Ink composition, window using the same, and manufacturing method of window using the same

Patent metadata

Field	Value
Publication number	US-12227658-B2
Application number	US-202318129121-A
Country	US
Kind code	B2
Filing date	Mar 31, 2023
Priority date	May 2, 2019
Publication date	Feb 18, 2025
Grant date	Feb 18, 2025

Abstract

An ink composition includes an acrylic resin including a polymerization product of a first monomer having a hydroxyl group, a second monomer having an epoxy group, a third monomer having an acrylate group, and a fourth monomer having a substituted or unsubstituted phenyl group, a first curing agent having an isocyanate group, and a second curing agent having an amine group. Durability and abrasion resistance of a window may be improved.

First claim

What is claimed is:

1. A window comprising:
a base substrate comprising a flat area and at least one bent area adjacent the flat area; and
a printed layer disposed on one face of the base substrate and formed with an ink composition,
wherein the ink composition comprises:
an acrylic resin comprising a polymerization product of a first monomer having a hydroxyl group, a second monomer having an epoxy group, a third monomer having an acrylate group, and a fourth monomer having a substituted or unsubstituted phenyl group;
an epoxy resin;
a first curing agent having an isocyanate group; and
a second curing agent having an amine group,
wherein a solid content of the epoxy resin is present in the ink composition in about 12.5 parts by weight to about 25 parts by weight based on 100 parts by weight (solid content) of the acrylic resin.

2. The window of claim 1 , wherein
the first monomer is hydroxypropyl acrylate,
the second monomer is glycidyl methacrylate, glycidyl acrylate, allyl glycidyl ether, or a combination thereof,
the third monomer is methyl methacrylate, and
the fourth monomer is benzyl methacrylate, styrene, t-butyl styrene, or a combination thereof.

3. The window of claim 2 , wherein
the first curing agent comprises two or more isocyanate groups, and
the second curing agent comprises two or more amine groups.

4. The window of claim 1 , comprising, based on 100 moles of the acrylic resin,
from about 10 moles to about 30 moles of the first monomer;
from about 10 moles to about 20 moles of the second monomer;
from about 20 moles to about 35 moles of the third monomer; and
from about 20 moles to about 35 moles of the fourth monomer.

5. The window of claim 1 , wherein the acrylic resin is represented by the following Formula 1:

in Formula 1,
“a”, “c”, and “d” are each independently an integer of 1 to 3,
“b” is 1 or 2,
X is

R 1 and R 2 are each independently hydrogen or a methyl group, and
“n” is an integer of 200 to 400.

6. A manufacturing method of a window, the method comprising:
providing a base substrate comprising a flat area and at least one bent area adjacent the flat area;
printing an ink composition on a face of the base substrate; and
curing the printed ink composition,
wherein the ink composition comprises:
an acrylic resin comprising a polymerization of product of a first monomer having a hydroxyl group, a second monomer having an epoxy group, a third monomer having an acrylate group, and a fourth monomer having a substituted or unsubstituted phenyl group;
an epoxy resin;
a first curing agent having an isocyanate group; and
a second curing agent having an amine group,
wherein a solid content of the epoxy resin is present in the ink composition in about 12.5 parts by weight to about 25 parts by weight based on 100 parts by weight (solid content) of the acrylic resin.

7. The manufacturing method of a window of claim 6 , wherein the ink composition further comprises an epoxy resin.

8. The manufacturing method of a window of claim 6 , wherein
the first monomer is hydroxypropyl acrylate,
the second monomer is glycidyl methacrylate, glycidyl acrylate, allyl glycidyl ether, or a combination thereof,
the third monomer is methyl methacrylate, and
the fourth monomer is benzyl methacrylate, styrene, t-butyl styrene, or a combination thereof.

9. The manufacturing method of a window of claim 6 , wherein the printing is a process of transcribing the ink composition onto the base substrate using a rubber pad with a convex bottom.

10. A window comprising:
a base substrate comprising a flat area and at least one bent area adjacent the flat area; and
a printed layer disposed on one face of the base substrate and formed with an ink composition,
wherein the cured ink composition comprises:
an acrylic resin comprising a polymerization product of a first monomer having a hydroxyl group, a second monomer having an epoxy group, a third monomer having an acrylate group, and a fourth monomer having a substituted or unsubstituted phenyl group;
a first curing agent having an isocyanate group; and
a second curing agent having an amine group,
wherein the ink composition includes: from about 10 moles to about 30 moles of the first monomer; from about 10 moles to about 20 moles of the second monomer; from about 20 moles to about 35 moles of the third monomer; and from about 20 moles to about 35 moles of the fourth monomer.

11. The window of claim 10 , wherein the ink composition further comprises an epoxy resin.

12. The window of claim 10 , wherein
the first monomer is hydroxypropyl acrylate,
the second monomer is glycidyl methacrylate, glycidyl acrylate, allyl glycidyl ether, or a combination thereof,
the third monomer is methyl methacrylate, and
the fourth monomer is benzyl methacrylate, styrene, t-butyl styrene, or a combination thereof.

13. The window of claim 11 , wherein a solid content of the epoxy resin is present in the ink composition in about 12.5 parts by weight to about 25 parts by weight based on 100 parts by weight (solid content) of the acrylic resin.

Assignees

• Samsung Display Co Ltd

Inventors

• Choi Ji Won
• Kim Dongho
• Lee Dongwoon

Classifications

• C03C2218/32

  After-treatment · CPC title

• C03C17/326

  Epoxy resins · CPC title

• B41M7/009

  using thermal means, e.g. infrared radiation, heat · CPC title

• B41M1/34

  on glass or ceramic surfaces {(ink-jet printing on glass or ceramic surfaces B41M5/00)} · CPC title

• G02B1/14

  Protective coatings, e.g. hard coatings · CPC title