Method for producing nickel nanopowder and nickel nanopowder produced using same

Patent metadata

Field	Value
Publication number	US-12233464-B2
Application number	US-202118247735-A
Country	US
Kind code	B2
Filing date	Aug 18, 2021
Priority date	Oct 6, 2020
Publication date	Feb 25, 2025
Grant date	Feb 25, 2025

Abstract

Provided is a method of producing a nickel nanopowder, the method capable of preventing coagulation between particles and, accordingly, providing a nickel nanopowder having a small average particle size and a low coagulation rate. According to an embodiment of the present invention, the method of producing a nickel nanopowder includes providing a nickel salt and a shell-forming material; nucleating and growing nickel core particles from the nickel salt; forming a shell layer on surfaces of the nickel core particles using the shell-forming material; and removing the shell layer to form the nickel nanopowder.

First claim

The invention claimed is:

1. A method of producing a nickel nanopowder, the method comprising:
providing a nickel salt and a shell-forming material;
nucleating and growing nickel core particles from the nickel salt;
forming a shell layer on surfaces of the nickel core particles using the shell-forming material; and
removing the shell layer to form the nickel nanopowder,
wherein, in the forming, a free energy of formation of the shell-forming material is smaller than a free energy of formation of the nickel salt.

2. The method according to claim 1 , wherein the shell layer induces non-sintering-type coagulation of the nickel core particles, and
the non-sintering-type coagulated nickel core particles are individualized as the shell layer is removed, thereby forming the nickel nanopowder.

3. The method according to claim 1 , wherein, in the providing, the shell-forming material is provided in a range of 0.4 mmol/L to 2.5 mmol/L in a molar ratio per the volume of an injection gas.

4. The method according to claim 1 , wherein, in the nucleating and growing, the nickel salt is reduced using a reducing gas, thereby forming the nickel core particles in a solid phase.

5. The method according to claim 1 , wherein, in the forming, a vaporized shell-forming material is precipitated and grown on surfaces of the nickel core particles to form the shell layer.

6. The method according to claim 1 , wherein the forming is performed in an area where temperature decreases according to a direction in which the nickel core particles are transported.

7. The method according to claim 1 , wherein, in the removing, the shell layer is selectively removed through wet post-processing.

8. The method according to claim 1 , wherein the nickel salt comprises at least one of nickel acetate, nickel bromide, nickel carbonate, nickel chloride, nickel fluoride, nickel hydroxide, nickel iodide, nickel nitrate, nickel oxide, nickel phosphate, nickel silicate, nickel sulfate, and nickel sulfide.

9. The method according to claim 1 , wherein the shell-forming material comprises a water-soluble metal salt.

10. The method according to claim 1 , wherein the shell-forming material comprises at least one of aluminum (Al), barium (Ba), calcium (Ca), chromium (Cr), cobalt (Co), copper (Cu), iron (Fe), lead (Pb), lithium (Li), magnesium (Mg)), manganese (Mn), mercury (Hg), nickel (Ni), potassium (K), rubidium (Rb), silver (Ag), sodium (Na), strontium (Sr), tin (Sn), lanthanum (La), silicon (Si), gallium (Ga), scandium (Sc), titanium (Ti), vanadium (V), zirconium (Zr), yttrium (Y), cadmium (Cd), actinium (Ac), cesium (Cs)), hafnium (Hf) and zinc (Zn), or the shell-forming material comprises at least one of metal acetate, metal bromide, metal carbonate, metal chloride, metal fluoride, metal hydroxide, metal iodide, metal nitrate, metal oxide, metal phosphate, metal silicate, metal sulfate, and metal sulfide.

11. A method of producing a metal nanopowder, the method comprising:
providing a metal salt and a shell-forming material;
nucleating and growing metal core particles from the metal salt;
forming a shell layer on the surface of the metal core particles using the shell-forming material; and
removing the shell layer to form the metal nanopowder,
wherein, in the forming, a free energy of formation of the shell-forming material is smaller than a free energy of formation of the metal salt.

Assignees

• Korea Inst Ind Tech

Inventors

• Yang Seung Min
• Moon Geon Dae
• Jeong Young Kyu
• Kwon Ohyung
• Kim Gun Hee
• Kim Kyung Hoon

Classifications

• B22F2999/00

  Aspects linked to processes or compositions used in powder metallurgy · CPC title

• B22F2998/10

  Processes characterised by the sequence of their steps · CPC title

• B22F2304/054

  Particle size between 1 and 100 nm · CPC title

• B22F2302/25

  Oxide · CPC title

• B22F2301/15

  Nickel or cobalt · CPC title