Pigment composition, identification medium, and method for determining authenticity

Patent metadata

Field	Value
Publication number	US-12209186-B2
Application number	US-202017629861-A
Country	US
Kind code	B2
Filing date	Jul 21, 2020
Priority date	Jul 30, 2019
Publication date	Jan 28, 2025
Grant date	Jan 28, 2025

Abstract

A pigment composition including: a first cholesteric liquid crystal pigment; and a second cholesteric liquid crystal pigment, wherein: the first cholesteric liquid crystal pigment is a pigment having: a center wavelength of a selective reflection band within a wavelength range of 400 nm or more and 800 nm or less; and a selective reflection bandwidth of 150 nm or less; the second cholesteric liquid crystal pigment is a pigment having a selective reflection bandwidth of 200 nm or more within a wavelength range of 400 nm or more and 800 nm or less; the selective reflection band of the first cholesteric liquid crystal pigment and a selective reflection band of the second cholesteric liquid crystal pigment at least partially overlap with each other; and a containing amount of the first cholesteric liquid crystal pigment relative to a total amount of the first cholesteric liquid crystal pigment and the second cholesteric liquid crystal pigment is more than 0% by weight and 30% by weight or less.

First claim

The invention claimed is:

1. A pigment composition comprising a mixture of a first cholesteric liquid crystal pigment; and a second cholesteric liquid crystal pigment, wherein:
at least one of the first cholesteric liquid crystal pigment and the second cholesteric liquid crystal pigment is in flake form,
an average particle diameter of the flake is 20 μm or more and 120 μm or less,
the first cholesteric liquid crystal pigment is a pigment having: a center wavelength of a selective reflection band within a wavelength range of 400 nm or more and 800 nm or less; and a selective reflection bandwidth of 150 nm or less;
the second cholesteric liquid crystal pigment is a pigment having a selective reflection bandwidth of 200 nm or more within a wavelength range of 400 nm or more and 800 nm or less;
the selective reflection band of the first cholesteric liquid crystal pigment and a selective reflection band of the second cholesteric liquid crystal pigment at least partially overlap with each other; and
a containing amount of the first cholesteric liquid crystal pigment relative to a total amount of the first cholesteric liquid crystal pigment and the second cholesteric liquid crystal pigment is more than 0% by weight and 30% by weight or less.

2. The pigment composition according to claim 1 , wherein the containing amount of the first cholesteric liquid crystal pigment relative to the total amount of the first cholesteric liquid crystal pigment and the second cholesteric liquid crystal pigment is 20% by weight or less.

3. The pigment composition according to claim 1 , wherein a selective reflection bandwidth of the first cholesteric liquid crystal pigment is 120 nm or less.

4. The pigment composition according to claim 1 , wherein the first cholesteric liquid crystal pigment and the second cholesteric liquid crystal pigment have an identical twist direction.

5. The pigment composition according to claim 1 , wherein the first cholesteric liquid crystal pigment and the second cholesteric liquid crystal pigment have twist directions that are different each other.

6. The pigment composition according to claim 1 , wherein:
the first cholesteric liquid crystal pigment is in flake form, and
an average particle diameter of the flakes of the first cholesteric liquid crystal pigment is 20 μm or more and 120 μm or less.

7. An ink composition comprising: the pigment composition according to claim 1 ; and a binder resin.

8. An identification medium comprising: a binder resin; and a pigment dispersed in the binder resin, wherein
the pigment is the pigment composition according to claim 1 .

9. A method for determining authenticity of the identification medium according to claim 8 , comprising:
a step 1 of observing reflected light from the identification medium via a counterclockwise circular polarizing plate and a clockwise circular polarizing plate to determine whether a difference exists in at least one of hue, lightness, and saturation of the reflected light;
a step 2 of observing the identification medium by naked eye to determine whether a color originating from the second cholesteric liquid crystal pigment is visually recognizable; and
a step 3 of observing the identification medium with a microscope to determine whether a color originating from the first cholesteric liquid crystal pigment and the color originating from the second cholesteric liquid crystal pigment are both visually recognizable.

Assignees

• Zeon Corp

Inventors

• Aimatsu Masashi

Classifications

• C08F222/1025

  of aromatic dialcohols · CPC title

• C09B69/107

  containing an azomethine dye · CPC title

• C09B67/0097

  Dye preparations of special physical nature; Tablets, films, extrusion, microcapsules, sheets, pads, bags with dyes · CPC title

• C09B69/106

  containing an azo dye · CPC title

• C09D11/101

  Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing · CPC title