Composition and cured product of same

Patent metadata

Field	Value
Publication number	US-12227611-B2
Application number	US-202017760980-A
Country	US
Kind code	B2
Filing date	Sep 11, 2020
Priority date	Sep 17, 2019
Publication date	Feb 18, 2025
Grant date	Feb 18, 2025

Abstract

Provided is a composition capable of forming a cured product having excellent adhesion to a substrate, hardness, scratch resistance, and chemical resistance. The composition of the present disclosure includes a polyol compound (A) and an isocyanate compound (B), the polyol compound (A) containing a compound (a1) having a number average molecular weight calibrated with polystyrene standards of less than 800 and being represented by Formula (1), where R 1 to R 3 are a group represented by Formula (1a); and the isocyanate compound (B) containing a compound (b) represented by Formula (2), where L 1 to L 3 are a hydrogen atom, an NCO group, or an alkyl group having from 1 to 10 carbon atom(s) and having a group represented by Formula (2′).

First claim

The invention claimed is:

1. A composition comprising:
a polyol compound (A) and
an isocyanate compound (B),
wherein the polyol compound (A) comprises a compound (a1) having a number average molecular weight calibrated with polystyrene standards of less than 800, the compound (a1) being represented by Formula (1):

wherein in Formula (1), R 1 to R 3 , each identical or different, are a group represented by Formula (1a):

wherein in Formula (1a), L 1 and L 2 , each identical or different, represent an alkylene group having from 1 to 10 carbon atom(s), and m represents a number of 0 or greater, except m does not simultaneously equal 0 for R 1 to R 3 , and the bond with the wavy line binds to a nitrogen atom in Formula (1); and
wherein the isocyanate compound (B) comprises a compound (b) represented by Formula (2):

wherein in Formula (2), L 3 to L 5 , each identical or different, represent a hydrogen atom, an NCO group, or an alkyl group having from 1 to 10 carbon atom(s) and having a group represented by Formula (2′), except L 3 to L 5 do not simultaneously represent hydrogen atoms:

wherein in Formula (2′), L 6 and L 7 , each identical or different, represent an alkylene group having from 1 to 10 carbon atom(s), and the bond with the wavy line binds to a carbon atom of the alkyl group having from 1 to 10 carbon atom(s) in L 3 to L 5 in Formula (2); and
wherein a content of the isocyanate compound (B) in the composition is from 40 to 140 parts by weight relative to 100 parts by weight of the polyol compound (A).

2. The composition according to claim 1 , wherein the polyol compound (A) further comprises a polyol (a2) in an amount ranging from 0.01 to 1.5 parts by weight relative to 1 part by weight of the compound (a1), the polyol (a2) having a hydroxyl value (KOH mg/g) from 30 to 300.

3. The composition according to claim 1 , wherein an equivalent ratio of an NCO group in the isocyanate compound (B) to an OH group in the polyol compound (A), that is NCO/OH, is in a range from 0.2 to 2.0.

4. The composition according to claim 1 , further comprising a polysiloxane derivative (C) in an amount from 0.1 to 0.5 parts by weight relative to 100 parts by weight of a total of the polyol compound (A) and the isocyanate compound (B).

5. The composition according to claim 1 , further comprising a solvent represented by Formula (3):

wherein in Formula (3), R 4 and R 6 , each identical or different, represent a hydrogen atom or an alkyl group having from 1 to 5 carbon atom(s), R 5 represents an alkylene group having from 1 to 5 carbon atom(s), s represents an integer of 1 or greater, and t represents 0 or 1, and when s is an integer of 2 or greater, each of a plurality of R 5 is identical or different from each other.

6. The composition according to claim 1 , wherein the composition is a coating agent.

7. A cured product of the composition described in claim 1 .

8. A plastic molded product, having at least a portion of a surface being covered with a coating including the cured product described in claim 7 .

Assignees

• Daicel Corp

Inventors

• Konno Takashi
• Maetsu Naritoshi
• Watanabe Jun
• Hatanaka Shintarou

Classifications

• C08J2367/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds; (C08J2367/06 takes precedence) · CPC title

• C08G18/44

  Polycarbonates · CPC title

• C08G18/3851

  containing three nitrogen atoms in the ring · CPC title

• C09D7/65

  macromolecular (C09D7/41-C09D7/48 take precedence) · CPC title

• C08G77/46

  containing polyether sequences · CPC title