Polyethylene composition for pipe applications with improved sagging properties

Patent metadata

Field	Value
Publication number	US-12227633-B2
Application number	US-202017080767-A
Country	US
Kind code	B2
Filing date	Oct 26, 2020
Priority date	Dec 23, 2013
Publication date	Feb 18, 2025
Grant date	Feb 18, 2025

Abstract

The present invention relates to a polyethylene composition comprising, a base resin (A) comprising
a copolymer of ethylene and at least one comonomer selected from alpha-olefins having from three to twelve carbon atoms, wherein the ethylene copolymer comprises a low molecular weight component (A-1) and a high molecular weight component (A-2) with the low molecular weight component (A-1) having a lower weight average molecular weight than the high molecular weight component (A-2), (B) carbon black in an amount of 1.0 to 10 wt % based on the total amount of the polyethylene composition, and (C) optional further additives other than carbon black.

First claim

The invention claimed is:

1. A bimodal polyethylene composition consisting of
a bimodal base resin (A) comprising:
a copolymer of ethylene and at least one comonomer selected from alpha-olefins having from three to twelve carbon atoms,
wherein the ethylene copolymer comprises a low molecular weight component (A-1) and a high molecular weight component (A-2) with the low molecular weight component (A-1) having a lower weight average molecular weight than the high molecular weight component (A-2),
(B) carbon black in an amount of 1.0 to 10 wt % based on the total amount of the polyethylene composition, and
(C) optional stabilizing additives;
wherein the base resin (A) has a density of equal to or more than 943 kg/m 3 to equal to or less than 957 kg/m 3, determined according to ISO 1183, and
the composition has a melt flow rate MFR5 (190° C., 5 kg) of equal to or more than 0.12 g/10 min to equal to or less than 0.20 g/10 min, determined according to ISO 1133, a melt flow rate MFR 21 (190° C., 21.6 kg) of equal to or more than 5.6 g/10 min to equal to or less than 6.5 g/10 min, determined according to ISO 1133, a shear thinning index SHI 2.7/210 of equal to or more than 120 to equal to or less than 130 and a viscosity at a constant shear stress of 747 Pa, eta 747, of equal to or more than 700 kPas to equal to or less than 1200 kPas, and
wherein the low molecular weight component (A-1) has a melt flow rate MFR 2 (190° C., 2.16 kg) of 200 g/10 min to 400 g/10 min, determined according to ISO 1133.

2. The bimodal polyethylene composition according to claim 1 , wherein the low molecular weight component (A-1) is an ethylene homopolymer.

3. The bimodal polyethylene composition according to claim 1 , wherein the high molecular weight component (A-2) is a copolymer of ethylene and a comonomer selected from alpha-olefins having from three to twelve carbon atoms.

4. The bimodal polyethylene composition according to claim 1 , wherein the weight ratio of the low molecular weight component (A-1) to the high molecular component (A-2) is from 45:55 to 55:45.

5. The bimodal polyethylene composition according to claim 1 , wherein the composition has a density of equal to or more than 953 kg/m 3 to equal to or less than 967 kg/m 3, determined according to ISO 1183.

6. The bimodal polyethylene composition according to claim 1 , wherein the composition has a shear thinning index SHI 5/200 of equal to or more than 50 to equal to or less than 100.

7. The bimodal polyethylene composition according to claim 1 , wherein the composition has at least one of the following properties a) a weight average molecular weight, Mw, of 250 to 360 kg/mol, and/or b) Mz value of 1600 to 2500 kg/mol.

8. The bimodal polyethylene composition according to claim 1 , wherein the composition has a molecular weight distribution Mw/Mn, of at least 25.

9. The bimodal polyethylene composition according to claim 1 , wherein the composition has a tensile modulus of equal to or less than 1250 MPa, determined according to ISO 527-2:1993.

10. A bimodal polyethylene composition consisting of a bimodal base resin (A) comprising:
a copolymer of ethylene and at least one comonomer selected from alpha-olefins having from three to twelve carbon atoms,
wherein the ethylene copolymer comprises a low molecular weight component (A- 1) and a high molecular weight component (A-2) with the low molecular weight component (A-1) having a lower weight average molecular weight than the high molecular weight component (A-2),
(B) carbon black in an amount of 1.0 to 10 wt % based on the total amount of the polyethylene composition, and
(C) optional stabilizing additives other than carbon black, wherein the optional further additives other than carbon black (C) are selected from the group consisting of antioxidant agents, metal scavengers and/or UV stabilizers, antistatic agents, processing aid agents and combinations thereof;
wherein the base resin (A) has a density of equal to or more than 943 kg/m 3 to equal to or less than 957 kg/m 3, determined according to ISO 1183, and
the composition has a melt flow rate MFR 5 (190° C., 5 kg) of equal to or more than 0.12 g/10 min to equal to or less than 0.20 g/10 min, determined according to ISO 1133, a melt flow rate MFR 21 (190° C., 21.6 kg) of equal to or more than 5.6 g/10 min to equal to or less than 6.5 g/10 min, determined according to ISO 1133, a shear thinning index SHI 2.7/210 of equal to or more 120 to equal to or less than 130 and a viscosity at a constant shear stress of 747 Pa, eta 747, of equal to or more than 700 kPas to equal to or less than 1200 kPas, and
wherein the low molecular weight component (A-1) has a melt flow rate MFR 2 (190° C., 2.16 kg) of 200 g/10 min to 400 g/10 min, determined according to ISO 1133.

11. The bimodal polyethylene composition according to claim 10 , wherein the bimodal base resin (A) consists of the copolymer of ethylene and at least one comonomer selected from alpha-olefins having from three to twelve carbon atoms.

Assignees

• Abu Dhabi Polymers Co Ltd Borouge
• Borealis Ag

Inventors

• Tynys Antti
• Harjuntausta Jarmo
• Adhyatmabhattar Mohana Murali

Classifications

• C08L23/06

  Polyethylene · CPC title

• C08K3/04

  Carbon · CPC title

• C08L2314/02

  Ziegler natta catalyst · CPC title

• C08L2308/00

  Chemical blending or stepwise polymerisation process with the same catalyst · CPC title

• C08L2203/18

  used for pipes · CPC title