Method for manufacturing grain-oriented electrical steel sheet

Patent metadata

Field	Value
Publication number	US-12180558-B2
Application number	US-202017422695-A
Country	US
Kind code	B2
Filing date	Jan 16, 2020
Priority date	Jan 16, 2019
Publication date	Dec 31, 2024
Grant date	Dec 31, 2024

Abstract

A method for manufacturing a grain-oriented electrical steel sheet includes: a silicon steel material production process of producing a silicon steel material; a hot rolling process of obtaining a hot rolled sheet by subjecting the silicon steel material to hot rolling; a cold rolling process of obtaining a steel sheet of a final sheet thickness by subjecting the hot rolled sheet to a single cold rolling process or multiple cold rolling processes having intermediate annealing performed between the cold rolling processes; a decarburization annealing process of subjecting the steel sheet to decarburization annealing; and a final annealing process of applying an annealing separator containing alumina as a main component to the steel sheet and subjecting the steel sheet to final annealing.

First claim

The invention claimed is:

1. A method for manufacturing a grain-oriented electrical steel sheet, comprising:
a silicon steel material production process of producing a silicon steel material;
a hot rolling process of obtaining a hot rolled sheet by subjecting the silicon steel material to hot rolling;
a cold rolling process of obtaining a steel sheet of a final sheet thickness by subjecting the hot rolled sheet to a single cold rolling process or multiple cold rolling processes having intermediate annealing performed between the cold rolling processes;
a decarburization annealing process of subjecting the steel sheet to decarburization annealing; and
a final annealing process of applying an annealing separator containing alumina as a main component to the steel sheet and subjecting the steel sheet to final annealing,
wherein the silicon steel material contains: in terms of mass %,
Si: 0.8 to 7.0%;
C: 0.085% or less;
acid-soluble Al: 0.010 to 0.065%;
N: 0.004 to 0.012%;
Mn: 1.00% or less;
S: 0.050% or less;
a total of 0.01 to 0.20% of one or both of Sn and Sb; and
the remainder: Fe and impurities,
wherein the decarburization annealing process includes: performing the decarburization annealing using a decarburization annealing furnace including a heating area and a soaking area,
an oxidation degree P1 of an atmosphere gas in the heating area satisfies the following Expression 1, and
an oxidation degree P2 of an atmosphere gas in the soaking area satisfies the following Expression 2, and
wherein the P1 and the P2 described above satisfy the following Expression 3:
0.01≤ P 1≤0.15  (Expression 1);

0.01≤ P 2≤0.15  (Expression 2); and

P 1> P 2  (Expression 3).

2. The method for manufacturing a grain-oriented electrical steel sheet according to claim 1 , wherein the silicon steel material further contains, in terms of mass %, Cr: 0.02 to 0.50%.

3. The method for manufacturing a grain-oriented electrical steel sheet according to claim 1 , wherein the silicon steel material further contains, in terms of mass %,
Cu: 0% or more and 0.4% or less;
P: 0% or more and 0.5% or less;
Ni: 0% or more and 1.0% or less;
B: 0% or more and 0.008% or less;
V: 0% or more and 0.15% or less;
Nb: 0% or more and 0.20% or less;
Mo: 0% or more and 0.10% or less;
Ti: 0% or more and 0.015% or less; and
Bi: 0% or more and 0.010% or less.

4. The method for manufacturing a grain-oriented electrical steel sheet according to claim 1 , further comprising:
a nitriding treatment process from before the decarburization annealing process to before secondary recrystallization initiation in the final annealing process.

5. The method for manufacturing a grain-oriented electrical steel sheet according to claim 1 , further comprising:
a hot-band annealing process of subjecting the hot rolled sheet obtained in the hot rolling process to annealing after the hot rolling process and before the cold rolling process.

6. The method for manufacturing a grain-oriented electrical steel sheet according to claim 2 , wherein the silicon steel material further contains, in terms of mass %,
Cu: 0% or more and 0.4% or less;
P: 0% or more and 0.5% or less;
Ni: 0% or more and 1.0% or less;
B: 0% or more and 0.008% or less;
V: 0% or more and 0.15% or less;
Nb: 0% or more and 0.20% or less;
Mo: 0% or more and 0.10% or less;
Ti: 0% or more and 0.015% or less; and
Bi: 0% or more and 0.010% or less.

7. The method for manufacturing a grain-oriented electrical steel sheet according to claim 2 , further comprising:
a nitriding treatment process from before the decarburization annealing process to before secondary recrystallization initiation in the final annealing process.

8. The method for manufacturing a grain-oriented electrical steel sheet according to claim 3 , further comprising:
a nitriding treatment process from before the decarburization annealing process to before secondary recrystallization initiation in the final annealing process.

9. The method for manufacturing a grain-oriented electrical steel sheet according to claim 2 , further comprising:
a hot-band annealing process of subjecting the hot rolled sheet obtained in the hot rolling process to annealing after the hot rolling process and before the cold rolling process.

10. The method for manufacturing a grain-oriented electrical steel sheet according to claim 3 , further comprising:
a hot-band annealing process of subjecting the hot rolled sheet obtained in the hot rolling process to annealing after the hot rolling process and before the cold rolling process.

11. The method for manufacturing a grain-oriented electrical steel sheet according to claim 1 , wherein the silicon steel material contains, in terms of mass %, S: 0.020% to 0.050%.

Assignees

• Nippon Steel Corp

Inventors

• Ushigami Yoshiyuki
• Nakamura Shuichi
• Fujii Hiroyasu
• Fujii Norikazu

Classifications

• C22C38/60

  containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur · CPC title

• C22C38/54

  with boron · CPC title

• C22C38/50

  with titanium or zirconium · CPC title

• C22C38/48

  with niobium or tantalum · CPC title

• C22C38/46

  with vanadium · CPC title