Perylene imide and composite photocatalytic material thereof, preparation method therefor and application thereof in removing organic pollutants from water

Patent metadata

Field	Value
Publication number	US-12226759-B2
Application number	US-202017624186-A
Country	US
Kind code	B2
Filing date	Nov 8, 2020
Priority date	Dec 15, 2019
Publication date	Feb 18, 2025
Grant date	Feb 18, 2025

Abstract

Melamine is calcined to obtain melem; melem, perylene tetracarboxylic dianhydride and a solvent are mixed to obtain a mixture, and the mixture is subjected to a solvothermal reaction in an inert atmosphere to obtain perylene imide; and the perylene imide is dispersed in an aqueous solution containing a bismuth source and a tungsten source, and is subjected to a hydrothermal reaction to obtain a perylene imide/bismuth tungstate composite photocatalytic material. By means of constructing an organic-inorganic composite photocatalytic material, the introduction of the organic photocatalytic material that responds to visible light may enable the composite material to have a wider spectral response range; and the introduction of an inorganic semiconductor catalyst enables the composite material to produce more oxidizing active free radicals, thereby enhancing the photocatalytic degradation performance of the composite material on organic pollutants. The constructed organic-inorganic composite photocatalytic material has an excellent catalytic performance.

First claim

What we claim is:

1. A method of preparing a perylene imide comprising the following steps:
calcining melamine to obtain a melem;
mixing the melem, perylene tetracarboxylic dianhydride and a solvent to obtain a mixture, and
placing the mixture in an inert atmosphere to obtain perylene imide by a solvothermal reaction,
wherein the calcination is carried out in air and calcined at 400˜450° C. for 3-5 h, and the solvothermal reaction is carried out in inert gas at 180-200° C. for 72-120 h; and
wherein the solvent is a mixture of DMF and ethylene glycol, and a molar ratio of the melem to the perylene tetracarboxylic dianhydride is 2:3.

2. A method of preparing a perylene imide/bismuth tungstate composite photocatalytic material comprising the following steps:
1) calcining melamine to obtain a melem; thereafter, mixing the melem, perylene tetracarboxylic dianhydride and a solvent to obtain a mixture, and then placing the mixture in an inert atmosphere to obtain perylene imide by solvothermal reaction;
2) dispersing the perylene imide obtained in step 1) in an aqueous solution containing bismuth source and tungsten source to obtain the perylene imide/bismuth tungstate composite photocatalytic material by hydrothermal reaction,
wherein the calcination is carried out in air and calcined at 400-450° C. for 3-5 h, and the solvothermal reaction is carried out in inert gas at 180-200° C. for 72-120 h;
wherein the solvent is a mixture of DMF and ethylene glycol, and a molar ratio of the melem to the perylene tetracarboxylic dianhydride is 2:3;
wherein centrimethyl ammonium bromide is used as a template in the hydrothermal reaction, and the hydrothermal reaction is carried out at 120-180° C. for 12-24 h; and
wherein the bismuth source is bismuth nitrate pentahydrate, the tungsten source is sodium tungstate dihydrate, and a molar ratio of bismuth source to tungsten source is 2:1.

3. The method according to claim 2 , further comprising photodegrading organic pollution in water for the removal of the organic pollution in the water with the perylene imide/bismuth tungstate composite photocatalytic material of claim 2 .

Assignees

• Univ Soochow

Inventors

• Lu Jianmei
• Li Najun

Classifications

• B01J35/45

  Nanoparticles · CPC title

• B01J35/39 Primary

  Photocatalytic properties · CPC title

• C02F2305/10

  Photocatalysts · CPC title

• C02F1/30

  by irradiation · CPC title

• B01J37/08

  Heat treatment {(B01J37/0009, B01J37/0018 take precedence)} · CPC title