Process for producing a sintered lithium disilicate glass ceramic dental restoration and kit of parts

Patent metadata

Field	Value
Publication number	US-12207982-B2
Application number	US-202217567323-A
Country	US
Kind code	B2
Filing date	Jan 3, 2022
Priority date	Jun 23, 2014
Publication date	Jan 28, 2025
Grant date	Jan 28, 2025

Abstract

A process for producing a sintered lithium disilicate glass ceramic dental restoration by way of sintering under reduced atmospheric pressure conditions at a temperature above 600° C. is described. Further described is a kit of parts for producing a sintered lithium disilicate glass ceramic dental restoration.

First claim

The invention claimed is:

1. A process for producing a sintered lithium disilicate glass ceramic dental restoration out of a porous 3-dim article, the process comprising:
sintering the porous 3-dim article having the shape of a dental restoration with an outer and inner surface to obtain a sintered lithium disilicate ceramic dental restoration,
the sintered lithium disilicate glass ceramic dental restoration comprising:
Si oxide calculated as SiO2: from 55 to 80 wt.-%;
Li oxide calculated as Li2O: from 7 to 16 wt.-%;
Al oxide calculated as Al 2 O 3 : from 1 to 5 wt.-%; and
P oxide calculated as P 2 O 5 : from 1 to 5 wt.-%,

wt.-% with respect to the weight of the dental restoration,
the sintering being done under reduced atmospheric pressure conditions, the reduced atmospheric pressure conditions being first applied at a temperature of at least 600° C.

2. The process of claim 1 comprising:
providing a porous 3-dim article, the 3-dim article having either the shape of a dental milling block or of a dental restoration with an outer and inner surface; and
for porous 3-dim articles having the shape of a milling block, machining the porous 3-dim article to obtain a machined porous 3-dim article having the shape of a dental restoration with an outer and inner surface.

3. The process of claim 1 , the porous 3-dim article having the shape of a dental crown, dental bridge, veneer, inlay, onlay or part thereof.

4. The process of claim 1 , the porous 3-dim article being characterized by at least one of the following features:
Pore volume: 70 to 20%;
Density: from 0.5 to 2 g/cm3;
Flexural strength: 20 to 75 MPa according to ISO 6872.

5. The process of claim 1 , the material of the sintered lithium disilicate glass ceramic dental restoration being characterized by at least one of the following features:
Pore volume: 0 to 2%;
Density: from 2.1 to 3 g/cm3;
Flexural strength: 250 to 450 MPa according to ISO 6872.

6. The process of claim 1 , the porous 3-dim article being obtained by a process comprising an additive manufacturing technology using a glass powder, the process optionally comprising the step of coloring the porous 3-dim article by using coloring components during the additive manufacturing technology.

7. The process of claim 1 , the porous 3-dim article being obtained by a process comprising the steps of:
providing a glass powder;
pressing the glass powder to obtain a 3-dim article; and
conducting a pre-sintering step to obtain the porous 3-dim article.

8. The process of claim 1 , further comprising a coloring step, the coloring step being conducted by:
either applying a coloring solution to only parts of the outer surface of the porous 3-dim article having the shape of a dental restoration; or
treating the whole surface of the porous 3-dim article having the shape of a dental restoration with a coloring solution.

9. The process of claim 8 , the coloring solution comprising a solvent and coloring ions selected from V, Mn, Fe, Er, Tb, Y, Ce, Sm, Dy or combinations thereof or coloring pigments comprising any of those coloring ions or combinations thereof.

10. The process of claim 1 , the sintered lithium disilicate glass ceramic dental restoration further comprising at least one, two, three or all of the following components:
K oxide calculated as K2O: from 0.1 to 5 wt.-%;
Zr oxide calculated as ZrO 2 : from 0.1 to 15 wt.-%;
Zn oxide calculated as ZnO2: from 0 to 2 wt.-%;
Ce oxide calculated as CeO2: from 0 to 2 wt.-%;
Cs oxide calculated as CsO2: from 0 to 8 wt.-%;
Coloring metal oxides calculated as MO2 or M2O3, with M being a metal ion: from 0 to 5 wt.-%.

11. The process of claim 1 , the lithium disilicate glass ceramic dental restoration not comprising ZrO2 in an amount of more than 20 wt.-%.

12. The process of claim 1 , the process not comprising at least one or all of the following steps:
machining the sintered lithium disilicate 3-dim article;
machining an article containing lithium metasilicate as main crystalline phase;
machining an article containing lithium disilicate as main crystalline phase.

13. The process of claim 1 , wherein the sintering is conducted without supporting the inner surface of the dental restoration.

14. A process for producing a sintered lithium disilicate glass ceramic dental restoration out of a porous 3-dim article, the process comprising:
providing a porous 3-dim article, the 3-dim article having the shape of a dental milling block, the porous 3-dim article having a density from 0.5 to 2 g/cm3,
machining the porous 3-dim article to obtain a machined porous 3-dim article having the shape of a dental restoration with an outer and inner surface,
optionally coloring the porous 3-dim article having the shape of a dental restoration,
sintering the porous 3-dim article having the shape of a dental restoration with an outer and inner surface at reduced atmospheric pressure without supporting the inner surface of the porous 3-dim article having the shape of a dental restoration during sintering to obtain a sintered lithium disilicate ceramic dental restoration,
the sintering being done under reduced atmospheric pressure conditions, the reduce atmospheric pressure conditions being first applied at a temperature above 600° C.,
the sintered lithium disilicate glass ceramic dental restoration having a density from 2 to 3 g/cm3 and comprising:
Si oxide calculated as SiO2: from 55 to 80 wt.-%;
Li oxide calculated as Li2O: from 7 to 16 wt.-%;
Al oxide calculated as Al 2 O 3 : from 1 to 5 wt.-%; and
P oxide calculated as P 2 O 5 : from 1 to 5 wt.-%,
wt.-% with respect to the weight of the dental restoration.

Assignees

• Solventum Intellectual Properties Company

Inventors

• Mayr Helmar
• Schechner Gallus

Classifications

• C03C2218/114

  by brushing, pouring or doctorblading · CPC title

• C03C2218/111

  by dipping, immersion · CPC title

• C03C2217/485

  Pigments · CPC title

• C03C2205/06

  for dental use · CPC title

• C03C2204/00

  Glasses, glazes or enamels with special properties · CPC title