Solid state tunable ionic oscillator dielectric materials and resonant devices

Patent metadata

Field	Value
Publication number	US-12193333-B2
Application number	US-201917264726-A
Country	US
Kind code	B2
Filing date	Aug 1, 2019
Priority date	Aug 1, 2018
Publication date	Jan 7, 2025
Grant date	Jan 7, 2025

Abstract

An article comprising a ferroelectric material in its ferroelectric phase, wherein the article is configured to enable low-loss propagation of signals with ultra-low dielectric loss at one or more select frequencies.

First claim

What is claimed is:

1. An article comprising a ferroelectric material including a high density of one or more fluctuating ferroelectric domain walls, wherein the article contains one or more fluctuating ferroelectric domain walls that enable efficient propagation of signals with ultra-low dielectric loss, the ultra-low dielectric loss comprising a range of 10 3 <Q<10 7 , or 10 −3 >tanδ>10 −7 , wherein Q refers to a quality factor, at one or more select frequencies, wherein the density of domain walls ranges from 1-100 per 50,000 nm 2 .

2. The article of claim 1 , wherein the article is configured to enable low-loss propagation of signals with ultra-low dielectric loss, the ultra-low dielectric loss comprising a range of 10 3 <Q<10 7 , or 10 −3 >tanδ>10 −7 , at or within 20% of the ferroelectric phase transition temperature T C of the ferroelectric material.

3. The article of claim 1 , wherein the one or more select frequencies are between 0.01 GHz and 300 GHz.

4. An article comprising a ferroelectric material in thin film form in its ferroelectric phase, wherein the composition and strain of the material are selected to stabilize the material, for a given temperature, in or about two or more energetically equivalent thermodynamically predicted domain wall variant types as specified by a domain wall variant boundary or vertex of intersecting boundaries, thereby enabling efficient propagation of signals with ultra-low dielectric loss, the ultra-low dielectric loss comprising a range of 10 3 <Q<10 7 , or 10 −3 >tanδ>10 −7 , wherein Q refers to a quality factor, at select frequencies.

5. The article of claim 4 , wherein at least one of a range and values of at least one of fluctuation frequency and frequencies are controlled based on changes in fluctuating ferroelectric domain wall oscillation frequency in response to electric field applied to the ferroelectric material.

6. The article of claim 4 , wherein the one or more select frequencies are between 0.01 GHz and 300 GHz.

7. The article of claim 4 , wherein at least one of a range and values of at least one of fluctuation frequency and frequencies of the article are controlled based on the density of fluctuating ferroelectric domain walls.

8. The article of claim 4 , wherein the magnitude of the quality factor Q is controlled by the density of fluctuating ferroelectric domain walls and increases with domain wall density.

9. The article of claim 4 , wherein the at least one of a range and values of at least one of fluctuation frequency and frequencies are controlled based on at least one of the type and types of fluctuating ferroelectric domain wall variants.

10. The article of claim 4 , wherein the at least one of a range and values of at least one of fluctuation frequency and frequencies are controlled based on the degree of strain.

11. The article of claim 4 , wherein ferroelectric material is in a phase comprising one of: normal ferroelectric, improper ferroelectric, hybrid improper ferroelectric, or multi-ferroic ferromagnetic or antiferromagnetic ferroelectric.

12. The article of claim 4 , wherein the at least one of a range and values of at least one of fluctuation frequency and frequencies are controlled based on changes in fluctuating ferroelectric domain wall oscillation in response to magnetic field applied across the multiferroic ferromagnetic, or antiferromagnetic, ferroelectric material due to multiferroic coupling of magnetic field to ferroelectric polarization.

13. The article of claim 4 , wherein the ferroelectric material has 1-100 per 40,000 nm 2 of engineered planar two-dimensional topological defects that, under selected electric DC bias or zero electric DC bias, oscillate at the one or more select frequencies and within 100 degrees C. of the T C of the ferroelectric material.

14. The article of claim 13 , wherein the select frequencies are between 0.1 GHz and 300 GHz.

15. The article of claim 13 , wherein the planar two-dimensional topological defects comprise fluctuating ferroelectric domain walls, and wherein the fluctuating ferroelectric domain walls, under the application of a DC or AC electric field or under zero DC or AC electric field, oscillate or fluctuate in their position with respect to time.

16. The article of claim 15 , wherein the timescale or rate of the fluctuations vary depending upon the electrostatic potential landscape and domain width or at least one of fluctuating ferroelectric domain wall density, applied field, temperature, coherent strain, relaxed strain, and stress.

17. The article of claim 4 , wherein ferroelectric material comprises perovskites, Ba x Sr 1-x TiO 3 (BST x ), PbTiO 3 , Pb(Zr,Ti)O 3 , (Pb,Sr)TiO 3 , BiFeO 3 , Bi(Fe,Mn)O 3 , or Ruddelson-Popper phases A n+1 B n X 3n+1 , or Ruddelson-Popper phases A n+1 A′ 2 B n X 3n+1 where A and A′ represent alkali and/or alkaline earth metals, and B denotes a rare earth metal, and X=O or other ferroelectrics, or a combination thereof.

18. A method of making the article of claim 4 .

19. A resonator comprising the article of claim 4 .

Assignees

• Univ Drexel
• Univ Bar Ilan
• Univ California

Inventors

• Spanier Jonathan E
• Gu Zongquan
• Grinberg Ilya
• Samanta Atanu
• Barak Haim
• Meyers Cedric J G
• York Robert A

Classifications

• H10N30/8561

  Bismuth-based oxides · CPC title

• H10N30/8536 Primary

  Alkaline earth metal based oxides, e.g. barium titanates · CPC title

• H01P7/10

  Dielectric resonators · CPC title

• H10N30/8548

  Lead-based oxides · CPC title

• H10N30/8554 Primary

  Lead-zirconium titanate [PZT] based · CPC title