Mineral composition

Patent metadata

Field	Value
Publication number	US-12220681-B2
Application number	US-201917298126-A
Country	US
Kind code	B2
Filing date	Nov 28, 2019
Priority date	Nov 29, 2018
Publication date	Feb 11, 2025
Grant date	Feb 11, 2025

Abstract

Compositions suitable for the purification of liquids, methods for making said compositions, and the uses of said compositions.

First claim

The invention claimed is:

1. A composition comprising:
a palygorskite, or sepiolite mineral;
a second mineral comprising moler, wherein the second mineral is different from the palygorskite, or sepiolite mineral already present in the composition; and
synthetic amorphous silica;
wherein the synthetic amorphous silica is dispersed on the surface of at least one of the palygorskite, or sepiolite mineral and the second mineral.

2. The composition of claim 1 , wherein the synthetic amorphous silica is dispersed on the surface of both the palygorskite, or sepiolite mineral and the second mineral.

3. The composition of claim 1 , wherein the synthetic amorphous silica is silica gel.

4. The composition of claim 1 , wherein:
at least 60 wt % of particles in the composition are equal to or smaller than 75 μm; and/or
the composition has a d50 ranging from about 10 μm to about 60 μm; and/or
the composition has a d90 ranging from about 40 μm to about 150 μm; and/or
the composition has a d10 ranging from about 1 μm to about 10 μm.

5. The composition of claim 1 , wherein the composition comprises:
from about 60 wt % to about 98 wt % of the palygorskite, or sepiolite mineral;
from about 1 wt % to about 35 wt % of the second mineral; and
from about 1 wt % to about 15 wt % of the synthetic amorphous silica.

6. The composition of claim 1 , wherein the ratio of the palygorskite, or sepiolite mineral to the second mineral in the composition ranges from about 20:1 to about 1:1.

7. The composition of claim 1 , wherein the composition has a specific surface area (SSA) equal to or greater than about 100 m 2 /g.

8. The composition of claim 1 , wherein the composition has a pore volume equal to or less than 0.9 cm3/g.

9. The composition of claim 1 , wherein the composition has a filterability equal to or greater than 0.01 Darcy.

10. The composition of claim 2 , wherein:
at least 60 wt % of particles in the composition are equal to or smaller than 75 μm;
the composition has a d10 ranging from about 1 μm to about 10 μm;
the composition has a d50 ranging from about 10 μm to about 60 μm; and
the composition has a d90 ranging from about 40 μm to about 150 μm.

11. The composition of claim 10 , wherein the composition comprises:
from about 60 wt % to about 98 wt % of the palygorskite, or sepiolite mineral;
from about 1 wt % to about 35 wt % of the second mineral; and
from about 1 wt % to about 15 wt % of the synthetic amorphous silica.

12. The composition of claim 11 , wherein:
the composition has a specific surface area (SSA) equal to or greater than 200 m 2 /g;
the composition has a pore volume equal to or less than 0.5 cm 3 /g; and
the composition has a filterability equal to or greater than 0.04 Darcy.

13. A method for making the composition of claim 1 , the method comprising forming synthetic amorphous silica on at least one of a palygorskite, or sepiolite mineral and a second mineral comprising Moler such that the synthetic amorphous silica is dispersed on the surface of the palygorskite, or sepiolite mineral and/or the second mineral, wherein
a) the synthetic amorphous silica is dispersed on the surface of both of the palygorskite, or sepiolite mineral and the second mineral;
b) the synthetic amorphous silica is dispersed on the surface of the palygorskite, or sepiolite mineral, and the palygorskite, or sepiolite mineral having synthetic amorphous silica on its surface is combined with the second mineral; or
c) the synthetic amorphous silica is dispersed on the surface of the second mineral, and the second mineral having synthetic amorphous silica on its surface is combined with the palygorskite, or sepiolite mineral.

14. The method of claim 13 , wherein the synthetic amorphous silica is formed on the palygorskite, or sepiolite mineral and/or the second mineral by combining the palygorskite, or sepiolite mineral and/or the second mineral with a silicate and an acid.

15. A method of filtering a liquid, the method comprising combining the liquid with the composition of claim 1 .

Assignees

• Imertech Sas

Inventors

• Kapralou Christina
• Karalis Thanasis
• Dedeloudis Christos

Classifications

• C01B33/38 Primary

  Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type {(activation of naturally occurring clays B01J20/12; pillared layered base-exchange silicates B01J29/049)} · CPC title

• B01J20/28071

  being less than 0.5 ml/g · CPC title

• B01J20/28057

  Surface area, e.g. B.E.T specific surface area · CPC title

• B01J20/28011

  Other properties, e.g. density, crush strength · CPC title

• B01J20/28004

  Sorbent size or size distribution, e.g. particle size · CPC title