Method for generating synthesis gas for use in hydroformylation reactions

Patent metadata

Field	Value
Publication number	US-12215432-B2
Application number	US-201917046049-A
Country	US
Kind code	B2
Filing date	Apr 11, 2019
Priority date	Apr 13, 2018
Publication date	Feb 4, 2025
Grant date	Feb 4, 2025

Abstract

A method for the generation of a gas mixture including carbon monoxide, carbon dioxide and hydrogen for use in hydroformylation plants, including the steps of evaporating water to steam; feeding the steam to a solid oxide electrolysis cell (SOEC) or an SOEC stack at a sufficient temperature for the cell or cell stack to operate while effecting a partial conversion of steam to hydrogen; utilizing the effluent SOEC gas including H2 together with CO2 from an external source as feed for a RWGS reactor in which the RWGS reaction takes place, converting some of the CO2 and H2 to CO and H2O; removing some of or all the remaining steam from the raw product gas stream; using said gas mixture comprising CO, CO2 and H2 for liquid phase hydroformylation utilizing carbon monoxide and hydrogen as reactants, while recycling CO2 to the RWGS reactor.

First claim

The invention claimed is:

1. A method for the generation of a gas mixture comprising carbon monoxide, carbon dioxide and hydrogen for use in hydroformylation plants, comprising the steps of:
evaporating water to steam,
feeding the steam to a solid oxide electrolysis cell (SOEC) or an SOEC stack at a sufficient temperature for the cell or cell stack to operate while supplying an electrical current to the SOEC or SOEC stack to effect a partial conversion of steam to hydrogen forming a raw product gas,
feeding CO 2 from an external source,
utilizing the raw product gas comprising H 2 together with the CO 2 as feed for a reverse water gas shift (RWGS) reactor in which the RWGS reaction takes place, converting some of the CO 2 and H 2 to CO and H 2 O forming a RWGS product gas, wherein the raw product gas is transferred directly to the RWGS reactor without cooling the raw product gas,
removing some of or all the remaining steam from the RWGS product gas stream by cooling the RWGS product gas stream allowing for condensation of at least part of the steam as liquid water and separating a remaining product gas from the liquid water, the remaining product gas comprising CO, CO 2 and H 2 , and
using the remaining product gas for a liquid phase hydroformylation process utilizing carbon monoxide and hydrogen as reactants.

2. The method according to claim 1 , wherein the temperature, at which H 2 is produced by electrolysis of H 2 O in the SOEC or SOEC stack, is around 700° C.

3. The method according to claim 1 , comprising removing essentially all the remaining steam from the RWGS product gas stream by cooling the RWGS product gas stream allowing for condensation of the steam as liquid water and separating the remaining product gas from the liquid water.

4. The method according to claim 1 , further comprising recycling CO 2 from the remaining product gas to the RWGS reactor.

5. The method according to claim 1 , further comprising utilizing the CO 2 to form a CO 2 -expanded liquid (CXL) reaction medium for the hydroformylation process.

Assignees

• Haldor Topsoe As

Inventors

• Schjødt Niels Christian
• Küngas Rainer
• Hinnemann Berit
• Blennow Bengt Peter Gustav

Classifications

• C25B15/083

  Separating products · CPC title

• C25B15/081

  Supplying products to non-electrochemical reactors that are combined with the electrochemical cell, e.g. Sabatier reactor · CPC title

• C07C45/50

  by oxo-reactions · CPC title

• C25B15/021

  of heating or cooling · CPC title

• C25B9/70

  Assemblies comprising two or more cells · CPC title