Foaming and shaping process for a thermoplastic sheet, and associated apparatus and shaped foamed thermoplastic sheet

Patent metadata

Field	Value
Publication number	US-12233579-B2
Application number	US-202218290420-A
Country	US
Kind code	B2
Filing date	May 27, 2022
Priority date	Jul 9, 2021
Publication date	Feb 25, 2025
Grant date	Feb 25, 2025

Abstract

A method of foaming and shaping a thermoplastic sheet comprising a poly(phenylene ether), a polyetherimide, or a combination thereof includes foaming the thermoplastic sheet with supercritical carbon dioxide to form a foamed thermoplastic sheet, and shaping the foamed thermoplastic sheet to form a shaped foamed thermoplastic sheet. The shaping step includes compressing the foamed thermoplastic sheet between a first metal plate and a secondi metal plate, each of which has a grooved surface facing the thermoplastic sheet. The first metal plate and the second metal plate are connected by a flexible, compressible linkage capable. When the flexible, compressible linkage is in its uncompressed state, only the second (lower) metal plate is in contact with the shaped foamed thermoplastic sheet. When the flexible, compressible linkage is in its compressed state, both the first (upper) and second (lower) metal plates are in contact with the shaped foamed thermoplastic sheet.

First claim

The invention claimed is:

1. A method of foaming and shaping a thermoplastic sheet, comprising:
foaming a thermoplastic sheet with supercritical carbon dioxide to form a foamed thermoplastic sheet; wherein the thermoplastic sheet comprises a thermoplastic composition comprising a poly (phenylene ether), a polyetherimide, or a combination thereof; and wherein the thermoplastic composition is characterized by a glass transition temperature of 20 to 300° C. determined by differential scanning calorimetry according to ASTM D3418-15 at heating rate of 20° C./minute; and
shaping the foamed thermoplastic sheet to form a shaped foamed thermoplastic sheet; wherein the shaping comprises compressing the foamed thermoplastic sheet between a first metal plate and a second metal plate; wherein a surface of the first metal plate and a surface of the second metal plate comprise a plurality of grooves, each groove having a width of 0.1 to 1 millimeter and a depth of 0.1 to 1 millimeter, and each groove being separated from the nearest groove by a center-to-center distance of 0.5 to 5 millimeters; wherein the first metal plate and the second metal plate are connected by a flexible linkage capable of modulating a separation between the first metal plate and the second metal plate; and wherein the compressing the foamed thermoplastic sheet between a first metal plate and a second metal plate comprises controlling a minimum separation of the first metal plate and the second metal plate.

2. The method of claim 1 , wherein the flexible linkage comprises a metal wire, a metal band, poly (para-phenylene terephthalamide) fibers, carbon fibers, glass fibers, or a combination thereof.

3. The method of claim 1 , wherein the flexible linkage comprises a metal wire or a metal band comprising galvanized iron, wherein the galvanized iron comprises 99.9 to 99.99 weight percent iron and 0.01 to 0.1 weight percent carbon, based on the weight of galvanized iron.

4. The method of claim 1 , wherein the thermoplastic composition comprises a poly (phenylene ether).

5. The method of claim 4 , wherein the thermoplastic composition has a glass transition temperature of 100 to 300° C. and comprises, based on the total weight of the thermoplastic composition, 40 to 78 weight percent of the poly (phenylene ether); 10 to 48 weight percent of polystyrene, a rubber-modified polystyrene, or a combination thereof; 2 to 10 weight percent of a block copolymer comprising a polystyrene block and a polybutadiene block, a block copolymer comprising a polystyrene block and a hydrogenated polybutadiene block, or a combination thereof; and 10 to 20 weight percent of a flame retardant; wherein the sum of the weight percents of the poly (phenylene ether), the polystyrene or rubber-modified polystyrene or combination thereof, the block copolymer, and the flame retardant is 95 to 100 weight percent.

6. The method of claim 4 , wherein the thermoplastic composition has a glass transition temperature of 100 to 300° C. and comprises, based on the total weight of the thermoplastic composition, 50 to 78 weight percent of the poly (phenylene ether); 10 to 38 weight percent of polystyrene, a rubber-modified polystyrene, or a combination thereof; 2 to 10 weight percent of a block copolymer comprising a polystyrene block and a polybutadiene block, a block copolymer comprising a polystyrene block and a hydrogenated polybutadiene block, or a combination thereof; and 10 to 20 weight percent of a flame retardant; wherein the sum of the weight percents of the poly (phenylene ether), the polystyrene or rubber-modified polystyrene or combination thereof, the block copolymer, and the flame retardant is 95 to 100 weight percent.

7. The method of claim 1 , wherein the thermoplastic composition comprises a polyetherimide.

8. A shaped foamed thermoplastic sheet produced by the method of claim 1 and comprising a plurality of projections corresponding to the plurality of grooves of the first metal plate and the second metal plate.

9. The shaped foamed thermoplastic sheet of claim 8 , wherein the thermoplastic composition comprises a poly (phenylene ether).

10. The shaped foamed thermoplastic sheet of claim 9 , wherein the thermoplastic composition has a glass transition temperature of 100 to 300° C. and comprises, based on the total weight of the thermoplastic composition, 40 to 78 weight percent of the poly (phenylene ether); 10 to 48 weight percent of polystyrene, a rubber-modified polystyrene, or a combination thereof; 2 to 10 weight percent of a block copolymer comprising a polystyrene block and a polybutadiene block, a block copolymer comprising a polystyrene block and a hydrogenated polybutadiene block, or a combination thereof; and 10 to 20 weight percent of a flame retardant; wherein the sum of the weight percents of the poly (phenylene ether), the polystyrene or rubber-modified polystyrene or combination thereof, the block copolymer, and the flame retardant is 95 to 100 weight percent.

11. The shaped foamed thermoplastic sheet of claim 9 , wherein the thermoplastic composition has a glass transition temperature of 100 to 300° C. and comprises, based on the total weight of the thermoplastic composition, 50 to 78 weight percent of the poly (phenylene ether); 10 to 38 weight percent of polystyrene, a rubber-modified polystyrene, or a combination thereof; 2 to 10 weight percent of a block copolymer comprising a polystyrene block and a polybutadiene block, a block copolymer comprising a polystyrene block and a hydrogenated polybutadiene block, or a combination thereof; and 10 to 20 weight percent of a flame retardant; wherein the sum of the weight percents of the poly (phenylene ether), the polystyrene or rubber-modified polystyrene or combination thereof, the block copolymer, and the flame retardant is 95 to 100 weight percent.

12. The shaped foamed thermoplastic sheet of claim 8 , wherein the thermoplastic composition comprises a polyetherimide.

13. An electric vehicle battery comprising the shaped foamed thermoplastic sheet of claim 8 .

14. An apparatus for shaping a foamed thermoplastic sheet, comprising: a first metal plate and a second metal plate; wherein the foamed thermoplastic sheet comprises a thermoplastic composition is characterized by a glass transition temperature of 20 to 300° C. determined by differential scanning calorimetry according to ASTM D3418-15 at heating rate of 20° C./minute; wherein each of the first metal plate and the second metal plate comprises a thermoplastic-facing major surface; wherein the thermoplastic-facing major surfaces of the first metal plate and the second metal plate comprise a plurality of grooves, each groove having a width of 0.1 to 1 millimeter and a depth of 0.1 to 1 millimeter, and each groove being separated from the nearest groove by a center-to-center distance of 0.5 to 5 millimeters; and wherein the thermoplastic-facing major surface of the first metal plate or the second metal plate or both comprises a rigid spacer to control a minimum separation of the first metal plate and the second metal plate; a flexible linkage connecting the first metal plate and the second metal plate, the flexible linkage being capable of modulating a separation between the first metal plate and the second metal plate; and a hydraulic system capable of compressing the flexible linkage connecting the first metal plate and the second metal plate.

15. The apparatus of claim 14 , wherein the flexible linkage comprises a metal wire, a metal band, poly (para-phenylene terephthalamide) fibers, carbon fibers, glass fibers, or a combination thereof.

Assignees

• Shpp Global Tech Bv

Inventors

• Hou Bruce
• Liu Chao
• Zheng Liping

Classifications

• B29K2071/12

  PPO, i.e. polyphenylene oxide; PPE, i.e. polyphenylene ether · CPC title

• B29K2105/0026

  Flame proofing or flame retarding agents · CPC title

• B29K2995/0012

  having particular thermal properties · CPC title

• B29K2105/04

  cellular or porous · CPC title

• B29K2105/0088

  Blends of polymers · CPC title