Lithium-sulfur battery including a cathode formed from multiple adjacent carbonaceous regions

Patent metadata

Field	Value
Publication number	US-12191491-B2
Application number	US-202217693984-A
Country	US
Kind code	B2
Filing date	Mar 14, 2022
Priority date	Jul 23, 2021
Publication date	Jan 7, 2025
Grant date	Jan 7, 2025

Abstract

A cathode with one or more carbonaceous regions positioned adjacent to one another. At least one region includes carbonaceous particles, where each particle includes carbon fragments and a deformable perimeter that may coalesce with adjacent particles. At least one region may include aggregates, where each aggregate may be formed of several particles joined to one another. Pores may be interspersed throughout the aggregates. At least one region may include agglomerates, where each agglomerate may be formed of a multitude of the aggregates joined to one other. At least one region has an electrical conductivity in an approximate range between 500 S/m to 20,000 S/m at a pressure of 12,000 pounds per square in (psi).

First claim

What is claimed is:

1. A cathode for a battery, wherein the cathode includes one or more regions positioned adjacent to one another, at least one region including:
a plurality of carbonaceous particles configured to coalesce with adjacent carbonaceous particles, each carbonaceous particle including:
a plurality of porous regions nested within each other, wherein each of the respective porous regions is characterized by one or more of a corresponding porosity or a corresponding pore density;
a plurality of carbon fragments disposed across the plurality of porous regions, wherein each carbon fragment is separated from an adjacent carbon fragment by mesopores; and
a deformable perimeter:

a plurality of aggregates, each aggregate formed of several carbonaceous particles joined to one another;
a plurality of pores interspersed throughout the plurality of aggregates; and
a plurality of agglomerates, each agglomerate formed of a multitude of the aggregates joined to one other.

2. The cathode of claim 1 , wherein the at least one region further includes a permeable shell configured to form a separated liquid phase on the permeable shell.

3. The cathode of claim 1 , further comprising at least one electrically conductive region.

4. The cathode of claim 1 , wherein the at least one region has an electrical conductivity in an approximate range between 500 S/m to 20,000 S/m at a pressure of 12,000 pounds per square in (psi).

5. The cathode of claim 1 , further comprising at least one polymer-based binder dispersed throughout the at least one region, the at least one polymer-based binder configured to adhere adjacent aggregates to one another.

6. The cathode of claim 1 , wherein the plurality porous regions nested within each other includes:
a first porosity region located at and around a center of the respective carbonaceous particle; and
a second porosity region surrounding the first porosity region.

7. The cathode of claim 6 , wherein the first porosity region has a first pore density, and the second porosity region has a second pore density.

8. The cathode of claim 7 , wherein the second pore density is different than the first pore density.

9. The cathode of claim 1 , further comprising one or more additional porous regions positioned adjacent to and coupled with the one or more regions of the cathode.

10. The cathode of claim 9 , wherein the one or more additional porous regions are arranged in order of incrementally decreasing concentration levels of materials relative to the one or more regions of the cathode.

11. The cathode of claim 1 , wherein at least some pores of the plurality of pores include sulfur.

12. The cathode of claim 11 , wherein the cathode has a sulfur to carbon weight ratio between approximately 1:5 and 10:1.

13. The cathode of claim 1 , further comprising one or more electrically conductive additives dispersed within the one or more regions of the cathode.

14. The cathode of claim 1 , further comprising a protective sheath disposed on the cathode.

15. The cathode of claim 14 , wherein the protective sheath comprises a tri-functional epoxy compound and a di-amine oligomer-based compound, the tri-functional epoxy compound and the di-amine oligomer-based compound being configured to chemically react with each other.

16. The cathode of claim 15 , wherein the tri-functional epoxy compound is one or more of trimethylolpropane triglycidyl ether (TMPTE), tris(4-hydroxyphenyl) methane triglycidyl ether, or tris(2,3-epoxypropyl) isocyanurate.

17. The cathode of claim 15 , wherein the protective sheath is configured to prevent polysulfide migration within a lithium-sulfur battery associated with the cathode, based on chemical bonding between the protective sheath and one or more lithium-containing polysulfide intermediates generated during operational discharge-charge cycling of the lithium-sulfur battery.

Assignees

• Lyten Inc

Inventors

• Lanning Bruce
• Stowell Michael W
• Gazda Jerzy
• Bell Jeffrey
• Kumar Anurag

Classifications

• H01M4/04

  Processes of manufacture in general · CPC title

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• H01M4/622

  being polymers · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/58

  of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates · CPC title