Process for converting organosilanes

Patent metadata

Field	Value
Publication number	US-12195486-B2
Application number	US-201917625128-A
Country	US
Kind code	B2
Filing date	Nov 14, 2019
Priority date	Jul 10, 2019
Publication date	Jan 14, 2025
Grant date	Jan 14, 2025

Abstract

A method for converting organosilanes by reacting at least one silane (1) of the general formula

R a SiCl 4-a   (I)

with at least one further silane (2) of the general formula

R b SiCl 4-b   (II)

wherein silane (2) is identical or different from silane (1), optionally with additional use of silanes (3) which contain Si-bonded hydrogen and have the formula

R d H e SiCl 4-d-e   (III)

in the presence of aluminum salts, preferably aluminum halides, as catalysts and in the presence of cocatalysts, to obtain at least one silane (4) which differs from silanes (1) and (2) and has the general formula

R c SiCl 4-c   (IV).

First claim

The invention claimed is:

1. A method for converting organosilanes by reacting at least one silane (1) of the general formula
R a SiCl 4-a   (I)

with at least one further silane (2) of the general formula
R b SiCl 4-b   (II)

wherein silane (2) is identical or different from silane (1),
optionally with additional use of silanes (3) which contain Si-bonded hydrogen and have the formula
R a H e SiCl 4-d-e   (III)

in the presence of aluminum salts, as catalysts and in the presence of cocatalysts,
to obtain at least one silane (4) which differs from silanes (1) and (2) and has the general formula
R c SiCl 4-c   (IV),

wherein R denotes in each case identical or different alkyl radicals having 1 to 4 carbon atoms or a phenyl radical,
a is 2, 3 or 4,
b is 0, 1, 2 or 3,
c is 1, 2 or 3,
d is 0, 1, 2 or 3 and
e is 1, 2 or 3,
with the proviso that the sum total of d+e is at most 4,
characterized in that the cocatalysts used are those selected from the group of trifluoromethanesulfonic acid, trifluoromethanesulfonic esters, aluminum tris(trifluoromethanesulfonate), metal salts of yttrium and hafnium, metal salts of the lanthanides and actinides, and mixtures of these cocatalysts.

2. The method as claimed in claim 1 , characterized in that the catalyst used is aluminum trichloride.

3. The method as claimed in claim 2 , characterized in that aluminum trichloride is either used as such or is produced in situ.

4. The method as claimed in claim 2 , characterized in that aluminum trichloride is produced in situ from ethylaluminum sesquichloride and hydrogen chloride.

5. The method as claimed in claim 1 , characterized in that, as the metal salts of yttrium or hafnium or of the lanthanides and actinides, use is made of halides; sulfonates; oxides or carboxylates.

6. The method as claimed in claim 1 , characterized in that the metals of the lanthanides and actinides that are used are lanthanum, cerium, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium or lutetium.

7. The method as claimed in claim 1 , characterized in that the metal salts used are yttrium trichloride, cerium trichloride, neodymium trichloride, gadolinium trifluoride, gadolinium trichloride, gadolinium tribromide, gadolinium (III) acetate, terbium trichloride, holmium trichloride or lutetium trichloride.

8. The method as claimed in claim 1 , characterized in that aluminum salts are used in amounts of from 0.2% to 10% by weight, based in each case on the total weight of silanes (1) and (2) used.

9. The method as claimed in claim 1 , characterized in that cocatalysts are used in amounts of 0.002% to 2.5% by weight, based in each case on the total weight of silanes (1) and (2) used.

10. The method as claimed in claim 1 , characterized in that the silane (1) used is tetramethylsilane, trimethylchlorosilane, dimethyldichlorosilane and phenyltrichlorosilane.

11. The method as claimed in claim 1 , characterized in that the silane (2) used is dimethyldichlorosilane, methyltrichlorosilane and tetrachlorosilane.

12. The method as claimed in claim 1 , characterized in that the silane (1) used is tetramethylsilane and the silane (2) used is dimethyldichlorosilane, with trimethylchlorosilane being obtained.

13. The method as claimed in claim 1 , characterized in that the silane (1) used is tetramethylsilane and the silane (2) used is tetrachlorosilane, with trimethylchlorosilane being obtained.

Assignees

• Wacker Chemie Ag

Inventors

• Betschinger Frank
• Bockholt Andreas
• Böck Manfred
• Fleischmann Gerald
• Käppler Klaus

Classifications

• C07F7/125 Primary

  by reactions involving both Si-C and Si-halogen linkages, the Si-C and Si-halogen linkages can be to the same or to different Si atoms, e.g. redistribution reactions · CPC title