Alloyed galvanized steel sheet, electrodeposition-coated steel sheet, automotive part, method of producing electrodeposition-coated steel sheet, and method of producing alloyed galvanized steel sheet

Patent metadata

Field	Value
Publication number	US-12221705-B2
Application number	US-202118251269-A
Country	US
Kind code	B2
Filing date	Nov 5, 2021
Priority date	Nov 6, 2020
Publication date	Feb 11, 2025
Grant date	Feb 11, 2025

Abstract

Provided is an alloyed galvanized steel sheet with excellent resistance to cracking in resistance welding at a welded portion, even if crystal orientations of an Fe-based electroplating layer and a cold-rolled steel sheet are integrated at a high ratio at the interface between the Fe-based electroplating layer and the cold-rolled steel sheet. The alloyed galvanized steel sheet has a Si-containing cold-rolled steel sheet containing Si in an amount of 0.1 mass % to 3.0 mass %; an Fe-based electroplating layer formed on at least one surface of the Si-containing cold-rolled steel sheet with a coating weight per surface exceeding 20.0 g/m 2 , and an alloyed galvanized layer formed on the Fe-based electroplating layer, where crystal orientations of the Fe-based electroplating layer and the Si-containing cold-rolled steel sheet are integrated at a ratio of more than 50% at the interface between the Fe-based electroplating layer and the Si-containing cold-rolled steel sheet.

First claim

The invention claimed is:

1. An alloyed galvanized steel sheet comprising:
a Si-containing cold-rolled steel sheet containing Si in an amount of 0.1 mass % or more and 3.0 mass % or less;
an Fe-based electroplating layer formed on at least one surface of the Si-containing cold-rolled steel sheet with a coating weight per surface of more than 20.0 g/m 2 ; and
an alloyed galvanized layer formed on the Fe-based electroplating layer, wherein
crystal orientations of the Fe-based electroplating layer and the Si-containing cold-rolled steel sheet are integrated at a ratio of more than 50% at an interface between the Fe-based electroplating layer and the Si-containing cold-rolled steel sheet.

2. The alloyed galvanized steel sheet according to claim 1 , wherein the Si-containing cold-rolled steel sheet contains Si in an amount of 0.50 mass % or more and 3.0 mass % or less.

3. The alloyed galvanized steel sheet according to claim 1 , wherein the Fe-based electroplating layer is formed with a coating weight per surface of 25.0 g/m 2 or more.

4. The alloyed galvanized steel sheet according to claim 1 , wherein the Si-containing cold-rolled steel sheet has a chemical composition containing, in addition to Si, in mass %,
C: 0.8% or less,
Mn: 1.0% or more and 12.0% or less,
P: 0.1% or less,
S: 0.03% or less,
N: 0.010% or less, and
Al: 1.0% or less, with the balance being Fe and inevitable impurities.

5. The alloyed galvanized steel sheet according to claim 4 , wherein the chemical composition further comprises at least one selected from the group consisting of
B: 0.005% or less,
Ti: 0.2% or less,
Cr: 1.0% or less,
Cu: 1.0% or less,
Ni: 1.0% or less,
Mo: 1.0% or less,
Nb: 0.20% or less,
V: 0.5% or less,
Sb: 0.200% or less,
Ta: 0.1% or less,
W: 0.5% or less,
Zr: 0.1% or less,
Sn: 0.20% or less,
Ca: 0.005% or less,
Mg: 0.005% or less, and
REM: 0.005% or less.

6. The alloyed galvanized steel sheet according to claim 1 , wherein the Fe-based electroplating layer has a chemical composition containing at least one element selected from the group consisting of B, C, P, N, O, Ni, Mn, Mo, Zn, W, Pb, Sn, Cr, V, and Co, in a total amount of 10 mass % or less, with the balance being Fe and inevitable impurities.

7. An alloyed galvanized steel sheet comprising:
a cold-rolled steel sheet;
an Fe-based electroplating layer formed on at least one surface of the cold-rolled steel sheet with a coating weight per surface of more than 20.0 g/m 2 ; and
an alloyed galvanized layer formed on the Fe-based electroplating layer, wherein
crystal orientations of the Fe-based electroplating layer and the cold-rolled steel sheet are integrated at a ratio of more than 50% at an interface between the Fe-based electroplating layer and the cold-rolled steel sheet, and
the cold-rolled steel sheet is a cold-rolled steel sheet where a test specimen of the cold-rolled steel sheet that is cut to a size of 50 mm×150 mm with a direction orthogonal to a rolling direction as a lengthwise direction is overlapped with a test galvannealed steel sheet that is cut to the same size having a hot-dip galvanized layer with a coating weight per surface of 50 g/m 2 to obtain a sheet combination,
next, using a 50-Hz single-phase AC resistance welding machine comprising a servomotor pressure mechanism, the sheet combination is inclined 5° to a lengthwise direction side of the sheet combination with respect to a plane perpendicular to a line connecting central axes of an electrode pair with a tip diameter of 6 mm of the resistance welding machine, a lower electrode of the electrode pair and the sheet combination are fixed so that a gap of 60 mm in a lengthwise direction of the sheet combination and 2.0 mm in a thickness direction of the sheet combination is provided between the lower electrode and the test specimen, an upper electrode of the electrode pair is movable, and resistance welding is applied to the sheet combination under a set of conditions: applied pressure: 3.5 kN, hold time: 0.16 seconds, and welding current and welding time to produce a nugget diameter of 5.9 mm, to obtain a sheet combination with a welded portion, and
the sheet combination with a welded portion is then cut in half along a lengthwise direction of the test specimen to include a welded portion, a cross section of the welded portion is observed under an optical microscopy at a magnification of 200×, and a crack having a length of 0.1 mm or more is observed.

8. An electrodeposition-coated steel sheet comprising: a chemical conversion layer formed on the alloyed galvanized steel sheet as recited in claim 1 ; and an electrodeposition coating layer formed on the chemical conversion layer.

9. An automotive part at least partially made from the electrodeposition-coated steel sheet as recited in claim 8 .

10. A method of producing an electrodeposition-coated steel sheet, the method comprising:
subjecting the alloyed galvanized steel sheet as recited in claim 1 to chemical conversion treatment to obtain a chemical-conversion-treated steel sheet with a chemical conversion layer formed on the alloyed galvanized layer; and
subjecting the chemical-conversion-treated steel sheet to electrodeposition coating treatment to obtain an electrodeposition-coated steel sheet with an electrodeposition coating layer formed on the chemical conversion layer.

11. A method of producing the alloyed galvanized steel sheet of claim 1 , the method comprising:
subjecting a cold-rolled steel sheet containing Si in an amount of 0.1 mass % or more and 3.0 mass % or less to Fe-based electroplating to obtain a pre-annealing Fe-based electroplated steel sheet with a pre-annealing Fe-based electroplating layer formed on at least one surface thereof;
then subjecting the pre-annealing Fe-based electroplated steel sheet to annealing in an atmosphere with a dew point of −30° C. or lower to obtain an Fe-based electroplated steel sheet;
then subjecting the Fe-based electroplated steel sheet to galvanization to obtain a galvanized steel sheet; and
then further subjecting the galvanized steel sheet to alloying treatment to obtain the alloyed galvanized steel sheet comprising an Fe-based electroplating layer having a coating weight per surface of more than 20.0 g/m 2 .

12. The method of producing an alloyed galvanized steel sheet according to claim 11 , wherein the cold-rolled steel sheet contains Si in an amount of 0.5 mass % or more and 3.0 mass % or less.

13. The method of producing an alloyed galvanized steel sheet according to claim 11 , wherein a coating weight, in unit of g/m 2 , per surface of the pre-annealing Fe-based electroplating layer, denoted by C.W. Fe0 , satisfies the following formula (1):
(C.W. Fe0 )>20.0+(C.W. Zn )×[mass%Fe]/100  (1)

where C.W. Zn denotes a target value of a coating weight, in unit of g/m 2 , per surface of the alloyed galvanized layer, provided:
25.0 g/m 2 ≤C.W. Zn ≤80.0 g/m 2 , and

[mass % Fe] denotes a target value of an Fe content, in mass %, in the alloyed galvanized layer.

14. A method of producing the alloyed galvanized steel sheet of claim 7 , the method comprising:
subjecting a cold-rolled steel sheet to Fe-based electroplating to obtain a pre-annealing Fe-based electroplated steel sheet with a pre-annealing Fe-based electroplating layer formed on at least one surface thereof;
then subjecting the pre-annealing Fe-based electroplated steel sheet to annealing in an atmosphere with a dew point of −30° C. or lower to obtain an Fe-based electroplated steel sheet;
then subjecting the Fe-based electroplated steel sheet to galvanization to obtain a galvanized steel

Assignees

• Jfe Steel Corp

Inventors

• Yamamoto Shunsuke
• Takashima Katsutoshi
• Aoyama Mai
• Okumura Yusuke
• Kanazawa Tomomi
• Hoshino Katsuya
• Matsuda Hiroshi
• Okumura Ei
• Makimizu Yoichi
• Koba Masaki

Classifications

• C21D8/02

  during manufacturing of plates or strips (C21D8/12 takes precedence) · CPC title

• Y10T428/12958

  Next to Fe-base component · CPC title

• C25D5/36

  of iron or steel · CPC title

• C25D3/20

  of iron · CPC title

• C23C2/40

  Plates; Strips · CPC title