Method for manufacturing films of high consistency nanocellulose suspensions

Patent metadata

Field	Value
Publication number	US-12187864-B2
Application number	US-202017598914-A
Country	US
Kind code	B2
Filing date	Mar 31, 2020
Priority date	Apr 5, 2019
Publication date	Jan 7, 2025
Grant date	Jan 7, 2025

Abstract

According to an example aspect of the present invention, there is provided a rapid, economically feasible method for producing continuous films with excellent properties using nanocellulose suspensions at high consistency.

First claim

The invention claimed is:

1. A method for manufacturing films from nanocellulose comprising:
feeding a nanocellulose suspension comprising modified or unmodified nanocellulose, with or without additives, and having at least 5 wt. % total solids, between two substrates, wherein at least one substrate is porous, to obtain a multi-layered structure, and
passing the multi-layered structure through one or more nips defining controlled gap(s) to form a film, wherein the feeding and passing take place before any drying of the nanocellulose.

2. The method according to claim 1 , wherein the nanocellulose comprises cellulose nanofibrils (CNF), microfibrillar cellulose (MFC), cellulose nanocrystals (CNC), bacterial cellulose suspensions, or any mixture of these, in modified or unmodified form.

3. The method according to claim 1 , wherein the mass percentage of the nanocellulose is at least 50% of the total dry mass of the suspension.

4. The method according to claim 1 , wherein the consistency of the nanocellulose suspension being used for film formation is in the range of 5-60%.

5. The method according to claim 1 , further comprising controlling film thickness by adjusting the nip gaps.

6. The method according to claim 1 , wherein the film is dried at ambient conditions or using external heating.

7. The method according to claim 1 , further comprising separating the film from the two substrates, keeping the film attached to either substrate, or transferring the film as a semi-dry or a fully dry film to a third substrate.

8. The method according to claim 1 , wherein the consistency of the nanocellulose suspension is at least 10%.

9. The method according to claim 1 , wherein the two substrates comprise a porous substrate and a nonporous substrate.

10. The method according to claim 9 , wherein the porous substrate comprises pores having a smaller pore size than the dimensions of the modified or unmodified nanocellulose.

11. The method according to claim 1 , wherein the two substrates each have a surface roughness in the range of 0.1-10 μm.

12. The method according to claim 1 , wherein the formed film has a thickness of 10-500 μm.

13. The method according to claim 1 , wherein the additives are present in the suspension, and wherein the additives comprise at least carboxymethyl cellulose (CMC) and sorbitol.

14. The method according to claim 1 , wherein the one or more nips comprises a plurality of nips, wherein a predetermined distance exists between respective pairs of the nips, and wherein the predetermined distance between the respective pairs of the nips decreases in a flow direction of the multi-layered structure through the plurality of nips.

15. The method of claim 1 , further comprising, after the feeding and passing steps, drying the film.

16. A method for manufacturing films from nanocellulose comprising:
feeding a nanocellulose suspension comprising modified or unmodified nanocellulose, with or without additives, between two substrates, wherein at least one substrate is porous, to obtain a multi-layered structure, and
passing the multi-layered structure through one or more nips defining one or more controlled gaps to form a film,
wherein the nanocellulose suspension has a solids content of at least 12% by weight, and
wherein the feeding and passing take place before any drying of the nanocellulose.

17. The method of claim 16 , wherein the nanocellulose suspension has a solids content of at least 15% by weight.

18. The method of claim 16 , wherein the nanocellulose suspension has a solids content of 20-60% by weight.

19. A method for manufacturing films from nanocellulose comprising:
feeding a nanocellulose suspension comprising modified or unmodified nanocellulose, with or without additives, and having at least 5 wt. % total solids, between two substrates, wherein at least one substrate is porous, to obtain a multi-layered structure,
passing the multi-layered structure through one or more nips defining one or more controlled gaps to form a film, and
only after the feeding and passing, drying the formed film.

Assignees

• Teknologian Tutkimuskeskus Vtt Oy

Inventors

• Kumar Vinay
• Jaiswal Aayush Kumar

Classifications

• C08L2205/02

  containing two or more polymers of the same C08L -group · CPC title

• C08L1/02

  Cellulose; Modified cellulose · CPC title

• C08J2301/02

  Cellulose; Modified cellulose · CPC title

• B32B27/36

  comprising polyesters · CPC title

• B32B27/32

  comprising polyolefins {(comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30)} · CPC title