Imidazolium ionic liquids made using cardanol extracted from cashew nutshell oil to enhance crude oil recovery in oilfields

Patent metadata

Field	Value
Publication number	US-12226751-B2
Application number	US-202418612458-A
Country	US
Kind code	B2
Filing date	Mar 21, 2024
Priority date	Jun 20, 2023
Publication date	Feb 18, 2025
Grant date	Feb 18, 2025

Abstract

Modified chemical structures of cardanol extracted from cashew nut shell oil, and the use of the same to prepare imidazolium ionic liquids (IILs). The IILs can be used to prepare different types of silica, magnetite and calcium carbonate nanoparticles (NPs) as multifunctional oilfield chemicals for use in various oil spill collection, de-emulsification, viscosity improvement, asphaltene dispersant, and enhanced oil recovery applications.

First claim

We claim:

1. A method for preparing a dicardnyl tri-imidazolium ionic liquid (DCTIm), the method comprising:
heating a dicardenoxy imidazolium ionic liquid (DCIm) with an alkyl halide; and
obtaining the dicardnyl tri-imidazolium ionic liquid (DCTIm);

wherein the DCIm is prepared according to a method comprising:
obtaining cardanol extracted from cashew nut oil;
dissolving the cardanol in a mixture of epichlorhydrin and water to obtain CGE having the formula:

mixing the CGE with a compound of the formula H 2 N—(—CH 2 —CH 2 —NH) n —H, wherein n is an integer between 3 and 5, to obtain a cardanol amine (CIm) having the formula:

dissolving the CIm in acetic acid or trifluoroacetic acid to obtain an amine solution; and
adding an aldehyde solution to the amine solution to obtain the DCIm.

2. The method as recited in claim 1 , wherein the cardanol is dissolved in the mixture of epichlorohydrin and water at a molar ratio of about 1:2 of cardanol to epichlorohydrin.

3. The method as recited in claim 1 , wherein the aldehyde solution is prepared by dissolving glyoxal monohydrate with formaldehyde in an acetic acid or trifluoroacetic acid aqueous solution.

Assignees

• Univ King Saud

Inventors

• Atta Ayman M
• Al-Lohedan Hamad A
• Ezzat Abdelrahman O
• Aldalbahi Ali K

Classifications

• C08G65/3317

  phenolic · CPC title

• C02F2101/32

  Hydrocarbons, e.g. oil · CPC title

• C02F1/281

  using inorganic sorbents · CPC title

• C02F1/285

  using synthetic organic sorbents · CPC title

• E02B15/041

  Devices for distributing materials, e.g. absorbed or magnetic particles over a surface of open water to remove the oil, with or without means for picking up the treated oil (E02B15/042 takes precedence) · CPC title