Nickel-based superalloy formed by selective laser melting and preparation method thereof

Patent metadata

Field	Value
Publication number	US-12186803-B2
Application number	US-202217685824-A
Country	US
Kind code	B2
Filing date	Mar 3, 2022
Priority date	Mar 3, 2021
Publication date	Jan 7, 2025
Grant date	Jan 7, 2025

Abstract

Disclosed are a nickel-based superalloy formed by selective laser melting and a preparation method thereof. In the method, CrFeNb alloy powder is used as a grain refiner, and its element composition is within the composition range of a nickel-based superalloy powder to ensure that the prepared nickel-based superalloy has the same element composition with the original alloy; the grain size in the nickel-based superalloy could be refined by the addition of CrFeNb alloy powder, such that the anisotropic columnar grain structure in the alloy is transformed to equiaxed grain structure, thereby improving mechanical properties of the alloy.

First claim

What is claimed is:

1. A method for preparing a nickel-based superalloy formed by selective laser melting, comprising:
(1) ball milling and drying a nickel-based superalloy powder and a grain refiner in sequence to obtain a mixed powder,
the nickel-based superalloy powder comprising, percentages by mass, 18-19% of Fe, 52-53% of Ni, 19-20% of Cr, 3.0-3.5% of Mo, 0.2-0.3% of Al, 0.7-0.8% of Ti, 5.4-5.6% of Nb, 0.2-0.3% of Co, 0.01-0.02% of C, 0.04-0.05% of Mn, 0.1-0.2% of Si, 0.02-0.03% of Cu, not more than 0.0015% of S, and not more than 0.005% of B, and the grain refiner being a CrFeNb alloy powder; and

(2) selective laser melting the mixed powder obtained in act (1) to obtain the nickel-based superalloy,
wherein the CrFeNb alloy powder in act (1) comprises, in percentages by mass, 24-28% of Cr, 25-30% of Fe, and 45-50% of Nb;
the grain refiner in the mixed powder in act (1) accounts for 2 wt. %-4 wt. %;
the selective laser melting in act (2) is performed under conditions:
a laser power of 200-250 W, a scanning speed of 667-833 mm/s, and a layer thickness of 40-60 μm, a hatch distance of 50-90 μm, and a laser spot diameter of 75 μm; and
the method further comprises heating the nickel-based superalloy to a first temperature of 1050-1200° C. and maintaining at the first temperature for 1-2 hours, cooling in a furnace to a second temperature of 950-1000° C. and maintaining at the second temperature for 1-1.5 hours, and air-cooling to a third temperature of 700-750° C. and maintaining at the third temperature for 6-10 h; cooling to a fourth temperature of 600-650° C. at a rate of 50-60° C./h and maintaining at the fourth temperature for 6-10 h, and cooling in the furnace to room temperature.

2. The method as claimed in claim 1 , wherein in act (1), the nickel-based superalloy powder has a particle size of not larger than 53 μm, an average particle size of 20-25 μm, an oxygen content of 300-310 ppm, an apparent density of 4.30-4.40 g/cm 3 , and a tap density of 5.00-5.10 g/cm 3 .

3. The method as claimed in claim 1 , wherein in act (1), the CrFeNb alloy powder has a particle size of not larger than 25 μm, and a theoretical density of 8.0-8.5 g/cm 3 .

4. The method as claimed in claim 1 , wherein the drying in act (1) is performed at a temperature of 60-80° C. for 12-24 h.

5. The method as claimed in claim 1 , wherein the selective laser melting in act (2) is performed in a protective argon atmosphere.

Assignees

• Univ Northwestern Polytechnical

Inventors

• Su Haijun
• Zhao Yong
• Wang Meng
• Zhang Jun
• Guo Min
• Liu Lin
• Fu Hengzhi

Classifications

• C22C19/057 Primary

  with the maximum Cr content being less 10% · CPC title

• B22F2304/10

  Micron size particles, i.e. above 1 micrometer up to 500 micrometer · CPC title

• B22F2301/155

  Rare Earth - Co or -Ni intermetallic alloys · CPC title

• B22F2201/11

  Argon · CPC title

• B22F2009/043

  by ball milling · CPC title