Additive, electrolyte for rechargeable lithium battery and rechargeable lithium battery

Patent metadata

Field	Value
Publication number	US-12218308-B2
Application number	US-202117397033-A
Country	US
Kind code	B2
Filing date	Aug 9, 2021
Priority date	Aug 25, 2020
Publication date	Feb 4, 2025
Grant date	Feb 4, 2025

Abstract

An additive, an electrolyte for a rechargeable lithium battery, and a rechargeable lithium battery including the same, the additive being represented by Chemical Formula 1 or Chemical Formula 2:

First claim

What is claimed is:

1. An electrolyte for a rechargeable lithium battery, the electrolyte comprising:
a non-aqueous organic solvent,
a lithium salt, and
an additive represented by Chemical Formula 1 or Chemical Formula 2:

wherein, in Chemical Formula 1 and Chemical Formula 2,
R 1 to R 8 are each independently an unsubstituted C1 to C10 alkyl group, an unsubstituted C2 to C10 alkenyl group, an unsubstituted C3 to C10 cycloalkyl group, an unsubstituted C3 to C10 cycloalkenyl group, an unsubstituted C2 to C10 alkynyl group, an unsubstituted C3 to C10 cycloalkynyl group, or an unsubstituted C6 to C20 aryl group,
R 1 to R 8 are separately present, or at least one pair of R 1 and R 2 ; R 3 and R 4 ; R 5 and R 6 ; and R 7 and R 8 are linked to each other to provide an unsubstituted monocyclic aliphatic heterocycle, an unsubstituted polycyclic aliphatic heterocycle, an unsubstituted monocyclic aromatic heterocycle, or an unsubstituted polycyclic aromatic heterocycle, and
L 1 to L 4 are each independently an unsubstituted C1 to C20 alkylene group.

2. The electrolyte as claimed in claim 1 , wherein:
the additive is represented by Chemical Formula 1,
Chemical Formula 1 is represented by Chemical Formula 1A or Chemical Formula 1B:

in Chemical Formula 1A,
R 11 to R 30 are each independently hydrogen, a halogen, or an unsubstituted C1 to C10 alkyl group,
n1 to n4 are each independently an integer of 0 to 4, and
L 1 and L 2 are each independently an unsubstituted C1 to C20 alkylene group;

in Chemical Formula 1B,
R 31 and R 32 are each independently an unsubstituted C2 to C10 alkylene group, and
L 1 and L 2 are each independently an unsubstituted C1 to C20 alkylene group.

3. The electrolyte as claimed in claim 2 , wherein:
the additive is represented by Chemical Formula 1B,
Chemical Formula 1B is represented by Chemical Formula 1B-I or Chemical Formula 1B-II:

in Chemical Formula 1B-I and Chemical Formula 1B-II,
R 101 to R 120 are each independently hydrogen, a halogen, or an unsubstituted C1 to C10 alkyl group, and
L 1 and L 2 are each independently an unsubstituted C1 to C20 alkylene group.

4. The electrolyte as claimed in claim 1 , wherein:
the additive is represented by Chemical Formula 2,
Chemical Formula 2 is represented by Chemical Formula 2A or Chemical Formula 2B:

in Chemical Formula 2A,
R 33 to R 52 are each independently hydrogen, a halogen, or an unsubstituted C1 to C10 alkyl group,
n5 to n8 are each independently an integer of 0 to 4, and
L 3 and L 4 are each independently an unsubstituted C1 to C20 alkylene group;

in Chemical Formula 2B,
R 53 and R 54 are each independently an unsubstituted C2 to C10 alkylene group, and
L 3 and L 4 are each independently an unsubstituted C1 to C20 alkylene group.

5. The electrolyte as claimed in claim 4 , wherein:
the additive is represented by Chemical Formula 2B,
Chemical Formula 2B is represented by Chemical Formula 2B-I or Chemical Formula 2B-II:

wherein, in Chemical Formula 2B-I and Chemical Formula 2B-II,
R 121 to R 140 are each independently hydrogen, a halogen, or an unsubstituted C1 to C10 alkyl group, and
L 3 and L 4 are each independently an unsubstituted C1 to C20 alkylene group.

6. The electrolyte as claimed in claim 1 , wherein:
the additive is represented by Chemical Formula 1B-I-1 or Chemical Formula 2B-I-1:

in Chemical Formula 1B-I-1 and Chemical Formula 2B-I-1, R 101 to R 108 , R 121 to R 128 , and R 141 to R 156 are each independently hydrogen, a halogen, or an unsubstituted C1 to C10 alkyl group.

7. The electrolyte as claimed in claim 1 , wherein the additive is included in an amount of about 0.1 wt % to about 10 wt %, based on a total weight of the electrolyte for a rechargeable lithium battery.

8. A rechargeable lithium battery, comprising:
a positive electrode including a positive active material;
a negative electrode including a negative active material; and
the electrolyte as claimed in claim 1 .

9. The rechargeable lithium battery as claimed in claim 8 , wherein:
the positive active material is represented by Chemical Formula 5:
Li x M 1 1-y-z M 2 y M 3 z O 2   [Chemical Formula 5]

in Chemical Formula 5,
0.5≤x≤1.8, 0≤y≤1, 0≤z≤1, 0≤y+z<1, and M 1 , M 2 , and M 3 are each independently Ni, Co, Mn, Al, Sr, Mg, La, or a combination thereof.

10. The rechargeable lithium battery as claimed in claim 8 , wherein:
the positive active material is a lithium composite oxide represented by Chemical Formula 5-1, Chemical Formula 5-2, or Chemical Formula 5-3:
Li x1 Ni y1 CO z1 Al 1-y1-z1 O 2   [Chemical Formula 5-1]

in Chemical Formula 5-1, 1≤x1≤1.2, 0<y1<1, and 0<z1<1,
Li x2 Ni y2 Co z2 Mn 1-y2-z2 O 2   [Chemical Formula 5-2]

in Chemical Formula 5-2, 1≤x2≤1.2, 0<y2<1, and 0<z2<1,
Li x3 CoO 2   [Chemical Formula 5-3]

in Chemical Formula 5-3, 0.5<x3≤1.

Assignees

• Samsung Sdi Co Ltd

Inventors

• Cho Wonseok
• Kim Dahyun
• Kim Minseo
• Kim Sanghyung
• Kim Sanghoon
• Park Sangwoo
• Park Hyejin
• Woo Myungheui
• Ryu Bokyung
• Lee Tae Jin
• TSAY Olga
• Shatunov Pavel

Classifications

• H01M2300/0025

  Organic electrolyte · CPC title

• H01M2004/028

  Positive electrodes · CPC title

• H01M10/0568

  characterised by the solutes · CPC title

• H01M10/0525 Primary

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title