Continuous separation of radionuclides by shock electrodialysis

Patent metadata

Field	Value
Publication number	US-12237091-B2
Application number	US-202017105942-A
Country	US
Kind code	B2
Filing date	Nov 27, 2020
Priority date	Nov 27, 2019
Publication date	Feb 25, 2025
Grant date	Feb 25, 2025

Abstract

Radioactive nuclides (radionuclides) are separate from an aqueous radioactive liquid by feeding the liquid into a chamber between a porous anode and a porous cathode of a shock electrodialysis device. Meanwhile, an anolyte is fed through the porous anode, and a catholyte is fed through the porous cathode. A voltage is applied to the porous anode and to the porous cathode to create a voltage differential across the chamber. The liquid is passed through the chamber, and cations are selectively driven from the liquid into the cathode by the voltage differential. The voltage differential creates a desalination shock that produces an ion-enriched zone on one side of the desalination shock and a deionized zone on an opposite side. A brine including the radioactive cations is extracted from the ion-enriched zone through a brine outlet, and fresh water is extracted from the deionized zone through a fresh-water outlet.

First claim

What is claimed is:

1. A system for separating radioactive nuclides, the system comprising:
a source of an aqueous radioactive liquid including radioactive nuclides, including cobalt (2+) ions and monovalent cations, wherein the aqueous radioactive liquid has a total salt concentration of less than 0.1 mM;
a feed conduit for liquid flow from the source of aqueous radioactive liquid;
a shock electrodialysis device configured to receive the aqueous radioactive liquid from the feed conduit and including:
a chamber including:
respective inlets for:
the aqueous radioactive liquid, wherein the inlet for the radioactive liquid is in fluid communication with the feed conduit from the source;
an anolyte; and
a catholyte; and

respective outlets for:
purified water;
a brine that includes the radioactive nuclides;
the anolyte; and
the catholyte;

a porous anode contained in the chamber and configured for flow of the anolyte therethrough;
a porous cathode contained in the chamber and configured for flow of the catholyte therethrough;
at least two of the following functioning as ion separators:
an ion-selective boundary;
the anode being configured for ion separation; and
the cathode being configured for ion separation,

wherein the ion separators are configured to selectively pass at least some cations, wherein a channel for flow of the aqueous radioactive liquid from the feed conduit is defined between the ion separators, and wherein the anode and the cathode are configured to drive ionic current in the aqueous radioactive liquid across the channel when the aqueous radioactive liquid fills the channel, and wherein the ion separator is configured to conduct the ionic current; and
a cationic porous medium between the ion-selective boundaries in the channel, wherein the cationic porous medium has a positive surface charge to promote flow of the ionic current across the channel and production of a desalination shock with a region of purified water on one side of the desalination shock and a brine that includes the radioactive nuclides from the aqueous radioactive liquid on an opposite side of the desalination shock and to selectively concentrate the cobalt (2+) ions over monovalent cations in the brine.

2. The system of claim 1 , further comprising a splitter positioned to separate (a) flow of the purified water to the outlet for the purified water and (b) flow of the brine to the outlet for the brine.

3. The system of claim 1 , wherein the source of the radioactive aqueous liquid is a nuclear reactor.

4. The system of claim 1 , wherein the radioactive aqueous liquid comprises cobalt and cesium.

5. The system of claim 1 , wherein the radioactive aqueous liquid further comprises boric acid and lithium.

6. The system of claim 1 , wherein the ion separators comprise a pair of the ion-selective boundaries.

7. The system of claim 6 , wherein the ion separators are ion-selective cation exchange membranes.

8. The system of claim 1 , further comprising a voltage source electrically coupled with the anode and the cathode.

9. The system of claim 1 , further comprising:
a first capacitive deionization unit with an inlet configured to receive the brine from the shock electrodialysis device;
a second capacitive deionization unit with an inlet configured to receive the purified water from the shock electrodialysis device.

10. The system of claim 9 , wherein each capacitive deionization unit comprises:
a first electrode capable of intercalating and deintercalating Li+ ions;
a porous second electrode;
a pair of membranes between the first electrode and the porous second electrode, wherein a channel for fluid flow is defined between the membranes.

11. A method for separating radioactive nuclides, comprising:
using the system for separating radioactive nuclides of claim 1 ;
feeding the aqueous radioactive liquid including radioactive nuclides into the chamber between the porous anode and the porous cathode of the shock electrodialysis device;
feeding the anolyte through the porous anode;
feeding the catholyte through the porous cathode;
applying a voltage to the porous anode and to the porous cathode to create a voltage differential across the chamber;
passing the aqueous radioactive liquid through the chamber and selectively driving cations from the aqueous radioactive liquid into the porous cathode via the creation of the voltage differential;
creating the desalination shock in the aqueous radioactive liquid via the creation of the voltage differential, the desalination shock producing an ion-enriched zone on one side of the desalination shock and a deionized zone on an opposite side of the desalination shock and selectively concentrating the cobalt (2+) ions over the monovalent cations in the brine;
extracting a brine including the radioactive cations from the ion-enriched zone through a brine outlet; and
extracting purified water from the deionized zone through a purified-water outlet.

12. The method of claim 11 , further comprising generating the aqueous radioactive liquid in a nuclear reactor.

13. The method of claim 11 , wherein a pair of ion-selective boundaries are positioned between the porous anode and the porous cathode and define the chamber therebetween.

14. The method of claim 13 , wherein the ion-selective boundaries are ion-selective cationic membranes.

15. The method of claim 11 , further comprising:
passing the brine through a first capacitive deionization unit; and
passing the purified water through a second capacitive deionization unit.

16. The method of claim 15 , further comprising:
applying a voltage to a first electrode in the first capacitive deionization unit to intercalate lithium ions from the brine into the first electrode;
applying a voltage to a porous second electrode in the first capacitive deionization unit to extract anions from the brine into the porous second electrode;
applying a voltage to a first electrode in the second capacitive deionization unit to deintercalate lithium ions from the first electrode into the purified water; and
applying a voltage to a porous second electrode in the second capacitive deionization unit to extract anions from the porous second electrode into the purified water.

17. The system for separating radioactive nuclides of claim 1 , wherein the aqueous radioactive liquid is a serially diluted solution.

Assignees

• Massachusetts Inst Technology

Inventors

• Conforti Kameron
• Alkhadra Mohammad Ayman
• Gao Tao
• Tian Huanhuan
• Bazant Martin Z

Classifications

• B01D61/4281

  comprising multiple membrane capacitive deionization steps · CPC title

• B01D61/461

  comprising only a single cell, only one anion or cation exchange membrane or one pair of anion and cation membranes · CPC title

• B01D2311/2684

  Electrochemical processes · CPC title

• B01D2311/06

  Specific process operations in the permeate stream · CPC title

• B01D2311/08

  Specific process operations in the concentrate stream · CPC title