Method of producing a secondary battery, and secondary battery

Patent metadata

Field	Value
Publication number	US-12224437-B2
Application number	US-202217668475-A
Country	US
Kind code	B2
Filing date	Feb 10, 2022
Priority date	Apr 27, 2021
Publication date	Feb 11, 2025
Grant date	Feb 11, 2025

Abstract

According to one embodiment, a method of producing a secondary battery is provided. The method includes preparing a battery architecture including a positive electrode, a negative electrode, and an electrolyte; adjusting a positive electrode potential to a range of 3.4 V to 3.9 V and a negative electrode potential to a range of 1.5 V to 2.0 V based on an oxidation-reduction potential of lithium, thereby providing a potential adjusted state; and holding the battery architecture in the potential adjusted state at a holding temperature of 50° C. to 90° C. The positive electrode includes a lithium-nickel-cobalt-manganese composite oxide. The negative electrode includes a niobium-titanium composite oxide. The electrolyte includes one or more first organic solvent having a viscosity of 1 cP or less.

First claim

What is claimed is:

1. A method of producing a secondary battery, the method comprising:
preparing a battery architecture, the battery architecture comprising a positive electrode, a negative electrode, and an electrolyte, the positive electrode comprising a lithium-nickel-cobalt-manganese composite oxide, the negative electrode comprising a niobium-titanium composite oxide, and the electrolyte comprising one or more of first organic solvents having a viscosity of 1 cP or less;
adjusting a positive electrode potential of the positive electrode to a range of 3.4 V or more and 3.9 V or less based on oxidation-reduction potential of lithium, and adjusting a negative electrode potential of the negative electrode to a range of 1.5 V or more and 2.0 V or less based on oxidation-reduction potential of lithium, thereby providing a potential adjusted state; and
holding the battery architecture in the potential adjusted state at a holding temperature in a range of 50° C. or more and 90° C. or less.

2. The method of producing a secondary battery according to claim 1 , wherein the battery architecture is held in the potential adjusted state at the holding temperature for 6 hours or more and 72 hours or less.

3. The method of producing a secondary battery according to claim 1 , wherein the electrolyte comprises the first organic solvent in a volume ratio of 10% or more.

4. The method of producing a secondary battery according to claim 1 , wherein the first organic solvent comprises one or more selected from the group consisting of diethyl carbonate, methyl ethyl carbonate, and ethyl propionate.

5. The method of producing a secondary battery according to claim 1 , wherein the electrolyte comprises a second organic solvent comprising propylene carbonate.

6. The method of producing a secondary battery according to claim 1 , wherein the electrolyte further comprises a sultone compound.

7. The method of producing a secondary battery according to claim 6 , wherein the sultone compound comprises one or more selected from the group consisting of 1,3-propane sultone, 1,3-propene sultone, 1,4-butane sultone, and 2,4-butane sultone.

8. The method of producing a secondary battery according to claim 1 , wherein the lithium-nickel-cobalt-manganese composite oxide comprises a compound represented by Li x Ni 1−y−z Co y Mn z O 2 wherein 0<x≤1, 0<y<1, 0<z<1, and y+z<1.

9. The method of producing a secondary battery according to claim 1 , wherein the niobium-titanium composite oxide includes one or more of monoclinic niobium-titanium composite oxides selected from the group consisting of: a compound represented by Li a Ti 1−b M1 b Nb 2−c M2 c O 7+δ , wherein M1 is at least one selected from the group consisting of Zr, Si, and Sn, M2 is at least one selected from the group consisting of V, Ta, and Bi, 0≤a≤5, 0≤b<1, 0≤c<2, and −0.3≤δ≤0.3; and a compound represented by Li a Ti 1−b M3 b+c Nb 2−c O 7−δ , wherein M3 is at least one selected from the group consisting of Mg, Fe, Ni, Co, W, Ta, and Mo, 0≤a≤5, 0≤b<1, 0≤c<2, and −0.3≤δ≤0.3.

10. A secondary battery produced by the method according to claim 1 .

Assignees

• Toshiba Kk

Inventors

• Yamada Arisa
• Kusama Tomoe
• Sugizaki Tomoko
• Kanai Yuta
• Yasumiishi Hirofumi
• Sasakawa Tetsuya
• Harada Yasuhiro

Classifications

• H01M4/134

  Electrodes based on metals, Si or alloys · CPC title

• H01M2004/027

  Negative electrodes · CPC title

• H01M2300/0037

  Mixture of solvents · CPC title

• H01M4/0471 Primary

  involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis · CPC title

• H01M4/1395

  of electrodes based on metals, Si or alloys · CPC title