Optical element comprising mix of NIR dyes for broader NIR cut and better aesthetic

Patent metadata

Field	Value
Publication number	US-12196989-B2
Application number	US-202017442473-A
Country	US
Kind code	B2
Filing date	Mar 23, 2020
Priority date	Mar 25, 2019
Publication date	Jan 14, 2025
Grant date	Jan 14, 2025

Abstract

Disclosed are optical elements that contains two or more near infrared absorbers and methods of producing the same. Two near infrared absorbers with different near infrared wavelengths absorption ranges and residual colors are mixed with a precursor of an optical substrate. The resulting mixture is subsequently processed to produce optical elements that have a broad near infrared wavelength absorption range and a neutral residual color.

First claim

The invention claimed is:

1. An ophthalmic lens comprising an optical substrate and two or more near infrared absorbers mixed in the optical substrate, wherein the two or more near infrared absorbers have different near infrared cut ranges and different residual colors; wherein the two or more near infrared absorbers in the optical substrate are adapted to generate a synergistic color intensity that is lower than individual color intensity of each of the two or more near infrared absorbers; and wherein the ophthalmic lens exhibits infrared absorbing ability.

2. The ophthalmic lens of claim 1 , wherein the two or more near infrared absorbers are mixed in the optical substrate substantially homogenously.

3. The ophthalmic lens of claim 1 , wherein the two or more near infrared absorbers in the optical substrate are adapted to generate a synergistic infrared absorption level that is higher than individual near infrared absorption level of any of the two or more near infrared absorbers.

4. The ophthalmic lens of claim 1 , wherein the two or more near infrared absorbers in the optical substrate are adapted to generate a synergistic infrared absorption range that is broader than individual infrared absorption range of each of the two or more near infrared absorbers.

5. The ophthalmic lens of claim 1 , wherein the two or more near infrared absorbers in the optical substrate are synergistically neutral colored.

6. The ophthalmic lens of claim 1 , wherein the two or more near infrared absorbers are adapted to synergistically cause less than 10% reduction on the average optical transmittance in the 380-780 nm wavelength range for the ophthalmic lens.

7. The ophthalmic lens of claim 1 , wherein the optical substrate comprises allyl diglycol carbonate, polyurethane, acrylic, polycarbonate, polyamide, poly(methyl methacrylate), co-polyester, cellulose triacetate, polyepisulfides, trivex, polyacrylics, polyols, polyamines, polyanhydrides, polycarboxilic acids, polyepoxides, polyisocyanates, polynorbornenes, polysiloxanes, polysilazanes, polystyrenes, polyolefinics, polyesters, polyimides, polyurethanes, polythiourethanes, polyallylics, polysulfides, polyvinylesters, polyvinylethers, polyarylenes, polyoxides, polysulfones, poly cyclo olefins, polyacrylonitriles, polyethylene terephtalates, polyetherimides, polypentenes, or any combinations thereof.

8. The ophthalmic lens of claim 1 , wherein the two or more near infrared absorbers comprise polymethine, phthalocyanine, porphyrine, triphenylmethane, iminium, squarylium, croconium, dithiolene, quinone, polyperylene, pyrilium, thiopyrilium, cyanine, or any combination thereof.

9. The ophthalmic lens of claim 1 , wherein the optical substrate comprises 1 to 500 ppm of the two or more near infrared absorbers.

10. A method of preparing the ophthalmic lens of claim 1 , the method comprising:
providing a precursor material for the optical substrate and the two or more near infrared absorbers that have different near infrared cut ranges and/or different residual colors;
determining a concentration for each of the two or more infrared absorbers in the optical substrate, at which the synergistic color intensity of the two or more near infrared absorbers is lower than the individual color intensity of any of the two or more near infrared absorbers;
mixing the precursor material with the two or more infrared absorbers at the determined concentrations to produce a substantially homogenous mixture; and
producing the ophthalmic lens using the mixture of the optical substrate and the two or more near infrared absorbers.

11. The method of claim 10 , wherein the producing step comprises casting, injection molding, extrusion compression molding, compression molding, transfer molding, 3D printing, or any combination thereof.

12. The method of claim 10 , further comprising mixing one or more of an ultraviolet light absorbing dye, a color balancing dye, a color enhancing dye, a blue light absorbing dye, and other visible light absorbing dyes with the precursor material before the producing step.

13. A method of preparing the ophthalmic lens of claim 1 , the method comprising:
providing a precursor material for the optical substrate and two or more near infrared absorbers that have different near infrared cut ranges and/or different residual colors;
determining a concentration for each of the two or more infrared absorbers in the substrate, at which synergistic color intensity of two or more near infrared absorbers is lower than the individual color intensity of any of the two or more near infrared absorbers;
dissolving the two or more infrared absorbers in a first amount of the precursor material to produce a near infrared dye master batch;
mixing a second amount of the precursor material with one or more of an ultraviolet dye, a monomer, a catalyst, and a releasing agent at a temperature of 23 to 27° C. under vacuum to produce a first mixture that is substantially homogenous;
cooling the first mixture to a temperature of 0 to 4° C.;
flowing an inert gas over the cooled first mixture;
mixing the near infrared dye master batch into the first mixture under vacuum at a temperature of 0 to 4° C. to produce a second mixture, which is a substantially homogenous mixture with each of the two or more near infrared absorbers at its determined concentration; and
producing the ophthalmic lens using the second mixture via casting.

14. The ophthalmic lens of claim 1 , wherein the two or more near infrared absorbers in the optical substrate are achromatic.

Assignees

• Essilor Int

Inventors

• Fromentin Pierre
• Waipunya Harutsai
• Shan Haifeng
• Chiu Hao-Wen

Classifications

• G02C7/108

  Colouring materials · CPC title

• G02B5/223 Primary

  containing organic substances, e.g. dyes, inks or pigments · CPC title

• G02B5/206

  comprising particles embedded in a solid matrix · CPC title

• G02B1/041

  Lenses · CPC title

• G02B5/208 Primary

  for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation · CPC title