Methods for reducing condensation

Patent metadata

Field	Value
Publication number	US-12188074-B2
Application number	US-202017030914-A
Country	US
Kind code	B2
Filing date	Sep 24, 2020
Priority date	Sep 30, 2019
Publication date	Jan 7, 2025
Grant date	Jan 7, 2025

Abstract

A method for reducing condensate in a subsurface formation is disclosed. The method includes introducing a reactive mixture including an aqueous solution, urea, dopamine, a silica nanoparticle precursor, a silane grafting compound, and an alcohol compound into the subsurface formation. The method also includes allowing generation of ammonia through thermal decomposition of the urea and allowing the silica nanoparticle precursor to hydrolyze, thereby forming silica nanoparticles. The method further includes allowing the silane grafting compound to graft onto the silica nanoparticles, thereby forming functionalized silica nanoparticles. The method also includes allowing polymerization of the dopamine, thereby forming polydopamine. The method also includes allowing the functionalized silica nanoparticles to attach to the subsurface formation via the polydopamine, thereby reducing condensate in the subsurface formation.

First claim

What is claimed is:

1. A method for reducing condensate in a subsurface formation, the method comprising:
introducing a reactive mixture comprising an aqueous solution, urea, dopamine, a silica nanoparticle precursor, a silane grafting compound, and an alcohol compound into the subsurface formation;
generating ammonia through thermal decomposition of the urea;
hydrolyzing the silica nanoparticle precursor, thereby forming silica nanoparticles;
grafting the silane grafting compound onto the silica nanoparticles, thereby forming functionalized silica nanoparticles;
polymerizing the dopamine, thereby forming polydopamine; and
attaching the functionalized silica nanoparticles to the subsurface formation via the polydopamine, thereby reducing condensate in the subsurface formation.

2. The method of claim 1 , in which the reactive mixture is in a single aqueous solution.

3. The method of claim 1 , in which introducing the reactive mixture comprises introducing the aqueous solution, urea, and dopamine into the subsurface formation separately from the silica nanoparticle precursor, the silane grafting compound, and the alcohol compound.

4. The method of claim 1 , further comprising introducing a buffer solution with the reactive mixture into the subsurface formation.

5. The method of claim 1 , in which attaching the functionalized silica nanoparticles to the subsurface formation thereby increases a water contact angle, an oil contact angle, or both on the subsurface formation from less than 90° to greater than or equal to 90°.

6. The method of claim 1 , in which the subsurface formation has a temperature of greater than or equal to 70° C.

7. The method of claim 1 , in which the silica nanoparticle precursor comprises a tetraalkyl orthosilicate.

8. The method of claim 1 , in which the silica nanoparticle precursor comprises tetramethyl orthosilicate, tetraethyl orthosilicate, tetrapropyl orthosilicate, tetrabutyl orthosilicate, glycidoxypropyltrimethoxysilane, aminopropyltriethoxysilane, (methacryloxy) propyltrimethoxysilane, 3 acrylamidopropyltrimethoxysilane, 4 aminobutryltriethoxysilane, aminophenyltrimethoxysilane, carboxyethylsilanetriol sodium, 4 bromobutyltrimethoxysilane, 2 (chloromethyl) allyltrimethoxysilane, hydroxymethyltriethoxysilane, 3 isocyanotopropyltrimethoxysilane, 3 mercaptopropyltrimethoxysilane, or allyltrimethoxysilane, or combinations of these.

9. The method of claim 1 , in which the silane grafting compound comprises fluorine, chlorine, bromine, iodine, or combinations of these attached to a silane group.

10. The method of claim 1 , in which the silane grafting compound comprises perfluorooctyltriethoxysilane, perfluorooctyltrichlorosilane, nanofluorohexyltrichlorosilane, tridecafluoro-1,1,2,2-tetrahydrooctyltrichlorosilane, heptadecafluoro-1,1,2,2-tetrahydrodecyltrichlorosilane, 1H,1H,2H,2H-perfluorodecyltriethoxysilane, perfluorodecyltrichlorosilane, or combinations of these.

11. The method of claim 1 , in which the alcohol compound comprises butanol.

12. A method for increasing a rate of hydrocarbon production from a subsurface formation, the method comprising:
producing a first rate of production of hydrocarbons from the subsurface formation through a wellbore;
introducing a reactive mixture comprising an aqueous solution, urea, dopamine, a silica nanoparticle precursor, a silane grafting compound, and an alcohol compound into the subsurface formation;
generating ammonia through thermal decomposition of the urea;
hydrolyzing the silica nanoparticle precursor, thereby forming silica nanoparticles;
grafting the silane grafting compound onto the silica nanoparticles, thereby forming functionalized silica nanoparticles;
polymerizing the dopamine, thereby forming polydopamine;
attaching the functionalized silica nanoparticles to the subsurface formation via the polydopamine, in which the functionalized silica nanoparticles reduce a first interfacial tension between the hydrocarbons and the subsurface formation to a second interfacial tension, thereby reducing condensate in the subsurface formation; and
increasing hydrocarbon production from the subsurface formation by producing a second rate of production of hydrocarbons from the subsurface formation, in which the second rate of production of hydrocarbons is greater than the first rate of production of hydrocarbons.

13. The method of claim 12 , in which the reactive mixture is in a single aqueous solution.

14. The method of claim 12 , in which introducing the reactive mixture comprises introducing the aqueous solution, urea, and dopamine into the subsurface formation separately from the silica nanoparticle precursor, the silane grafting compound, and the alcohol compound.

15. The method of claim 12 , in which attaching the functionalized silica nanoparticles to the subsurface formation thereby increases a water contact angle, an oil contact angle, or both on the subsurface formation from less than 90° to greater than or equal to 90°.

16. The method of claim 12 , in which the subsurface formation has a temperature of greater than or equal to 70° C.

17. The method of claim 12 , in which the silica nanoparticle precursor comprises tetramethyl orthosilicate, tetraethyl orthosilicate, tetrapropyl orthosilicate, tetrabutyl orthosilicate, glycidoxypropyltrimethoxysilane, aminopropyltriethoxysilane, (methacryloxy) propyltrimethoxysilane, 3 acrylamidopropyltrimethoxysilane, 4 aminobutryltriethoxysilane, aminophenyltrimethoxysilane, carboxyethylsilanetriol sodium, 4 bromobutyltrimethoxysilane, 2 (chloromethyl) allyltrimethoxysilane, hydroxymethyltriethoxysilane, 3 isocyanotopropyltrimethoxysilane, 3 mercaptopropyltrimethoxysilane, or allyltrimethoxysilane, or combinations of these.

18. The method of claim 12 , in which the silane grafting compound comprises fluorine, chlorine, bromine, iodine, or combinations of these attached to a silane group.

19. The method of claim 12 , in which the silane grafting compound comprises perfluoroalkyltriethoxysilane, perfluorooctyltriethoxysilane, perfluorooctyltrichlorosilane, nanofluorohexyltrichlorosilane, tridecafluoro-1,1,2,2-tetrahydrooctyltrichlorosilane, heptadecafluoro-1,1,2,2-tetrahydrodecyltrichlorosilane, 1H,1H,2H,2H-perfluorodecyltriethoxysilane, perfluorodecyltrichlorosilane, or combinations of these.

20. The method of claim 12 , in which the alcohol compound comprises butanol.

Assignees

• Saudi Arabian Oil Co

Inventors

• Wang Wei
• Ow Hooisweng
• Chang Sehoon

Classifications

• E21B43/241

  combined with solution mining of non-hydrocarbon minerals, e.g. solvent pyrolysis of oil shale · CPC title

• C08G61/124

  with a five-membered ring containing one nitrogen atom in the ring · CPC title

• C01P2004/64

  Nanometer sized, i.e. from 1-100 nanometer · CPC title

• C01C1/086

  from urea · CPC title

• C01B33/12

  Silica; Hydrates thereof, e.g. lepidoic silicic acid · CPC title