Low-pore pellets and method for producing molded body

Patent metadata

Field	Value
Publication number	US-12186947-B2
Application number	US-202017610886-A
Country	US
Kind code	B2
Filing date	May 13, 2020
Priority date	May 13, 2019
Publication date	Jan 7, 2025
Grant date	Jan 7, 2025

Abstract

Provided are a pellet including a thermoplastic resin and cellulose nanofibers that enables the production of a molded body which has a good appearance in which yellowing is suppressed, and a method for producing a molded body using the same. According to one aspect, there is provided a pellet including a thermoplastic resin and cellulose nanofibers, wherein the number of pore-containing pellets per 100 pellets is 10 or less. Further, according to another aspect, there is provided a method for producing a molded body, which includes a step of preparing the pellets, and a step of injection molding the pellets in a mold to obtain a molded body.

First claim

The invention claimed is:

1. Pellets of a resin composition comprising a thermoplastic resin and cellulose nanofibers, the pellets having a cylindrical or elliptic cylindrical shape, wherein:
(i) the number of void-containing pellets per 100 pellets is 10 or less provided that when the number is other than 0, the void-containing pellets have a percentage of the void area with respect to the total area of a cylindrical cross-section of at least 1.3% to 4% or lower, wherein the void area is visible in the center of a transverse-cut surface of the cylindrical cross-section;
(ii) the thermoplastic resin comprises a crystalline resin; and
(iii) the cellulose nanofibers are hydrophobized cellulose nanofibers having a fiber diameter of 50 to 1000 nm and a fiber length/fiber diameter (L/D) ratio of 30 or greater.

2. Pellets according to claim 1 , wherein the pellets have been cut from a strand and has a longitudinal direction corresponding to a machine direction (MD) upon forming the strand and a radial direction corresponding to a transverse direction (TD) upon forming the strand.

3. Pellets according to claim 1 , wherein the number of void-containing pellets per 100 pellets is 1 or less.

4. Pellets according to claim 1 , wherein the pellets have been cut from a strand and has a longitudinal direction corresponding to a machine direction (MD) upon forming the strand and a radial direction corresponding to a transverse direction (TD) upon forming the strand, and the angle formed by the normal to the cut surface of the pellets with respect to the longitudinal direction of the pellets is 5° to 30°.

5. Pellets according to claim 1 , wherein the pellets have been cut from a strand and has a longitudinal direction corresponding to a machine direction (MD) upon forming the strand and a radial direction corresponding to a transverse direction (TD) upon forming the strand, and the short diameters of the radial cross-sections of the pellets are 2 mm to 5 mm.

6. Pellets according to claim 1 , which comprise the cellulose nanofibers at 0.1 to 30 mass %.

7. Pellets according to claim 1 , wherein the thermoplastic resin is a polyamide-based resin and/or polyolefin-based resin.

8. Pellets according to claim 1 , which further comprise an elastomer.

9. Pellets according to claim 1 , which further comprise cellulose nanocrystals having diameters of 100 nm or smaller and an L/D of less than 30, or cellulose microfibers with fiber diameters of greater than 1 μm and up to 50 μm, or a mixture of the same.

10. Pellets according to claim 1 , wherein the difference Tcc−Tcp between the temperature decrease crystallization peak temperature Tcc of the resin composition measured with a differential scanning calorimeter and the temperature decrease crystallization peak temperature Tcp of the thermoplastic resin measured with a differential scanning calorimeter, is 5° C. to 30° C.

11. Pellets according to claim 1 , wherein the ratio Ve/Vc of the total volume (Ve) of pellet voids and the total volume (Vc) of the cellulose nanofibers, per 100 pellets, is 0 vol % to 4 vol %.

12. Pellets according to claim 1 , wherein:
the resin composition further comprises a resin crystallization temperature lowering agent, and
the resin crystallization temperature lowering agent is a compound that lowers the temperature decrease crystallization peak temperature of the resin composition by 5 to 30° C. as measured with a differential scanning calorimeter.

13. A method for producing a molded body, which comprises:
a step of preparing pellets according to claim 1 , and
a step of injection molding the pellets in a mold to obtain a molded body.

14. Pellets according to claim 1 , wherein the pellets have been cut from a strand and has a longitudinal direction corresponding to a machine direction (MD) upon forming the strand and a radial direction corresponding to a transverse direction (TD) upon forming the strand, and a length of the pellets is 2 to 5 mm.

Assignees

• Asahi Chemical Ind

Inventors

• Tanimoto Kazuhiro

Classifications

• C08L1/02

  Cellulose; Modified cellulose · CPC title

• C08K2201/011

  Nanostructured additives · CPC title

• C08K2201/004

  Additives being defined by their length · CPC title

• C08K2201/003

  Additives being defined by their diameter · CPC title

• C08K7/02

  Fibres or whiskers · CPC title