Carbon nanotube enhanced polymers and methods for manufacturing the same

Patent metadata

Field	Value
Publication number	US-12187871-B2
Application number	US-201715825745-A
Country	US
Kind code	B2
Filing date	Nov 29, 2017
Priority date	Aug 25, 2017
Publication date	Jan 7, 2025
Grant date	Jan 7, 2025

Abstract

A carbon nanotube enhanced polymer includes a polymer and a plurality of carbon nanotube sheetlets mixed with the polymer. The carbon nanotube sheetlets each include a network of intertwined carbon nanotubes.

First claim

What is claimed is:

1. A carbon nanotube enhanced polymer comprising:
a polymer powder; and
a plurality of carbon nanotube sheets in admixture with the polymer powder to yield a mixture, wherein each carbon nanotube sheet of the plurality of carbon nanotube sheets has a length in a range of 0.1 to 10,000 μm, and wherein each carbon nanotube sheet of the plurality of carbon nanotube sheets consists of a network of intertwined carbon nanotubes that are intertwined with each other to form a shape of the carbon nanotube sheet such that the network of intertwined carbon nanotubes holds the shape of the carbon nanotube sheet by way of the intertwining of the carbon nanotubes.

2. The carbon nanotube enhanced polymer of claim 1 wherein the polymer powder is selected from the group consisting of: polyetherketoneketone (PEKK), polyphenylene sulfide (PPS), polyamide 11, and combinations thereof.

3. The carbon nanotube enhanced polymer of claim 1 wherein each carbon nanotube sheet of the plurality of carbon nanotube sheets has the length in a range of 10 to 1000 μm.

4. The carbon nanotube enhanced polymer of claim 1 wherein each carbon nanotube sheet of the plurality of carbon nanotube sheets has the length in a range of 50 to 200 μm.

5. The carbon nanotube enhanced polymer of claim 1 wherein a weight percentage loading of the carbon nanotubes in the mixture is in a range of 0.0001 wt % to 25 wt %.

6. A method for manufacturing a carbon nanotube enhanced polymer, comprising:
providing the carbon nanotube enhanced polymer of claim 1 ; and
embedding the plurality of carbon nanotube sheets within a polymer matrix formed from the polymer powder to form an article.

7. The method of claim 6 wherein embedding the plurality of carbon nanotube sheets within the polymer matrix formed from the polymer powder comprising sintering the mixture.

8. A carbon nanotube enhanced polymer article formed by the method of claim 6 .

9. A carbon nanotube enhanced polymer comprising:
a polymer matrix; and
a plurality of carbon nanotube sheets embedded within the polymer matrix, wherein each carbon nanotube sheet of the plurality of carbon nanotube sheets has a length in a range of 0.1 to 10,000 μm, and wherein each carbon nanotube sheet of the plurality of carbon nanotube sheets consists of a network of intertwined carbon nanotubes that are intertwined with each other to form a shape of the carbon nanotube sheet such that the network of intertwined carbon nanotubes is configured to hold the shape of the carbon nanotube sheet by way of the intertwining of the carbon nanotubes.

10. The carbon nanotube enhanced polymer of claim 9 wherein the polymer matrix is selected from the group consisting of: polyetherketoneketone (PEKK), polyphenylene sulfide (PPS), polyamide 11, and combinations thereof.

11. The carbon nanotube enhanced polymer of claim 9 wherein each carbon nanotube sheet of the plurality of carbon nanotube sheets has the length in a range of 10 to 1000 μm.

12. The carbon nanotube enhanced polymer of claim 9 wherein each carbon nanotube sheet of the plurality of carbon nanotube sheets has the length in a range of 50 to 200 μm.

13. The carbon nanotube enhanced polymer of claim 9 wherein the carbon nanotube enhanced polymer is embedded with an amount of the carbon nanotube sheets sufficient to provide a resistance of the carbon nanotube enhanced polymer of less than 1E12 (1×10{circumflex over ( )}12) Ohms.

14. The carbon nanotube enhanced polymer of claim 9 wherein the carbon nanotubes comprise 0.0001 wt % to 25 wt % of a total weight of the polymer matrix and the plurality of carbon nanotube sheets.

15. The carbon nanotube enhanced polymer of claim 9 being a component of an air or space vehicle.

16. The carbon nanotube enhanced polymer of claim 9 wherein the carbon nanotube enhanced polymer is in a form of a filament.

17. A plurality of particulates of carbon nanotube enhanced polymer, wherein each particulate comprises the carbon nanotube enhanced polymer of claim 9 .

18. A method for manufacturing a carbon nanotube enhanced polymer, comprising:
providing the plurality of particulates of carbon nanotube enhanced polymer of claim 17 ; and
sintering the plurality of particulates of carbon nanotube enhanced polymer to form an article.

19. The method of claim 18 wherein sintering the plurality of particulates of carbon nanotube enhanced polymer comprises at least one of selective laser sintering and fused deposition modeling.

20. A carbon nanotube enhanced polymer article formed by the claim 18 .

Assignees

• Boeing Co

Inventors

• Tomzynska Anna M
• Aston Richard W
• Hastings Nicole M

Classifications

• Y10T428/30

  Self-sustaining carbon mass or layer with impregnant or other layer · CPC title

• B33Y70/10

  Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title

• B29L2031/30

  Vehicles, e.g. ships or aircraft, or body parts thereof {(vanes or blades B29L2031/08, air bags B29L2022/027)} · CPC title

• B29K2507/04

  Carbon · CPC title