Instant soluble temperature and salt resistant polyacrylamide and the preparation method and application thereof

Patent metadata

Field	Value
Publication number	US-12227696-B2
Application number	US-202318358879-A
Country	US
Kind code	B2
Filing date	Jul 25, 2023
Priority date	Mar 15, 2023
Publication date	Feb 18, 2025
Grant date	Feb 18, 2025

Abstract

The present invention pertains to the field of oilfield stimulation technologies for oil and gas field development, in particular to an instant soluble temperature and salt resistant polyacrylamide and the preparation method and application thereof, and the polyacrylamide is modified by adding rigid temperature and salt resistant monomer containing benzene ring and cationic fluorinated hydrophobic monomer on the basis of acrylamide monomer and sodium acrylate monomer, and then polymerized to obtain instant soluble temperature and salt resistant polyacrylamide. The temperature and salt resistant monomer containing benzene ring can improve the thermal stability and temperature and salt resistance of polyacrylamide, while the long-chain cationic fluorinated hydrophobic monomer can enhance the hydrophobicity of polymer. The comprehensive properties of polymer is improved by appropriate intermolecular association.

First claim

What is claimed is:

1. A method for preparing an instant soluble temperature and salt resistant polyacrylamide, comprising the following steps:
Feed acrylamide monomer, sodium acrylate monomer, a rigid temperature and salt resistant monomer containing a benzene ring, and a cationic fluorinated hydrophobic monomer in a fixed proportion, and add deionized water to prepare a compound monomer aqueous solution with a total monomer mass concentration of 15-35%; adjust the pH value of the compound monomer aqueous solution to 5-10, add into a deoxidizer, then place the solution in a constant temperature water bath, and introduce nitrogen for 5-60 min to obtain a polymeric composite system;
The structural formula of the rigid temperature and salt resistant monomer containing a benzene ring is:

where, R 1 is any of the following three structures:

where R 3 is —COONa or —SO 3 Na;
The structure of the fluorinated cationic hydrophobic monomer is as follows:

where, the structure of R 2 is as follows:

where, R 4 group is

the values of m are from 1 to 4 and the values of n are from 1 to 3;
Add a composite initiator to the polymeric composite system to initiate polymerization and obtain a polymer gel; the composite initiator is composed of an organic transition metal halide and a ligand containing nitrogen and phosphorus; the organic transition metal halide is one or more of cuprous chloride, ferrous chloride and cobalt chloride, and the ligand is one or more of N,N,N′,N′-Tetra (2-pyridylmethyl) ethylenediamine polydentate ligand, 2-bipyridyl, polyethylene polyamine, phthalic acid, succinic acid, and other ligands containing nitrogen and phosphorus;
Take out the polymer gel, then cut, dry and sieve it to obtain the instant soluble temperature and salt resistant polyacrylamide.

2. The method for preparing an instant soluble temperature and salt resistant polyacrylamide according to claim 1 ,
the molar ratio of acrylamide monomer, sodium acrylate monomer, the rigid temperature and salt resistant monomer containing a benzene ring, and the cationic fluorinated hydrophobic monomer is 1:(0.05-0.4):(0.005-0.05):(0.001-0.03);
the deoxidizer is one or more of sodium gluconate, sodium ascorbate, sodium bisulfite and sodium sulfite; the concentration of the deoxidizer is 10 to 200 ppm in the compound monomer aqueous solution;
the pH regulator is one or more of sodium bicarbonate, sodium hydroxide, potassium hydroxide, and glacial acetic acid.

3. The method for preparing an instant soluble temperature and salt resistant polyacrylamide according to claim 1 ,
wherein add the composite initiator to the polymeric site system to initiate polymerization comprises the following steps:
the composite initiator is added to initiate polymerization when the temperature of the complex system reaches the initiation temperature of 30-80° C.;
the polymerization reaction is completed to obtain polymer gel when the temperature rise of the reaction system is not higher than 1° C. within 30 minutes.

4. The method for preparing an instant soluble temperature and salt resistant polyacrylamide according to claim 1 ,
the concentration of the added composite initiator is 100 to 1,500 ppm in the compound monomer aqueous solution, and the mass ratio of the organic transition metal halide to the ligand is 1:1.

5. The method for preparing an instant soluble temperature and salt resistant polyacrylamide according to claim 1 ,
the composite initiator is composed of cobalt chloride and N,N,N′,N′-Tetra (2-pyridylmethyl) ethylenediamine polydentate ligand.

6. The method for preparing an instant soluble temperature and salt resistant polyacrylamide according to claim 1 ,
the synthesis path of the preparation method of the instant soluble temperature and salt resistant polyacrylamide is as follows:

where, the molar ratio of a:b:c:d is 1:(0.05-0.4):(0.005-0.05): (0.001-0.03).

7. The method for preparing an instant soluble temperature and salt resistant polyacrylamide according to claim 1 , wherein a molecular weight of the instant soluble temperature and salt resistant polyacrylamide is 3-15 million.

8. An instant soluble temperature and salt resistant polyacrylamide prepared with the method according to claim 1 , with a structural formula as follows:

Where, the molar ratio of a:b:c:d is 1:(0.05-0.4):(0.005-0.05): (0.001-0.03).

9. The instant soluble temperature and salt resistant polyacrylamide according to claim 8 , the molecular weight of the instant soluble temperature and salt resistant polyacrylamide is 3-15 million.

10. A drag reducer comprises the instant soluble temperature and salt resistant polyacrylamide is prepared according to the method of claim 1 .

Assignees

• Chengdu Leps Tech Co Ltd
• Univ Southwest Petroleum

Inventors

• Guo Jianchun
• Ren Shan
• Lu Cong
• Liu Bin
• Zhang Shaobin
• Mao Huifei
• Diao Su
• Yang Xueshan
• Tang Chaojun
• Ran Junyao
• Yang Guangyao

Classifications

• C09K2208/28

  Friction or drag reducing additives · CPC title

• C09K8/68 Primary

  containing organic compounds · CPC title