Polymer composition

Patent metadata

Field	Value
Publication number	US-12202964-B2
Application number	US-202017424943-A
Country	US
Kind code	B2
Filing date	Jan 27, 2020
Priority date	Jan 28, 2019
Publication date	Jan 21, 2025
Grant date	Jan 21, 2025

Abstract

The present invention relates to a polymer composition comprising (A) from 60 to 90 wt % of a non-elastomeric polyethylene; (B) from 9.0 to 38 wt % of an elastomer; wherein onto component (A) or components (A) and (B) an acid grafting agent (C) has been grafted in an amount of from 0.01 to 3.0 wt %, all based on the total weight of the polymer composition, and wherein the polymer composition has two distinct peaks and a valley between said peaks in the GPC curve and a Z value, determined from the areas below the two peaks of the GPC curve, of at least −0.3, wherein the Z-value is determined according to formula (I) Z=s/Abs(B−A) (I) wherein Abs(B−A) is the absolute value of (B−A); A=the area, between the tangent parallel to the MW axis going through log M (Min) and the LS15 signal, from log M of 5.1 to log M value where the LS signal is minimum log M (Min), in the log M range between 5.1 and 6; B=the area, between the tangent parallel to the MW axis going through log M (Min) and the LS 15 signal, from log M(Min) to the point where the LS signal is crossed again; and s is the slope between the two peaks of the GPC curve, defined at log M of 5.1 and 6, wherein the GPC curve is defined as the concentration normalized LS 15 signal along the molecular weight of conventional GPC, obtained from the GPC-VISC-LS analysis, a multi-layer structure such as a coated metal pipe, comprising one layer comprising said polymer composition and the use of said polymer composition as adhesive polymer composition and for the production of a multi-layer structure.

First claim

The invention claimed is:

1. A polymer composition comprising
(A) from 60 to 90 wt % of a non-elastomeric polyethylene;
(B) from 9.0 to 38 wt % of an elastomer;
wherein onto component (A) or components (A) and (B) an acid grafting agent (C) has been grafted in an amount of from 0.01 to 3.0 wt %, all based on the total weight of the polymer composition, and
wherein the polymer composition has two distinct peaks and a valley between said peaks in the GPC curve and a Z value, determined from the areas below the two peaks of the GPC curve, of at least −0.3, wherein the Z-value is determined according to formula (I)
Z=s /Abs( B−A )  (I)

wherein
Abs(B−A) is the absolute value of (B−A);
A=the area, between the tangent parallel to the MW axis going through log M (Min) and the LS15 signal, from log M of 5.1 to log M value where the LS signal is minimum log M (Min), in the log M range between 5.1 and 6;
B=the area, between the tangent parallel to the MW axis going through log M (Min) and the LS15 signal, from log M(Min) to the point where the LS signal is crossed again;
and
s is the slope between the two peaks of the GPC curve, defined at log M of 5.1 and 6,
wherein the GPC curve is defined as the concentration normalized LS 15 signal along the molecular weight of conventional GPC, obtained from the GPC-VISC-LS analysis.

2. The polymer composition according to claim 1 , wherein the non-elastomeric polyethylene is a copolymer of ethylene and one or more comonomer(s) selected from alpha-olefins having from 4 to 12 carbon atoms.

3. The polymer composition according to claim 1 , wherein the non-elastomeric polyethylene has a density of from 900 kg/m 3 to 960 kg/m 3 .

4. The polymer composition according to claim 1 , wherein the non-elastomeric polyethylene before grafting has a melt flow rate MFR 2 (190° C., 2.16 kg) of from 1.0 to 10.0 g/10 min.

5. The polymer composition according to claim 1 , wherein the non-elastomeric polyethylene has a polydispersity (PD), Mw/Mn, of from 1.5 to 6.0.

6. The polymer composition according to claim 1 , wherein the elastomer is selected from copolymers of ethylene with polar comonomer units, polyolefin plastomers, polyolefin elastomers, olefin block copolymers or mixtures thereof.

7. The polymer composition according to claim 1 , wherein the elastomer is a copolymer of ethylene with polar comonomer units having an amount of polar comonomer units in the range of from 15 to 40 wt %.

8. The polymer composition according to claim 1 , wherein the elastomer has a melt flow rate MFR 2 (190° C., 2.16 kg) of from 1.0 to 10.0 g/10 min.

9. The polymer composition according to claim 1 , wherein the acid grafting agent (C) is selected from unsaturated carboxylic acids or derivatives thereof such as anhydrides, esters and metallic or non-metallic salts.

10. The polymer composition according to claim 1 having a melt flow rate MFR 2 (190° C., 2.16 kg) of from 0.1 to 10.0 g/10 min and/or a density of from 900 kg/m 3 to 960 kg/m 3 .

11. The polymer composition according to claim 1 obtainable by a process comprising the steps of
feeding components (A), (B) and (C) into the feeding section of an extruder comprising a feeding section, a barrel section and a die plate, wherein the barrel section of the extruder downstream of the feeding section and upstream of the die plate is divided into a plurality of control zones, and the first control zone represents the first control zone within the barrel section downstream of the feeding zone in which the fed component(s) (A) and/or (B) start(s) to melt;
compounding the components (A) and (B) in order to form the polymer composition; and
grafting component (A) or components (A) and (B) with component (C) during the compounding step;
characterized in that the process further comprises the step of
independently controlling the temperature of each control zone of the plurality of control zones of the barrel section of the extruder as such that
a) the temperature in the first control zone of the barrel section downstream of the feeding section is in the range of from higher than 85° C. to 180° C.,
b) the temperature of the control zones of the barrel section from the first control zone of the barrel section downstream the feeding section to the control zone in the middle of the barrel section is increased over the length of the barrel section in two or more steps so that the temperature of the control zone in the middle of the barrel section is from 105% to 145% of the temperature in the first control zone of the barrel section downstream of the feeding section; and
c) the temperature of the control zones of the barrel section from control zone in the middle of the barrel section to the control zone of the barrel section directly upstream of the die plate in maintained at the same temperature or increased to a temperature of not more than 120% of the temperature of the control zone in the middle of the barrel section.

12. A multi-layer structure comprising one layer comprising the polymer composition according to claim 1 .

13. The multi-layer structure according to claim 12 being a three-layer coating of a metal pipe.

14. The multi-layer structure according to claim 12 having a peel strength at 23° C. of at least 200 N/cm and/or a peel strength at 80° C. of at least 100 N/cm.

15. The polymer composition according to claim 1 being an adhesive polymer composition.

16. The polymer composition according to claim 15 comprised in a multi-layer structure.

Assignees

• Borealis Ag

Inventors

• Jamieson John
• Ruskeeniemi Jari-Jussi
• Prades Floran
• Ajellal Noureddine
• Sundholm Tua
• Purmonen Jouni
• Legras Angelica Maëlle Delphine
• Klimke Katja
• Albrecht Andreas

Classifications

• C09J2463/006

  in the substrate · CPC title

• C09J2451/00

  Presence of graft polymer · CPC title

• C09J2423/046

  in the substrate · CPC title

• C09J151/06 Primary

  grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond · CPC title

• C08L2203/18

  used for pipes · CPC title