Lithium ion secondary battery

Patent metadata

Field	Value
Publication number	US-12199235-B2
Application number	US-202318097593-A
Country	US
Kind code	B2
Filing date	Jan 17, 2023
Priority date	Apr 30, 2019
Publication date	Jan 14, 2025
Grant date	Jan 14, 2025

Abstract

A lithium ion secondary battery is provided. The lithium ion secondary battery includes an electrolytic tank having an accommodating space, a positive electrode disposed in the accommodating space, a negative electrode disposed in the accommodating space and spaced apart from the positive electrode, and an isolation film disposed between the positive electrode and the negative electrode. In the X-ray diffraction spectrum of a first surface of the electrolytic copper foil, a ratio of the diffraction peak intensity I(200) of the (200) crystal face of the first surface relative to the diffraction peak intensity I(111) of the (111) crystal face of the first surface is between 0.5 and 2.0. A ratio of the diffraction peak intensity I(200) of the (200) crystal face of a second surface relative to the diffraction peak intensity I(111) of the (111) crystal face of the second surface is between 0.5 and 2.0.

First claim

What is claimed is:

1. A lithium ion secondary battery, comprising:
an electrolytic tank having an accommodating space for accommodating an electrolytic solution;
a positive electrode disposed in the accommodating space of the electrolytic tank;
a negative electrode disposed in the accommodating space of the electrolytic tank and spaced apart from the positive electrode; wherein the negative electrode includes an electrolytic copper foil, and the electrolytic copper foil has a first surface and a second surface opposite to the first surface; and
an isolation film disposed between the positive electrode and the negative electrode;
wherein in an X-ray diffraction spectrum of the first surface of the electrolytic copper foil, a ratio of a diffraction peak intensity I(200) of a (200) crystal face of the first surface relative to a diffraction peak intensity I(111) of a (111) crystal face of the first surface is between 0.5 and 2.0;
wherein in an X-ray diffraction spectrum of the second surface of the electrolytic copper foil, a ratio of a diffraction peak intensity I(200) of a (200) crystal face of the second surface relative to a diffraction peak intensity I(111) of a (111) crystal face of the second surface is between 0.5 and 2.0;
wherein the first surface is a surface that is in contact with a rotating electrode drum during a plating process and is defined as an S surface; and the second surface is a surface that is opposite to the S surface and is defined as an M surface; wherein in an X-ray diffraction spectrum of the S surface, a ratio of a diffraction peak intensity I(200) of a (200) crystal face of the S surface relative to a diffraction peak intensity I(111) of a (111) crystal face of the S surface is defined as a first diffraction peak intensity ratio; and in an X-ray diffraction spectrum of the M surface, a ratio of a diffraction peak intensity I(200) of a (200) crystal face of the M surface relative to a diffraction peak intensity I(111) of a (111) crystal face of the M surface is defined as a second diffraction peak intensity ratio; wherein the first diffraction peak intensity ratio is less than the second diffraction peak intensity ratio; and
wherein an absolute value of a difference between the first diffraction peak intensity ratio and the second diffraction peak intensity ratio is not less than 0.01 and not more than 0.30.

2. The lithium ion secondary battery according to claim 1 , wherein a distance between the first surface and the second surface is defined as a thickness of the electrolytic copper foil, and the thickness is between 2 μm and 20 μm.

3. The lithium ion secondary battery according to claim 1 , the electrolytic copper foil has a tensile strength between 28 kgf/mm 2 and 40 kgf/mm 2 and an elongation not less than 7% before a heat treatment process.

4. The lithium ion secondary battery according to claim 3 , wherein the electrolytic copper foil has a tensile strength between 25 kgf/mm 2 and 35 kgf/mm 2 and an elongation not less than 9.5% after the heat treatment process; wherein the heat treatment process includes: baking the electrolytic copper foil at a temperature between 130° C. and 250° C. for 0.5 hours to 1.5 hours.

5. The lithium ion secondary battery according to claim 1 , wherein the electrolytic copper foil further includes:
a first oxidation resistant layer disposed on the first surface; and
a second oxidation resistant layer disposed on the second surface;
wherein based on a total weight of the electrolytic copper foil, each of the first oxidation resistant layer and the second oxidation resistant layer includes a non-copper metal element in an amount ranging from 1 ppm to 1,000 ppm; wherein the non-copper metal element is at least one element selected from the group consisting of chromium, zinc, nickel, molybdenum, manganese, phosphorus, and combinations thereof.

6. The lithium ion secondary battery according to claim 1 , wherein the electrolytic copper foil further includes: a plurality of crystal grains distributed between the first surface and the second surface; wherein before a heat treatment process, each crystal grain has a grain size between 20 nm and 45 nm; wherein a grain size of each crystal grain that is treated by the heat treatment process is between 90% and 130% of a grain size of each crystal grain that is not treated by the heat treatment process.

Assignees

• Nan Ya Plastics Corp

Inventors

• Chen Chia-Ling
• Tzou Ming-Jen

Classifications

• H01M4/045

  Electrochemical coating; Electrochemical impregnation · CPC title

• H01M4/0438

  by electrochemical processing (electroless electrochemical plating C23C18/54) · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• C25D3/38

  of copper · CPC title

• H01M4/0471

  involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis · CPC title