Fully miscible antifoam formulations

Patent metadata

Field	Value
Publication number	US-12195693-B2
Application number	US-202218280389-A
Country	US
Kind code	B2
Filing date	May 26, 2022
Priority date	May 27, 2021
Publication date	Jan 14, 2025
Grant date	Jan 14, 2025

Abstract

Miscible antifoams are provided that do not separate out of a target liquid and that are easy to incorporate in the target liquid. A method or system involves mixing a liquid (‘a miscible antifoam’) into a target foaming liquid. This miscible antifoam is engineered/chosen such that it has both a higher surface tension and is more volatile than the target liquid, or engineered such that it has both a lower surface tension and is less volatility than the target liquid. The miscible antifoam leads to surface tension gradients that cause bubble rupture up to 10 times faster than the target liquid without the antifoam. Further, the miscible antifoams are easy to incorporate and do not separate out from the target liquid during operation—both of which are key limitations faced by existing antifoams.

First claim

What is claimed is:

1. A method of controlling foam using a miscible antifoam formulation, comprising:
(a) having a target liquid having a target liquid surface tension and a target liquid volatility; and
(b) selecting an antifoam liquid having an antifoam liquid surface tension and an antifoam liquid volatility,
wherein in the steps (a) and (b) ensuring that the antifoam liquid surface tension and the antifoam liquid volatility are both lower than the target liquid surface tension and the target liquid volatility, or
wherein in the steps (a) and (b) ensuring that the antifoam liquid surface tension and antifoam liquid volatility are both higher than the target liquid surface tension and target liquid volatility; and

(c) mixing the target liquid and the antifoam liquid to create the miscible antifoam formulation,
wherein, as a result of the selecting step of the antifoam liquid surface tension and the antifoam liquid volatility, foam of the target liquid is controlled by evaporation-induced Marangoni flows due to a positive surface tension gradient.

2. The method as set forth in claim 1 , wherein in the mixing step controlling volume concentrations for the antifoam liquid are between 0.5% and 5% and the target liquid are between 99.5% and 95%.

3. The method as set forth in claim 1 , wherein the antifoam liquid is Kerosene, Toluene, Xylene, or a combination thereof.

4. The method as set forth in claim 1 , wherein the target liquid is a lubricant or a diesel fuel.

5. The method as set forth in claim 1 , wherein the target liquid is a diesel fuel and the antifoam liquid is Toluene or Xylene.

6. The method as set forth in claim 1 , wherein the target liquid is a lubricant and the antifoam liquid is Kerosene.

Assignees

• Univ Leland Stanford Junior

Inventors

• Chandran Suja Vineeth
• Fuller Gerald G
• Calhoun Suzanne G K

Classifications

• C10N2030/18

  Anti-foaming property · CPC title

• C10M2229/025

  used as base material · CPC title

• C10M2203/10

  Petroleum or coal fractions, e.g. tars, solvents, bitumen · CPC title

• C10M2203/06

  Well-defined aromatic compounds · CPC title

• C10M127/06

  Alkylated aromatic hydrocarbons · CPC title