickening enabling particles can be from 10 wt. % to 40 wt. % of the total weight of the separator and shear thickening particles. Between 20-40 wt. % of the shear thickening enabling particles are located in the pores of the separator.

First claim

We claim:

1. An assembly, comprising:
a porous material having a surface and pores, the pores having an average pore diameter;

and
shear thickening particles having an average particle size of in a range of 50 nm to 1 μm,
the shear thickening particles being distributed at the surface and/or within the pores of the porous material, and
the shear thickening particles having an average hydrocluster diameter less than or equal to the average pore diameter.

2. The assembly of claim 1 , wherein the porous material has a porosity between about 20% to about 80% by volume of the porous material.

3. The assembly of claim 1 , wherein the porous material is a separator.

4. The assembly of claim 1 , wherein the shear thickening particles have a polydispersity index of no greater than 0.1.

5. The assembly of claim 1 , wherein the average pore diameter is from 1 to 100 times the size of the average hydrocluster diameter.

6. The assembly of claim 1 , wherein the shear thickening particles comprise from 10 wt. % to 40 wt. % of the total weight of the separator and shear thickening particles.

7. The assembly of claim 1 , wherein less than about 40 wt. % of the shear thickening particles are located at least partially in the pores of the porous material.

8. The assembly of claim 1 , further comprising:
a particle suspension agent selected from at least one of stabilization polymers covalently bound to the surface of the shear thickening particles or a stabilizing surfactant.

9. The assembly of claim 8 , wherein the shear thickening particles have an electrochemical double layer, and the particle suspension agent has a chain length of greater than double the thickness of the electrochemical double layer.

10. The assembly of claim 8 , wherein the particle suspension agent comprises a stabilizing surfactant, the stabilizing surfactant comprising a first portion for adsorbing to the particles, and a second portion that is dispersed in a solvent, the length of the surfactant from the first portion to the second portion being greater than twice the thickness of the electrochemical double layer.

11. The assembly of claim 1 , further comprising: an electrolyte.

12. The assembly of claim 11 , wherein the shear thickening particles comprise between about 10 wt. % to about 40 wt. % based on the total weight of the shear thickening particles and the electrolyte.

13. The assembly of claim 1 , further comprising:
an electrolyte salt selected from at least one of lithium hexafluorophosphate, lithium triflate, lithium perchlorate, lithium tetrafluoro borate lithium hexafluoro lithium arsenate, lithium bis(trifluoro methane sulphone)imide, lithium bis(oxalate) borate, sodium perchlorate, sodium tetrafluoro borate sodium hexafluoro arsenate, sodium bis(trifluoromethane sulphone)imide, sodium bis(oxalate) borate, sodium hexafluorophosphate or sodium triflate.

14. An assembly, comprising:
a porous material having a surface, pores, and a porosity between about 20% to about 80% by volume, the pores having an average pore diameter; and
shear thickening particles having a polydispersity index of no greater than 0.1 and an average particle size of in a range of 50 nm to 1 μm,
the shear thickening particles being distributed at the surface and/or within the pores of the porous material, and
the shear thickening particles having an average hydrocluster diameter less than or equal to the average pore diameter.

15. The assembly of claim 14 , wherein the porous material has a porosity between about 20% to about 40% by volume of the porous material.

16. The assembly of claim 14 , wherein the porous material is a separator.

17. The assembly of claim 14 , wherein the average pore diameter is from 1 to 100 times the size of the average hydrocluster diameter.

18. The assembly of claim 14 , further comprising: an electrolyte.

Assignees

• Ut Battelle Llc

Inventors

• Armstrong Beth L
• Veith Gabriel M
• Kalnaus Sergiy
• Wang Hsin
• Browning Katie L
• Cooley Kevin M

Classifications

• H01M50/431

  Inorganic material · CPC title

• H01M50/443

  Particulate material · CPC title

• H01M50/491

  Porosity · CPC title

• H01M10/0568 Primary

  characterised by the solutes · CPC title

• H01M2300/0094

  in the form of layered products, e.g. coatings · CPC title