Method for carburization of HDRI produced in H2 based direct reduction process

Patent metadata

Field	Value
Publication number	US-12180554-B2
Application number	US-201916972916-A
Country	US
Kind code	B2
Filing date	Jun 12, 2019
Priority date	Jun 12, 2018
Publication date	Dec 31, 2024
Grant date	Dec 31, 2024

Abstract

The invention relates to a process for producing carburized directly reduced iron sponge from iron oxide material. Firstly, direct reduction is carried out by means of a reduction gas consisting at least predominantly of H 2 and the carbon content in the iron sponge is then increased by means of a carburizing gas which is fed in, after which used carburizing gas is at least partly taken off while largely avoiding mixing with the reduction gas. The plant for producing carburized directly reduced iron sponge from iron oxide material comprises a reduction zone for directly reducing introduced iron oxide material to directly reduced product by means of reduction gas consisting predominantly of H 2 and a reduction gas feed conduit opening into the reduction zone. It also comprises a carburization zone having a carburizing gas feed conduit opening into the carburization zone and a carburization offgas conduit.

First claim

The invention claimed is:

1. A process for producing carburized directly reduced iron sponge from iron oxide material, comprising:
firstly, directly reducing the iron oxide material in a reduction zone by a reduction gas having a hydrogen content of at least 80% by volume; and
taking off a used reduction gas as a topgas;
wherein:
a carbon content in the directly reduced iron sponge is then increased in a carburization zone by a carburizing gas fed in; and
after which used carburizing gas is at least partly taken off while avoiding mixing with the reduction gas, resulting in a proportion of carbon-containing gases in the topgas being less than 20% by volume;
wherein the reduction gas is heated before it comes into contact with the iron oxide material;
wherein a first partial amount of the topgas is fed to utilization as fuel gas for heating at least one of the reduction gas and the carburizing gas, and a size of the first partial amount of the topgas is regulated as a function of at least one of nitrogen N 2 , carbon dioxide CO 2 , carbon monoxide CO, and methane CH 4 content in the topgas; and
wherein a second partial amount of the used carburizing gas is fed to utilization as fuel gas for heating the reduction gas, and a size of the second partial amount of the used carburizing gas is regulated as a function of at least one of carbon dioxide CO 2 , carbon monoxide CO, and methane CH 4 content in the topgas.

2. The process of claim 1 , wherein a first partial amount of the used carburizing gas is, after treatment, combined again with fresh carburizing gas components and used again as carburizing gas for increasing the carbon content of the iron sponge.

3. The process of claim 1 , wherein heating of at least one member of the group consisting of the two members:
carburizing gas, and
treated used carburizing gas before or after being combined with fresh carburizing gas components,
is carried out before it comes into contact with the iron sponge.

4. The process of claim 1 , wherein the carburizing gas contains components which react exothermically with the directly reduced iron sponge.

5. The process of claim 1 , wherein the iron sponge is heated at least one of before and during introduction of the carburizing gas.

6. The process of claim 1 , wherein solid carbon C is mixed with the iron sponge at least one of before, during, and after introduction of the carburizing gas.

7. The process of claim 1 , wherein a supply conduit connects the reduction zone to the carburization zone.

8. A method for producing carburized directly reduced iron from iron oxide material, comprising:
directly reducing the iron oxide material in a reduction zone by a reduction gas having a hydrogen content of at least 80% by volume;
taking off a used reduction gas as a topgas;
increasing, after the reducing operation, a carbon content in the directly reduced iron in a carburization zone by feeding in a carburizing gas; and
taking off, after the increasing of the carbon content operation, at least some of the carburizing gas, while avoiding substantial mixing of the carburizing gas with the reduction gas, resulting in a proportion of carbon-containing gases in the topgas being less than 20% by volume;
wherein the reduction gas is heated before it comes into contact with the iron oxide material;
wherein a first partial amount of the topgas is fed to utilization as fuel gas for heating at least one of the reduction gas and the carburizing gas, and a size of the first partial amount of the topgas is regulated as a function of at least one of nitrogen N 2 , carbon dioxide CO 2 , carbon monoxide CO, and methane CH 4 content in the topgas; and
wherein a second partial amount of the used carburizing gas is fed to utilization as fuel gas for heating the reduction gas, and a size of the second partial amount of the used carburizing gas is regulated as a function of at least one of carbon dioxide CO 2 , carbon monoxide CO, and methane CH 4 content in the topgas.

9. The method of claim 8 , wherein a supply conduit connects the reduction zone to the carburization zone.

Assignees

• Primetals Technologies Austria GmbH

Inventors

• Boehm Christian
• Millner Robert

Classifications

• C21B13/02

  in shaft furnaces · CPC title

• C21B13/0073

  Selection or treatment of the reducing gases · CPC title

• B22D7/005

  from non-ferrous metals · CPC title

• C21B2100/26

  by adding additional fuel in recirculation pipes · CPC title

• C21B13/029

  Introducing coolant gas in the shaft furnaces · CPC title