Preparing method of electrostatic charge image developing toner, electrostatic charge image developing toner, and electostatic charge image developer

Patent metadata

Field	Value
Publication number	US-12204276-B2
Application number	US-202117406271-A
Country	US
Kind code	B2
Filing date	Aug 19, 2021
Priority date	Mar 19, 2021
Publication date	Jan 21, 2025
Grant date	Jan 21, 2025

Abstract

A preparing method of an electrostatic charge image developing toner includes: aggregating binder resin particles in a dispersion containing the binder resin particles to form aggregated particles; and coalescing the aggregated particles by heating a dispersion containing the aggregated particles to form toner particles. The aggregating includes stirring the dispersion in the aggregating at a required stirring power of 1.0 kW/m 3 or more and 6.0 kW/m 3 or less per unit volume, and the preparing method satisfies the following Requirement (1), in which
Requirement (1): a viscosity of the dispersion during the stirring is 5 Pa·s or more and 50 Pa·s or less at a shear rate of 1/s, where the viscosity of the dispersion is measured at a sample temperature of 25° C. using a part of the dispersion as a sample.

First claim

What is claimed is:

1. A preparing method of an electrostatic charge image developing toner, the method comprising:
aggregating binder resin particles in a dispersion containing the binder resin particles to form aggregated particles; and
coalescing the aggregated particles by heating a dispersion containing the aggregated particles to form toner particles, wherein
a content of a surfactant in the dispersion at a start of the aggregating step is 1 wt % or more and 10 wt % or less with respect to a total weight of the binder resin particles,
the aggregating includes stirring the dispersion in the aggregating at a required stirring power of 1.0 kW/m 3 or more and 6.0 kW/m 3 or less per unit volume,
the preparing method satisfies both the following Requirement (1) and the following Requirement 2:
Requirement (1): a viscosity of the dispersion during the stirring is 30 Pa·s or more and 50 Pa·s or less at a shear rate of 1/s,
Requirement (2): the viscosity of the dispersion during the stirring is 0.5 Pa·s or more and 1.5 Pa·s or less at the shear rate of 20/s,

where, for both the Requirement (1) and the Requirement (2), the viscosity of the dispersion is measured at a sample temperature of 25° C. using a part of the dispersion as a sample,
the aggregating is performed in a stirring tank provided with a stirrer having a rotary shaft and a stirring blade attached to the rotary shaft,
through the aggregating, a ratio L/d of a distance L between a liquid level in the stirring tank and an uppermost end of the stirring blade to a blade diameter d of the stirring blade is 0.3 or more and 1.0 or less, and
through the aggregating the liquid level is above the stirring blade.

2. The preparing method of an electrostatic charge image developing toner according to claim 1 , wherein
through the aggregating, a temperature of the dispersion in the aggregating is 50° C. or lower.

3. The preparing method of an electrostatic charge image developing toner according to claim 1 , wherein
the aggregating is performed in a stirring tank provided with a jacket, and
through the aggregating, an internal temperature of the jacket is (a glass transition temperature of the binder resin particles+5° C.) or lower.

4. The preparing method of an electrostatic charge image developing toner according to claim 2 , wherein
the aggregating is performed in a stirring tank provided with a jacket, and
through the aggregating, an internal temperature of the jacket is (a glass transition temperature of the binder resin particles+5° C.) or lower.

5. The preparing method of an electrostatic charge image developing toner according to claim 1 , wherein
through the aggregating, the ratio L/d is 0.5 or more and 1.0 or less.

6. The preparing method of an electrostatic charge image developing toner according to claim 1 , wherein
through the aggregating, the ratio L/d is 0.5 or more and 0.8 or less.

7. The preparing method of an electrostatic charge image developing toner according to claim 1 , wherein
the aggregating includes adding an aggregating agent to the dispersion containing the binder resin particles, and
the aggregating agent contains a trivalent metal salt compound.

8. The preparing method of an electrostatic charge image developing toner according to claim 1 , wherein
the dispersion containing the binder resin particles further contains release agent particles, and
in the aggregating, the release agent particles are further aggregated to form the aggregated particles.

9. The preparing method of an electrostatic charge image developing toner according to claim 1 , wherein
the dispersion containing the binder resin particles further contains coloring agent particles, and
in the aggregating, the coloring agent particles are further aggregated to form the aggregated particles.

10. The preparing method of an electrostatic charge image developing toner according to claim 1 , further comprising:
after the aggregating, second aggregating of mixing the dispersion containing the aggregated particles and a dispersion containing resin particles to be a shell layer and aggregating the resin particles to be the shell layer on surfaces of the aggregated particles to form second aggregated particles, wherein
in the coalescing, a dispersion containing the second aggregated particles is heated and the second aggregated particles are coalesced to form toner particles.

11. An electrostatic charge image developing toner which is prepared by the preparing method of an electrostatic charge image developing toner according to claim 1 .

12. An electrostatic charge image developer comprising an electrostatic charge image developing toner which is prepared by the preparing method of an electrostatic charge image developing toner according to claim 1 .

13. The preparing method of an electrostatic charge image developing toner according to claim 1 , wherein the content of the surfactant in the dispersion at the start of the aggregating step is 1.5 wt % or more and 8 wt % or less with respect to the total weight of the binder resin particles.

14. The preparing method of an electrostatic charge image developing toner according to claim 1 , wherein the aggregating is performed in a stirring tank provided with a stirrer having a rotary shaft, and paddle blades are provided on the rotary shaft in two stages.

15. A preparing method of an electrostatic charge image developing toner, the method comprising:
aggregating binder resin particles in a dispersion containing the binder resin particles to form aggregated particles; and
coalescing the aggregated particles by heating a dispersion containing the aggregated particles to form toner particles, wherein
a content of a surfactant in the dispersion at a start of the aggregating step is 1 wt % or more and 10 wt % or less with respect to a total weight of the binder resin particles,
the aggregating includes stirring the dispersion in the aggregating at a required stirring power of 1.0 kW/m 3 or more and 6.0 kW/m 3 or less per unit volume,
the preparing method satisfies both the following Requirement (1) and the following Requirement 2:
Requirement (1): a viscosity of the dispersion during the stirring is 5 Pa·s or more and 50 Pa·s or less at a shear rate of 1/s,
Requirement (2): the viscosity of the dispersion during the stirring is 0.1 Pa·s or more and 2.0 Pa·s or less at the shear rate of 20/s,

where, for both the Requirement (1) and the Requirement (2), the viscosity of the dispersion is measured at a sample temperature of 25° C. using a part of the dispersion as a sample,
the aggregating is performed in a stirring tank provided with a stirrer having a rotary shaft and a stirring blade attached to the rotary shaft,
through the aggregating, a ratio L/d of a distance L between a liquid level in the stirring tank and an uppermost end of the stirring blade to a blade diameter d of the stirring blade is 0.3 or more and 1.0 or less, and
through the aggregating the liquid level is above the stirring blade.

Assignees

• Fujifilm Business Innovation Corp

Inventors

• Tatekawa Takahisa
• Tomita Daisuke
• Noguchi Daisuke
• Nakamura Kazuhiko
• Isshiki Yuji

Classifications

• G03G9/0804 Primary

  whereby the components are brought together in a liquid dispersing medium · CPC title

• G03G9/09392 Primary

  Preparation thereof · CPC title