Combined urea hydrolysis and selective catalytic reduction for emissions control
US-10934918-B1 · Mar 2, 2021 · US
US12209523B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12209523-B2 |
| Application number | US-202318191025-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 28, 2023 |
| Priority date | Nov 9, 2020 |
| Publication date | Jan 28, 2025 |
| Grant date | Jan 28, 2025 |
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A method for controlling a reductant generation device 100 , the reductant generation device 100 including: a sprayer 10 capable of spraying a reductant precursor 50 ; and a heater 20 comprising a ceramic substrate 21 , the heater 20 being arranged on a downstream side of the sprayer 10 and capable of heating the reductant precursor 50 to generate a reductant 60 . The method includes: a permeation step of spraying the reductant precursor 50 from the sprayer 10 and permeating the ceramic substrate 21 with the reductant precursor 50 when the heater is not heated; and after the permeation step, a heating step A of heating the reductant precursor 50 by the heater 20 and generating the reductant 60 while spraying the reductant precursor 50 from the sprayer 10.
Opening claim text (preview).
The invention claimed is: 1. A method for controlling a reductant generation device, the reductant generation device comprising: a sprayer capable of spraying a reductant precursor; and a heater comprising a ceramic substrate, the heater being arranged on a downstream side of the sprayer and capable of heating the reductant precursor to generate a reductant, the method comprising: a permeation step of spraying the reductant precursor from the sprayer and permeating the ceramic substrate with the reductant precursor when the heater is not heated; and after the permeation step, a heating step A of heating the reductant precursor by the heater and generating the reductant while spraying the reductant precursor from the sprayer. 2. The method according to claim 1 , wherein the reductant precursor in the ceramic substrate in the permeation step has a permeability of 5 to 75% of the total pore volume of the ceramic substrate. 3. The method according to claim 1 , wherein the method further comprises a heating step B of heating the reductant precursor by the heater and generating the reductant while spraying the reductant precursor from the sprayer, wherein the heating step B, the permeation step and the heating step A are performed in this order. 4. The method according to claim 1 , wherein the reductant precursor is an aqueous urea solution and the reductant is ammonia. 5. The method according to claim 1 , wherein the heater comprises: a pillar shaped ceramic honeycomb substrate having an outer peripheral wall, and a partition wall arranged on an inner side of the outer peripheral wall, the partition wall defining a plurality of cells, each of the cells forming a flow path from a first end face to a second end face; and a pair of electrode portions disposed on a side surface of the pillar shaped ceramic honeycomb substrate, wherein the pillar shaped ceramic honeycomb substrate generates heat by electrical conduction. 6. The method according to claim 1 , wherein the heater is housed in a cylindrical member, and the heater and the cylindrical member are fixed via an insulation maintaining portion. 7. A method for purifying an exhaust gas, the method comprising bringing the reductant generated by the method according to claim 1 into contact with an exhaust gas containing NOx. 8. A reductant generation system, the reduction generation system comprising: a reductant generation device comprising: a sprayer capable of spraying a reductant precursor; and a heater comprising a ceramic substrate, the heater being arranged on a downstream side of the sprayer and capable of heating the reductant precursor to generate a reductant; and a control device comprising: a reductant precursor spray control unit for controlling spraying of the reductant precursor from the sprayer; and a heater control unit for controlling heating of the reductant precursor by the heater, wherein the reductant precursor spray control unit generates a control signal for spraying the reductant precursor from the sprayer when the heater is not heated, and controls the reductant generation system such that the ceramic substrate can be permeated with the reductant precursor. 9. The reductant generation system according to claim 8 , wherein the reductant precursor spray control unit controls an amount of the reductant precursor sprayed so that a permeability of the reductant precursor in the ceramic substrate is 5 to 75% of the total pore volume of the ceramic substrate. 10. The reductant generation system according to claim 8 , wherein the heater comprises: a pillar shaped ceramic honeycomb substrate having an outer peripheral wall, and a partition wall arranged on an inner side of the outer peripheral wall, the partition wall defining a plurality of cells, each of the cells forming a flow path from a first end face to a second end face; and a pair of electrode portions disposed on a side surface of the pillar shaped ceramic honeycomb substrate, wherein the pillar shaped ceramic honeycomb substrate generates heat by electrical conduction. 11. The reductant generation system according to claim 8 , wherein the heater is housed in a cylindrical member, and the heater and the cylindrical member are fixed via an insulation maintaining portion. 12. An exhaust gas purification system comprising the reductant generation system according to claim 8 , wherein the reductant generation device is provided in an exhaust pipe through which an exhaust gas containing NOx can flow or in a branch pipe connected to the exhaust pipe.
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