Use of specific solutions and polymer materials obtained from these solutions for trapping toxic chemical agents

Patent metadata

Field	Value
Publication number	US-12220736-B2
Application number	US-201917040626-A
Country	US
Kind code	B2
Filing date	Mar 26, 2019
Priority date	Mar 27, 2018
Publication date	Feb 11, 2025
Grant date	Feb 11, 2025

Abstract

A solution comprising at least one protic solvent, at least one monomer comprising an (alkyl)acrylic, (alkyl)acrylate or (alkyl)acrylamide group, at least one crosslinking agent comprising at least two groups chosen from (alkyl)acrylic, (alkyl)acrylate or (alkyl)acrylamide groups, at least one photopolymerization initiator and at least one agent chosen from alkali metal halides, alkali metal phosphates, alkali metal sulfates and mixtures thereof; or—of a polymer material capable of being obtained by polymerization of the solution defined above comprising a polymer resulting from the polymerization of the monomer(s) and of the crosslinking agent(s) as defined above and trapping, at the center thereof, a liquid phase comprising at least one agent as defined above; for the trapping of at least one toxic chemical agent.

First claim

What is claimed is:

1. A method of trapping a chemical toxic agent present on a surface contaminated by said chemical toxic agent comprising the following steps:
a step of bringing into contact with the contaminated surface of solution composed exclusively of at least one protic solvent, at least one monomer comprising an (alkyl) acrylic group, an (alkyl) acrylate group or an (alkyl) acrylamide group, at least one crosslinking agent comprising at least two groups chosen from (alkyl) acrylic, (alkyl) acrylate or (alkyl) acrylamide groups, at least one photopolymerization initiator and at least one agent selected from among alkali halides, alkali phosphates, alkali sulphates and mixtures thereof;
a step of forming a polymeric material by polymerizing the monomer(s) and the crosslinking agent(s) present in the solution, whereby it is obtained a polymeric material comprising a polymer resulting from the polymerization of the monomer(s) and of the crosslinking agent(s) as defined above and trapping, within itself, a liquid phase comprising at least one agent as defined above;
a step of removing the polymeric material thus formed from said surface, by means of which said surface is thus depleted or even devoid of said chemical toxic agent.

2. The method according to claim 1 , wherein the protic solvent is water.

3. The method according to claim 1 , wherein the protic solvent is present in an amount of 40 to 60% by volume relative to the total volume of the solution.

4. The method according to claim 1 , wherein the at least one monomer comprising an (alkyl) acrylic group, an (alkyl) acrylate group, or an (alkyl) acrylamide group corresponds to the following formula (I):

in which:
R 1 represents —OR′ with R′ representing a hydrogen atom or an alkali element; or —OR 3 with R 3 representing an alkyl group; or —NR 4 R 5 with R 4 and R 5 representing, independently of each other, a hydrogen atom or an alkyl group; and
R 2 represents a hydrogen atom or an alkyl group.

5. The method according to claim 1 , in which the at least one monomer is a monomer corresponding to the following formula (II):

in which:
R 4 and R 5 are represent, independently of each other, a hydrogen atom or an alkyl group;
R 2 is represents a hydrogen atom or an alkyl group.

6. The method according to claim 1 , wherein the monomer is N,N′-dimethylacrylamide.

7. The method according to claim 1 , wherein the at least one crosslinking agent comprises at least two (alkyl) acrylate groups.

8. The method according to claim 1 , in which the at least one crosslinking agent corresponds to the following formula (III):

in which:
R 6 and R 7 represent, independently of each other, a hydrogen atom or an alkyl group;
n corresponds to the unit count in parentheses, this number ranging from 1 to 15.

9. The method according to claim 1 , wherein the crosslinking agent is polyethylene glycol dimethacrylate.

10. The method according to claim 1 , wherein the at least one crosslinking agent is present in an amount of 1 to 5% by volume relative to the total volume of the solution.

11. The method according to claim 1 , in which the at least one photopolymerization initiator is an initiator of the aromatic ketone family.

12. The method according to claim 1 , wherein the photopolymerization initiator is 1-hydroxy-cyclohexylphenyl ketone.

13. The method according to claim 1 , in which the at least one photopolymerization initiator is present in an amount of 1 to 15 g/L.

14. The method according to claim 1 , in which the at least one agent is present in an amount of 1 to 15 g/L.

15. The method according to claim 1 , wherein the agent is potassium fluoride.

16. The method according to claim 1 , wherein the chemical toxic agent is an organophosphorus compound.

Assignees

• Commissariat Energie Atomique

Inventors

• Cadra Stéphane
• Blondel Benoit

Classifications

• C08F220/56 Primary

  Acrylamide; Methacrylamide · CPC title

• C08K3/16

  Halogen-containing compounds · CPC title

• C08L33/24

  Homopolymers or copolymers of amides or imides · CPC title

• C08K5/16

  Nitrogen-containing compounds {(C08K5/0091 takes precedence)} · CPC title

• C08K5/10

  Esters; Ether-esters · CPC title